• Environmental Engineering Research
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• v.15 no.2
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• pp.85-91
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• 2010

Romania aims to adopt and implement the European Union's legislation, also including that for the field of water management. Like other countries, groundwater in Romania is locally polluted from point sources, such as leaking landfills, as well as from diffuse pollution sources, include fertilizers, pesticides and leakages from sewers, in urbanized areas. Diffuse pollution can also occur indirectly, by over-exploitation of groundwater wells, resulting in salt water intrusion, as well as from mining and exploitation of mineral aggregates. Romania has quite an intensive monitoring scheme to measure groundwater quality in phreatic and confined aquifers. The purpose of the work resumed in this paper was to derive natural background levels (NBL) for groundwater in order to distinguish the natural elevated concentrations of some substances (natural phenomena) from point and diffuse pollution (anthropogenic phenomena). Based on these NBLs, threshold values (TV) for groundwater will be set according to the requirements of the European Water Framework Directive and the related Groundwater Directive. This paper describes the results of a study for the derivation of NBL and TV in a pilot Groundwater Body. Also, the process and draft results for extrapolating this work for all Romanian groundwater bodies is explained, as well as points for future consideration with respect to monitoring and management.

• Natural Product Sciences
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• v.23 no.4
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• pp.235-238
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• 2017

Colorado potato beetle is a most destructive insect pest of potato throughout the world. Although utilization of chemical insecticides is a main method for management of this pest, their negative side-effects such as threat to humans and the environmental pollution prompted researchers to search for natural alternatives. Recently plant essential oils with low or without side-effects against noun-targeted organisms and with high availability were considered as safe bio-pesticides. In the present study, toxicity of essential oil of Iranian lemongrass, Cymbopogon citratus Stapf, was evaluated against 3th instar larvae and adults of Colorado potato beetle by a leaf dipping method. Results displayed essential oil had notable toxicity against both larvae and adults after 24 and 48 h exposure times. Probit analysis revealed $LC_{50}$ values (lethal concentration to kill 50% of population) with 95% confidence limits were 10.32 (9.17 - 11.72) and 7.76 (6.80 - 8.74) ${\mu}l/ml$ for larvae and 6.27 (4.82 - 8.15) and 4.35 (3.24 - 5.62) ${\mu}l/ml$ for adults after 24 and 48 h, respectively. Based on regression analysis, a positive correlation between log concentration of essential oil and insect mortality was achieved. Results indicated C. citratus essential oil can be candidate as a natural alternative to the harmful chemical insecticides in the management of Colorado potato beetle.

• The Korean Journal of Pesticide Science
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• v.12 no.2
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• pp.177-183
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• 2008

For the development of integrated pest management system by harmonizing biological and chemical control, some experiments were carried out to select low toxic pesticides against natural enemies. Leaf dipping method, body dipping method, and diet treatment method were used for the toxicity evaluation against Microplites mediator adults. We tested 49 different pesticides (34 insecticides, 11 fungicides, 4 herbicides) at recommending concentration commonly used to control insect pests, disease and up-land weeds in chinese cabbage field. 16 insecticides, 11 fungicides, and 4 herbicides were shown to be low toxic to Microplites mediator adults in the treatment of body dipping.

• Korean Journal of Environmental Agriculture
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• v.39 no.4
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• pp.368-374
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• 2020

