• 한국염색가공학회지
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• 제22권2호
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• pp.101-109
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• 2010

The objective of this study is to investigate the characteristics of natural indigo dyeing of cotton fabric. Reduction and dyeing were carried out by one-step process using an infrared dyeing machine at the liquor ratio of 1:100, and subsequently oxidation and washing in water were followed. Dye uptake was increased with the increase of indigo concentration. Over the full range of dyeing tests, the dyeing condition was optimized to $40^{\circ}C$ for 40min. For most of dye concentrations, the cotton fabrics showed mainly PB color. Maximum K/S value was shown at 4g/L of sodium hydrosulfite concentration and the color strength increased with the increase of dye concentration. Value(lightness) decreased with the increase of dye uptake irrespective of mercerization or reduction method, while the mercerized cotton showed two times higher dye uptake than the untreated cotton. Whereas hue of the untreated cotton showed large decrease of P character(5.6~3.5 PB) with the increase of dye uptake, that of the mercerized cotton increased P character(4.7~5.5 PB). Irrespective of mercerization, value and chroma decreased with the increased of dye uptake. In addition, the untreated showed lower chroma than the mercerized cotton. In the case of traditional reduction, hue of the untreated cotton was changed very little with the increase of dye uptake. For hydrosulfite reduction, P character decreased with the increase of dye uptake. The difference of hue value was small with the change of reduction method(hydrosulfite reduction or traditional fermentation). Color character was not influenced by the changed maximum absorption wavelength. Washing fastness showed 4~4/5 shade change rating without any staining. And dry rubbing fastness was good at low color strength. The bacterial reduction ratios of dyed cotton fabric were also increased.

• 한국의류산업학회지
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• 제13권2호
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• pp.263-268
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• 2011

One-step reduction/dyeing method was applied for ramie dyeing with natural indigo powder. The effect of reduction/dyeing conditions including the pH of bath, dye temperature and time, and concentration of indigo powder and reduction agent on dye uptake and color properties were investigated. Regardless of addition of alkali, the dyed fabrics appeared in the PB Munsell color range(${\lambda}_{max}$: 660 nm) and the dye uptake was much higher with no addition of sodium hydroxide. Dyeing was carried out through the use of only sodium hydrosulfite in the bath. The maximum dye uptake was obtained at 60 for 30min. Saturated dye uptake was obtained at 2 g/L of sodium hydrosulfite concentration up to 2 g/ L of indigo powder. Whereas, at higher indigo powder concentration (4 g/L), more than 3 g/L of reducing agent concentration was required for obtaining the saturated dye uptake. Color reproducibility was reliable with color difference in the range of 0.03~0.16. Regardless of color strength, fastness to rubbing was acceptable with a 3/4~4/5. Fastness to washing, dry cleaning, and light of samples with low color strength were poor. Whereas, fastness to washing, dry cleaning, and light of samples with high color strength were very good.

• 패션비즈니스
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• 제11권1호
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• pp.136-148
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• 2007

African marigold is a common plant easily available in many flower beds. It has been reported as a practical and prospective resource of dyes since the dyes can be extracted from their bodies as well as petals. In this research, cotton and ramie fabrics which are made from natural cellulose were dyed using the extract of the African Marigold which is a variety of marigold. Dyeing tests were carried out under different pH of the dye solution and mordants. Dyeability was evaluated by examining and measuring surface color, K/S value, and the changes in the maximum absorption wavelength. The probability of improving dyeability was investigated by pre-mordanting with pre-treated chitosan. For the dyeing with marigold extract, the color tone did not differ by pre-mordanting and non-mordanting. Reaction with post-mordanting was excellent, which was colored in various yellow series. The best dyeability was achieved in dye solution of pH 6.5-7.0 which is not conditioned. The largest K/S value and color difference were obtained in tin mordanting. The dye uptake was greatly increased in chitosan pre-treated mordanting compared with the post-mordanting without chitosan pre-treatment. Due to its high heat resistance, African Marigold extract is easy for dye extraction and dyeing, and its dyeability is excellent for natural cellulose fibers. Also, colorfastness was proved to be practically usable.

