• Journal of Soil and Groundwater Environment
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• 제16권5호
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• pp.67-73
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• 2011

Groundwaters were sampled from 730 wells being used for drinking purposes during 2007-2009. These samples were analysed using a gas-flow type GPC (Gas Proportional Counter) according to the USEPA method (900.0). We obtained a gross-alpha counting TDS (total dissolved solid) efficiency curve (Y = 0.0017X2 - 0.3122X + 19.165, X = TDS, Y = efficiency, $R^2$ = 0.9734) using natural uranium standard to get gross ${\alpha}$ value of the samples. The gross alpha values ranged from MDA (minimum detectable activity) to 14.88 pCi/L and 429 samples showed values higher than MDA (< 0.9 pCi/L). Correlations of the uranium values with the total alpha values and the gross-alpha values indicate that uranium values have high impacts on gross-alpha values. Groundwater samples of study areas were classified into four regions according to the rock types; plutonic (granite) rock region (427 areas), metamorphic rock region (181 aeras), sedimentary rock region (70 areas), volcanic rock region (52 areas). Groundwater of Cretaceous granite presented the highest gross-alpha value. Gross alpha in groundwaters showed no relationship with uranium in terms of the geological ages, rocks and minerals.

• Journal of the Korean Chemical Society
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• 제38권7호
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• pp.502-508
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• 1994

The measurement of trace amounts of uranium(VI) and thorium(VI) in the solutions containing high concentration of dissolved salts was carried out. The procedure using reversed phase liquid chromatography with trace enrichment techniques has been developed to cope with the high salt content of the samples. 2 ml of sample were passed through a small C_{18}$ reversed phase enrichment column with ${\alpha}$-HIBA eluent (0.11 M, pH 5.5) where the uranium and thorium were separated from other constituents and concentrated. The uranium and thorium were then backflushed from the column onto a deactivated C_{18}$ reversed phase analytical column where furthe separation was achieved with a mixed eluent (pH3.0, 0.17M ${\alpha}$-HIBA/0.0038 M 1-pentanesulfonate). The separated species were determined spectrophotometrically by postcolumn reaction with Arsenazo III, the chromogenic reagent. Detection limits were found within 1 ppb range for both species.

• Environmental Analysis Health and Toxicology
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• 제17권4호
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• pp.273-284
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• 2002

At present, the health risks associated with the natural radionuclides of ground water have become a concern as potential social problems. However, there are no regulatory actions or control strategies for such risks. Therefore, we have investigated and discussed the risks and associated management strategies for radionuclides in other countries. US EPA has proposed MCL (300 pCi/L) and AMCL (4,000 pCi/L) for radon, and 30 ppb for uranium, 15 pCi/L for gross-alpha and 5 pCi/L for radium as final MCLs. Also, Canada, WHO and European countries have their inherent management levels. Finally, we suggested several criteria for setting guidelines in our countries including exposure related criteria such as geological distribution, occurrence, exposure probability distribution, exposure population and multimedia exposure assessment, acceptable risk, and cost -benefit analysis. The national-scale exposure and risk assessment, and economic analysis should be conducted for producing and aggregating the representative information on these criteria.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 한국방사성폐기물학회 2004년도 학술논문집
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• pp.397-398
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• 2004

It is important to estimate the radiation activity of the nuclear fuel which is a source term of the loss of coolant accident. The purpose of this study is to identify the most important parameters of the source term calculation based on three fuel types: typical natural uranium CANDU fuel, slightly enriched uranium and DUPIC fuel. The characteristics of the radiation source term were analyzed through sensitivity calculations of the linear power, fuel turnup, and the power shape.(omitted)

• Nuclear Engineering and Technology
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• 제9권3호
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• pp.151-163
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• 1977

Being based on the Segal method, calculation was carried out for the natural uranium nuclear fuel cost with Zircaloy-4 cladding having design Parameters of Wolsung Nuclear Power Plant, CANDU-PHWR (Unit 1) , currently under construction in Korea aiming at its completion in 1982. An attempt was also made for tile sensitivity analysis of each fuel component; j. e., depreciation of fuel manufacturing plant caused by its life time, its load factor, production scale expansion of plant facilities, variations of construction and operating costs of fuel manufacturing plant, fluctuation of interest rates, extent of uranium ore price increases and effect of learning factor.

• Proceedings of the Korean Nuclear Society Conference
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• 한국원자력학회 1995년도 추계학술발표회논문집(2)
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• pp.1054-1059
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• 1995

국제원자력기구에서는 현재 적용되고 있는 보장조치(Safeguards) 방법을 보다 효과적이고 효율적으로 적용하기 위하여 1993년부터 'Program 93+2'라는 사업을 수행하고 있다. 이중 하나의 과제로 수행되고 있는 구역 보장조치는 기존의 보장조치 개념이 하나의 시설을 대상(Facility-Oriented Safeguards)으로 개발된 것과는 달리 동일한 범주의 핵물질을 취급하는 여러 개의 시설을 하나의 가상적인 구역(Fuel Cycle-Oriented Safeguards)으로 설정하여 보장조치를 적용하는 개념으로, 보다 강화된 사찰 활동에 의하여 보장조치 신뢰도를 향상시키면서 사찰 횟수 및 사찰량은 절감되고 있다. 우리나라는 한국원자력연구소의 중수로핵연료 가공시설과 월성 1호기를 천연우라늄 구역(Natural Uranium Zone)으로, 한국원전연료(주)의 경수로핵연료 가공시설과 국내의 모든 경수로를 저농축우라늄 구역(Low Enriched Uranium Zone)으로 설정하여 성공적으로 구역 보장조치를 적용하고 있다. 그러나 이러한 구역 보장조치의 적용에는 원자력산업 체제의 단순화와 같은 제약조건이 따른다. 앞으로 우리나라에서는 현재 적용되고 있는 구역 보장조치 방법이 보다 효율적으로 운영되고 시설 운영에 대한 방해를 최소화시키는 방안을 고려하여야 하며 이에 는 가공시설에서의 생산 및 수송 일정을 발전소 운영 및 사찰 일정과 적절히 조화시키는 방법, 가공시설에서 검증된 핵연료에 대하여 적절한 감시 및 봉인 장비를 적용하는 방법, 현재의 구역 이외의 시설 또는 핵물질에 새로운 구역을 설정, 적용하는 방안 등을 고려할 수 있다.