BACKGROUND: The residual analysis of polar pesticides has remained a challenge. It is even more difficult to simultaneously analyze multiple polar pesticides. Diquat, paraquat, and chlormequat are typical examples of highly polar pesticides. The existing methods for the analysis of diquat, paraquat and chlormequat are complex and time consuming. Therefore, a simple, quick and effective method was developed in the represent study for simultaneous analysis of diquat, paraquat and chlormequat in animal products, meat and fat using UPLC-MS/MS. METHODS AND RESULTS: Sample extraction was carried out using acidified acetonitrile and water and re- extracted with acidified acetonitrile and combine the extracts followed by centrifugation. The extract was then cleaned up with a HLB cartridge after reconstitution with acidic acetonitrile and water. The method was validated in quintuplicate at three different concentrations. The limits of detection (LOD) and quantification (LOQ) were 0.0015 and 0.005 mg/L, respectively. Matrix suppression effect was observed for all of the analytes. A seven point matrix matched calibration curve was constructed for each of the compound resulted excellent linearity with determination coefficients (R2) ≥ 0.991. Accuracy and precision of the method was calculated from the recovery and repeatability and ranged from 62.4 to 119.7% with relative standard deviation less than 18.8%. CONCLUSION: The recovery and repeatability of the developed method were in the acceptable range according to the Codex Alimentarius guideline. The developed method can be applied for the routine monitoring of diquat, paraquat, and chlormequat in animal products, meat and fat.

• Conservation Science in Museum
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• v.6
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• pp.39-46
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• 2005

The National Museum of Korea has a collection of various materials. In particular, items made from organic materials such as wood, paper, and leather are vulnerable to the influence of insects and germs, requiring fumigation as well as pesticides and bactericides. The influence of pesticides and bactericides on the change in dyed paper was examined by applying the oddy test used to confirm the toxicity of various materials used in museums. Results revealed that the products of B and H companies had the least influence on the change in dyed paper. On the other hand, the result of the examination of cochineal and curcuma dyed paper revealed a significant change in the control group compared to the one exposed together with dyed paper, probably because of humidity rather than the sample.

• Korean Journal of Environmental Agriculture
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• v.30 no.4
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• pp.357-366
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• 2011

BACKGROUND: Mathematical model such as GLEAMS have been developed and successfully applied to upland fields to estimate the level of pesticide residues in soil. But, the GLEAMS model rarely applied to the Korean conditions. METHODS AND RESULTS: To evaluate pesticide transport in soil residue using the GLEAMS model from pepper plot, Alachlor, Endosulfan, Cypermethrin and Fenvalerate were applied for standard and double rate. Soil sampling was conducted and decaying patterns of pesticides were investigated. Observed climate data such as temperature and irrigation amount were used for hydrology simulation. The observed pesticide residue data of 2008 were used for parameter calibration, and validation of GLEAMS model was conducted with observed data of 2009. After calibration, the $K_{oc}$ (Organic carbon distribution coefficient) and WSHFRC (Washoff fraction) parameters were identified as key parameters. The simulated concentrations of the pesticides except Fenvalerate were sensitive to $K_{oc}$ parameter. Overall, soil residue concentrations of Alachlor, Cypermethrin and Fenvalerate were fairly simulated compared to those of Endosulfan. The applicability of the GLEAMS model was also confirmed by statistical analysis. CONCLUSION(s): GLEAMS model was eligible for evaluation of pesticide soil residue for Alachlor, Cypermethrin and Fenvalerate.

• International Journal of Industrial Entomology and Biomaterials
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• v.6 no.2
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• pp.125-132
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• 2003

Uzi fly (Exorista bombycis Louis) is one of the major larval endo-parasitoid of silkworm (Bombyx mori). It causes extensive damage to sericulture industry. The application of synthetic organic pesticides has tremendous impact on minimizing pest population but their overuse and frequent misuse and high sensitivity towards the silkworms, has forced the entomologists to search for alternatives to chemical control, which is safe to silkworm, environment and farm workers. Biological control continues to offer exciting possibilities for the control of fly pest population. It is environmentally safe alternative to chemical control and offering a long-term protection. Several potential hymenopteran parasitoids have been screened. Among successful natural enemies, Nesolynx thymus, Trichomalopsis apanteloctena, Trichopria sp., Brachymeria lasus, Pediobius sp., Spalangia sp., Spilomicrus karnatakensis and Dhirhinus sp. are important. It is essential to predict accurately the efficacy of these natural enemies in a new habitat prior to its introduction. The important desirable attributes of these potential parasitoids viz., host searching capacity, specificity, power of increase and fitness and adaptability of the parasitoid in new environment has been recorded. Results of the host parasitoid interaction indicate that the aging of the host function as a factor that influence the host finding efficiency of the parasitoid. It is highly scored with 15-20 hrs old pupa of the host. However, aging of the parasitoid does not significantly affect it. The sex ratio is female biased which is advantageous from biological control point of view, Biological suppression methods involving conservation and utilization of natural enemies have been discussed in detail.