• 한국의류학회지
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• 제32권12호
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• pp.1963-1970
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• 2008

전통적인 니남쪽염료 제조법을 기준으로 굴껍질가루 대신 칼슘하이드록사이드를 사용하여 천연인디고분말염료를 만들었다. 제조한 인디고분말염료에 대한 텐셀의 염색성을 몇 가지 실험조건에서 조사하였으며 염색견뢰도를 측정하였다. 제조한 인디고분말염료는 약 15.5%의 인디고 성분과 0.757%의 인디루빈 성분을 함유하는 것으로 분석되었다. 환원과 염색을 자동염색기로 one-step으로 하였으며 환원제로 소디움하이드로설파이트를 사용하였다. 최대염착량은 $60^{\circ}C$에서 얻었으며 초기 20분 동안에 염착이 거의 이루어졌다. 본 연구의 실험조건 범위에서는 염료농도 4g/L까지는 2g/L의 환원제 농도에서, 염료농도 8g/L에서는 3g/L의 환원제 농도에서 최대염착량을 보였다. 텐셀은 염욕에 가성 소다를 넣지 않고 pH 5.75에서 염색할 때 훨씬 높은 염착량을 나타냈다. 염색견뢰도는 4/5-5등급으로 대체로 우수하였으며, 염착량이 낮을수록 더 높은 광퇴색을 보였다.

• 한국의류학회지
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• 제21권5호
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• pp.911-921
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• 1997

Recently the interest in natural dyeing has been increased because of the color clarity, natural grace and reactionism in fashion. Indigo dyeing, safflower dyeing and Gal-ott in Cheju-Do become generally known, so the study about the natural dyeing is continued with national intrust and support. In this study, 1 used artemisia for various dyeing tests because we can get it easily. 1 tested the dyeability in wool as well as cotton and silk with wormwood in natural dyeing material. I also dyed nylon with the same material for the comparison of the molecular structure. The mercerization and the chitosan treatment were done in cotton to improve the low dyeability in the natural dyeing. The result of this study are as follows; We have to dye repeatedly to get deep color in natural dyeing, and mordant treatment brought good result in color difference and dyeing fastness. 1. Compared with silk, wool and nylon, the dyeability of cotton was the worse. The color difference of cotton was 18.81 without mordants , and 24.05 with mordant. The dyeability of cotton was much increased by mordants such as potassiumdichromate, copper sulfate, iron sulfate and salt water. The color of cotton was turned into yellow-green in potassium dichromate and yellow-green with deep green in copper sulfate. The mercerization and the chitosan treatment of cotton made the improvement in color, dyeability, laundering fastness, abrasion fastness. 2. The color difference of silk was 3 times as high as cotton. It showed the similar degree with the chitosan treated-cotton. That is to say, silk had good dyeability because it contains amino group and carboxyl group. The dyebility of silk was increased by a mordant such as iron sulfate, potassium dichromate and salt water, Drycleaning fastness showed 5 grade, abrasion-fastness was high over 4~5 grade and sunlight fastness showed 1 grade in all case. 3. The color difference of wool was the best among four fabrics because of 18 kinds of amino acids. It is considered that the sulfate of wool has the polarity and help metal- mordants get the better dyeability such as potassium dichromate, iron sulfate, copper sulfate, and aluminum chloride. The color was reddish-green in potassium dichromate, yellow.greenin iron sulfate and copper sulfate, and yellow in the rest mordants. Drycleaning fastness of wool showed over 4~5 grade, abrasion fastness 5 grade. Sunlight-fastness 1 grade. 4. The dyeability of nylon was almost same because of the similar molecular structure with silk. The clarity of color was poor. The color was yellow-green in copper sulfate and yellow in the rest mordants. Laundering fastness and abrasion-fastness of nylon was good. Sunlight- fastness represented 1 grade.

• 한국염색가공학회지
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• 제17권2호
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• pp.10-18
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• 2005

Silk fabrics mordanted with $Fe^{2+},\;Ni^{2+},\;and\;Cu^{2+}$ were dyed with the aqueous extract of Cassia tora L. seed which was known to include water soluble colorant kaempferol, one of flavonol compounds. Kaempferol can react with free radicals and chelate transition metal ions, which is thought to catalyze processes leading to the appearance of free radicals and have antioxidant activity. In relation to the coordinating and chelating mechanism of the ions with the silk protein and kaempferol, reasonable conclusions should be made on the colorant uptake and the water fastness of the fabric. The amount of the colorant on the fabric was in the order of $Fe^{2+}>Ni^{2+}>Cu^{2+}$. In case of dyeing through coordinaiton bonds between transition metal ions and silk protein and colorants, it was thought that the ions with the smaller secondary hydration shell, the higher preference to the atoms of the ligand coordinated, and the suitable bonding stability for the substitution of primarily hydrated water molecules for colorants led to the higher colorant uptake. The water fastnsess of the fabric was in the order of $Fe^{2+}>Cu^{2+}>Ni^{2+}$. It should be reasonable to choose transition metal ions with weak and strong tendency to the ionic and the coordination bond, respectively, to the carboxylate anion of the silk protein. Although further research needs to be done, the conclusions above may be generally applied to the natural dyeing through the coordination bond mechanism between transition metal ions and colorants and substrates.