• Journal of Integrative Natural Science
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• 제7권2호
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• pp.130-137
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• 2014

Resins were synthesized by mixing N-phenylaza-15-crown-5 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous materials) divinylbenzene (DVB) copolymer with crosslink of 1%, 2%, 6%, and 12% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, thermo gravimetric analysis (TGA), surface area, and IR-spectroscopy. The effects of pH, equilibrium arrival time, dielectric constant of solvent and crosslink on adsorption of metal ions by the synthetic resin adsorbent were investigated. The metal ions were showed fast adsorption on the resins above pH 4. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium (VI) > zinc (II) > europium (III) ions. The uranium ion adsorbed in the order of 1%, 2%, 6%, and 12% crosslink resin and adsorption of resin decreased in proportion to the order of dielectric constant of solvents.

• Journal of Radiation Protection and Research
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• 제12권1호
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• pp.54-60
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• 1987

The quasi-exposure rate and the quasi-effective energy of the natural radiation in the field at 47 monitoring points around nuclear power plants have been studied with the pair filter thermoluminescence dosimeter system. The results of the six years observation showed that the relationship between the quasi-exposure rate $X_q$, and quasi-effective energy $E_q$ can be represented as a hyperbolic function: $X_q=A+C/(E_q-B)$, where the constants A and B correspond to the quasi-exposure rate of cosmic-rays and the minimum quasi-effective energy of natural radiation, respectively. Furthermore, the constant A is in close agreement with the values obtained by using ionization chambers and scintillation detectors. The constant B is approximately 0.68 MeV, closely corresponding to the mean energy of the photons emitted from natural uranium.

• Nuclear Engineering and Technology
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• 제55권10호
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• pp.3913-3923
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• 2023

Todays, medium energy resolution detectors are preferably used in radioisotope identification devices(RID) in nuclear and radioactive material categorization. However, there is still a need to develop or enhance « automated identifiers » for the useful RID algorithms. To decide whether any material is SNM or NORM, a key parameter is the better energy resolution of the detector. Although masking, shielding and gain shift/stabilization and other affecting parameters on site are also important for successful operations, the suitability of the RID algorithm is also a critical point to enhance the identification reliability while extracting the features from the spectral analysis. In this study, a RID algorithm based on Bayesian statistical method has been modified for medium energy resolution detectors and applied to the uranium gamma-ray spectra taken by a LaBr3:Ce detector. The present Bayesian RID algorithm covers up to 2000 keV energy range. It uses the peak centroids, the peak areas from the measured gamma-ray spectra. The extraction features are derived from the peak-based Bayesian classifiers to estimate a posterior probability for each isotope in the ANSI library. The program operations were tested under a MATLAB platform. The present peak based Bayesian RID algorithm was validated by using single isotopes(²⁴¹Am, ⁵⁷Co, ¹³⁷Cs, ⁵⁴Mn, ⁶⁰Co), and then applied to five standard nuclear materials(0.32-4.51% at.²³⁵U), as well as natural U- and Th-ores. The ID performance of the RID algorithm was quantified in terms of F-score for each isotope. The posterior probability is calculated to be 54.5-74.4% for ²³⁸U and 4.7-10.5% for ²³⁵U in EC-NRM171 uranium materials. For the case of the more complex gamma-ray spectra from CRMs, the total scoring (ST) method was preferred for its ID performance evaluation. It was shown that the present peak based Bayesian RID algorithm can be applied to identify ²³⁵U and ²³⁸U isotopes in LEU or natural U-Th samples if a medium energy resolution detector is was in the measurements.

• Analytical Science and Technology
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• 제16권6호
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• pp.450-457
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• 2003

The determination of uranium and its isotopes in spent nuclear fuels by isotope dilution mass spectrometry (IDMS) has been studied. The spent fuel samples were dissolved in 8 M $HNO_3$ or its mixture with 14 M $HNO_3-0.05M$ HF. The dissolved solutions were filterred on membrane filter with $1.2{\mu}m$ pore size. The uraniums in the spiked and unspiked sample solutions were quantitatively adsorbed by anion exchange resin, AG 1X8 and eluted with 0.1 M HCl. The contents of uranium and its isotopes ($^{234}U$, $^{235}U$, $^{236}U$ 및 $^{238}U$) in the spent fuel samples were determined by isotope dilution mass spectrometric method using $^{233}U$ as spike. The spike reference solution was standarized by reverse isotope dilution mass spectrometry (R-IDMS) using natural and depleted uranium. The results from IDMS were in average relative difference of 0.34% when compared with those by the potentiometric titration method.