• The Korean Journal of Ecology
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• v.21 no.1
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• pp.15-26
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• 1998

This study was conducted to analyze arthropod community patterns in smallrice fields managed by different cultural methods [Conventional and Low Input Sustainable Agriculture(LISA)] in Suwon in 1995 and 1996. A half of nitrogen fertilizers and a quarter of pesticides were applied in the LISA field compared to in the conventional field. Total 15 orders and 43 families of arthropods were collected in two years. No differences were found in arthropod abundance and arthropod species composition between two differently practiced fields. The arthropod community was analyzed using guild categories. The arthropods were found in the order of 'pest(phytophag)>natural enemy>non-pest' in their densities. The pest species were mainly Homoptera and dominated by Delphacidae (Nilaparvata lugens Stal and Sogatella furcifera Horvath). They constituted > 80% of pest abundance. The spider was the most dominant group in the natural enemy and constituted > 90% of natural enemy abundance. Hunting spiders constituted > 60% of spider abundance and were dominated by Pirata subpiraticus Bos. et Str.(Lycosidae). Pachygnatha clerki Sundevall(Tetragnathidae), Gnathonarium dentatum Weider and Ummeliata angulituberis Oi(Erigonidae) were the dominant species in webbing spiders.

• Journal of Life Science
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• v.20 no.1
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• pp.60-65
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• 2010

Since organic sulfur compounds respond to GC/ECD sensitively, they interfere with quantitative separation of pesticides during residual pesticide analysis of Allium species. In this study, it was intended to develop a rapid and simple method for pesticide multi-residues analysis through clean-up and interferences by a solid-phase extraction (SPE). An SPE method employing silver nitrate impregnated Florosil cartridge was developed and evaluated for the elimination of sulfur compounds from the test solution of Allium species during pesticide residues analysis. The silver nitrate impregnated Florosil cartridge was prepared by efflux of 3 ml of 20% silver nitrate solution through Florosil cartridge (1 g packing, 6 ml tube). The extracts equivalent to 2, 4 6, and 10 g of each sample were loaded onto the cartridge and allowed to exude, and then the exudations were analyzed by GC/ECD. More than 95% of sulfur compounds were removed from the loaded extracts equivalent, up to 6 g in onion, 4 g in spring onion and 4 g in shallot, respectively. 40 pesticides were spiked in the Allium species and loaded onto the cartridge to determine the recoveries; from this, the recoveries of 34 pesticides were within 70~120%.

• Food Science and Industry
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• v.50 no.2
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• pp.2-11
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• 2017

Packaging is the last defensive barrier that protects food products from insect infestation during storage. However, though packaging films are hermetically sealed, insects can still be attracted by strong olfactory cues and penetrate through packaging materials, resulting in contamination. Insect contamination may cause consumers to be repulsed by contaminated food products. Especially, it is well known that stored-product insects cause critical problems in the cereal industry by inducing quantitative and qualitative damages to the grain products. The contaminations are caused by insects' metabolic byproducts and body parts, consequentially caused customer repulsion. Therefore, it is necessary to repel and control insects. However, management systems for storage insects in food industry have been inadequate for many years. Synthetic pesticides has been widely used, but pesticides may accumulate in foods, causing acute and chronic symptoms in consumers. For this reason, there is a growing need for the development of natural insecticides that can replace synthetic pesticides. Thus, various reports about anti-insect packaging materials and strategies to repel insects were introduced in this study. Furthermore, we suggested new strategies to develop an insect-repelling active packaging materials which could be applied in the food packaging industry.