• 복식
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• 제54권7호
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• pp.55-62
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• 2004

Research into the ancient dyeing and weaving culture is of critical importance to the fact that they constitute an integral part of the Korean costume. Due to the absence of the originals reflecting ancient costume cultures, it is difficult to figure out what the dyeing and weaving culture was like in ancient times. Because of limited visual materials available from the wall paintings of ancient tombs, studies conducted so far concerning the costume culture for the Goguryeo have focused on visual elements such as shape, structure, and type. As a result, research into ancient Korean dyeing and weaving cultures hasn't been properly made. Thanks to the presence of both some dyeing fabric originals from Goguryeo's neighboring countries and some visual materials like the wall paintings of the Goguryeo, it may be possible to obtain some clues to the dyeing and weaving culture. The dotted Pattern costumes were selected such as Muyongchong, No. 1 Jangcheon Tomb, Gakjeochong, Samsilchong, Ssangyeongchong, Susanri Tomb. According to a book titled ‘Hanwon’, the Goguryeo people manufactured fabrics in such a way that resist-dyed spots produced elaborate patterns over the purple fabric. It can be safely said that such dot patterns were produced by means of dyeing rather than weaving, because identical patterns aren’t well produced by means of painting and embroidery. Considering Goguryeo’s natural features, the dot patterns mentioned in historical literatures are thought to have been produced using animal’s skin. However, there is highest possibility that the dot Patterns were Produced using tie-resist dyeing or wax-resist dyeing techniques. With respect to the dyeing and weaving culture for the Goguryeo, one must refer to neighboring countries’ dyeing and weaving environments, given that the Goguryeo had engaged substantial cultural exchanges with China.

• 한국가정과교육학회지
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• 제25권1호
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• pp.79-94
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• 2013

본 연구에서는 전통 의생활문화에 대한 인식을 고취시키고자 우리나라의 대표적 전통 천연염색 중 하나인 감즙염색을 이용한 학습자료를 제작하고 전통 의생활문화 체험이 가능한 교수-학습과정안을 개발하였다. 연구방법에 있어서 교육적 효과를 조사하기 위해서는 설문지를 작성하였고, 수업 실시 전과 후의 교육적 효과를 검증하기 위해서는 t-test, Kruscal-Wallis 검정 및 상관분석을 행하였다. 이를 고등학교 기술 가정과에 '감즙염색 직물을 이용한 생활소품 만들기' 주제로 수업에 적용하여 전통 이미지에 대한 인식의 변화와 학습에 대한 흥미도 및 태도 변화를 검토한 결과는 다음과 같다. 첫째, 감즙염색에 관해 연구해온 축적물로 독창적인 학습자료를 개발하여 감즙염색과 전통 의생활문화를 이해하기 위한 협동학습을 실시한 결과, 현대 감각을 살린 아이디어 소품이 창출되었다. 둘째, '청소년의 전통 의생활문화와 교육에 대한 인식'에 있어, 수업 전과 후의 차이를 나타내어 수업 후에 인식의 향상을 보였다. 나아가 조사대상을 상/중/하위 그룹으로 분류하여 분석한 결과, 긍정적인 변화에 있어서도 그룹 간 차이를 보였는데, 사전 점수가 가장 낮았던 하위 그룹에서 가장 높은 향상을 나타내었다. 셋째, '감즙염색 직물을 이용한 생활소품 만들기' 수업의 효과를 분석한 결과, 모든 문항에서 '보통' 이상으로 나타나, 학생들은 감즙염색 직물로 생활소품 만들기 체험을 통하여 전통 의생활문화에 대한 관심과 흥미도가 높아졌고 태도가 긍정적으로 변화하였음이 확인되었다. 넷째, 전통 의생활문화 인식과 그 교육에 대한 인식 간에는 문화에 대한 인식이 높은 학습자일수록 그 교육에 대한 인식도 높아 정적인 상관이 높은 것으로 나타났다. 이상과 같이 개발된 학습자료와 교수-학습과정안을 통한 전통 의생활문화 수업은 전통적인 천연염색과 의생활문화에 대한 가치와 의미를 이해하는 인식에서 향상된 변화를 가져왔고, 아이디어를 창출하는 교육적 효과를 가져왔다. 전통 의생활 문화 교육은 지속적이고 다면적인 심화된 연구와 현장교육의 상호작용이 이루어질 때 교육적 시너지효과가 더 발현될 것이다.