• Journal of ILASS-Korea
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• v.24 no.4
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• pp.163-170
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• 2019

In this study, feedback logic using dual O₂ sensor values were developed to increase the purification capability of a three-way catalyst (TWC) in a compressed natural gas (CNG) engine. A heavy-duty inline 6-cylinder engine was used and the CNG was supplied to the engine through a mixer. This study consists of two main parts, namely, the proportional integral (PI) control with a front O₂ sensor and the feedback control with dual O₂ sensors. In the PI control experiment, effects of various parameters, such as P gain, I gain, and lean delay, on the TWC capability were identified. Based on the results of the PI control experiment, the feedback logic using dual O₂ sensor values were developed. In both cases, the nitrogen oxides (NO_X) emissions were nearly zero. However, the carbon monoxide (CO) emissions were reduced significant in the feedback logic with dual O₂ sensors than in the PI control with the front O₂ sensor.

• Journal of Power System Engineering
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• v.22 no.1
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• pp.56-63
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• 2018

After the recent fabrication of diesel vehicle exhaust gas by Volkswagen, nitrogen oxides ($NO_x$) and particulate matter (PM) are drawing attention as representative pollutants included in exhaust gas. When gasoline and diesel fuels are combusted through direct injection into a combustion chamber at high pressure, PM emission is actually increased. To find a solution to this problem, a basic study was conducted to derive an optimized variable for combustion of compressed natural gas (CNG) by applying CNG, acknowledged as a clean fuel, to direct injection system. The essence of this study is in the introduction of a radical ignition technology for compressed natural gas (RI-CNG) in a sub-chamber type engine. The direct injection system was applied to a sub-chamber to remove residual gas from previous combustion cycle. In addition, optimal mixer distribution was achieved by precisely setting ignition timing based on fuel injection timing and excess air ratio.

• Journal of the Korean Society of Safety
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• v.14 no.1
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• pp.78-85
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• 1999

The removal characteristics of H$_2$S from IGCC process over the natural manganese ore(NMO) containing several metal oxides($MnO_x$ : 51.85%, $FeO_y$ : 3.86%, CaO : 0.11%) were carried out in a batch type fluidized bed reactor(I.D.=40mm, height=0.8m). The $H_2S$ breakthrough curves were obtained as a function of temperature, initial gas velocity, initial gas concentration, and aspect ratio. The effect of particle size ratio and particle mixing fraction on $H_2S$ removal were investigated with binary system of different particle size. From this study, the adsorption capacity of $H_2S$ increased with temperature but decreased with excess gas velocity. The breakthrough time for $H_2S$ is reduced as the gas velocity is increased which leaded to gas by-passing and gas-solid contacting in a fluidized bed reactor. The results of the binary particle system with different size in batch experimental could predict to improve the behavior of continuous process of $H_2S$ removal efficiency. The natural manganese ore could be considered as potential sorbent in $H_2S$ removal.

• International Journal of Advanced Culture Technology
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• v.4 no.1
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• pp.10-18
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• 2016

In the present study, a single cylinder four stroke dual fuel diesel engine was tested to investigate the performance and emission characteristics of various test fuels. The engine was tested in dual fuel mode using diesel and Karanja biodiesel blends as pilot fuel along with Natural gas as primary fuel with a constant gas flow rate under different loading conditions. From the experimentation it was found that smoke opacity and oxides of nitrogen (NOx) are at low level for all the prepared test fuels in dual fuel mode but the emissions of carbon monoxide (CO), carbon dioxide ($CO_2$) and hydrocarbon (HC) were found higher. In comparison to diesel fuel, by increasing the blend percentage different emission parameters are found to be reduced. At different loading conditions all the test fuels show poor performance in dual fuel mode of operation when compared with single mode of operation with diesel and biodiesel. With increase in gas flow rates, except (NOx) and smoke emissions, the other emission parameters like CO, HC and $CO_2$ values increased for all test fuels. Again, all blended fuels showed lower performance compared to diesel. The maximum pilot fuel savings for diesel was found decreasing with the increase in karanja biodiesel. From the present work it may be concluded that Karanja biodiesel with Natural gas in dual mode can be can used as promising alternative for diesel with some required engine modifications and further research must be carried out to minimize the emissions of CO, HC and $CO_2$.

• BMB Reports
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• v.34 no.3
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• pp.189-193
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• 2001

Curcumin a yellow pigment from Curcuma Tonga, has been known to possess antioxidative and anticarcinogenic properties, as well as to induce apoptosis in some cancer cells. There have been, however, several contradictory reports that hypothesized curcumin (a hydrophobic molecule) can bind a membrane Gpid bilayer and induce nonspecific cytotoxicity in some cell lines. Why curcumin shows these contradictory effects is unknown. In A-431 cells, growth inhibition by curcumin is due mostly to the specific inhibition of the intrinsic tyrosine kinase activity of the epidermal growth factor receptor, as reported earlier by Korutla et al. Thus, we assumed that the cell death of A-431 by curcumin might be due to the specific induction of apoptosis. In this paper we clearly show that curcumin induces apoptosis in A-431 cells. The cureumin-induced cell death of A-431 exhibited various apoptotic features, including DNA fragmentation and nuclear condensation. Furthermore, the curcumin-induced apoptosis of A-431 cells involved activation of caspase-3-like cysteine protease. Involvement of caspase-3 was further confirmed by using a caspase-3 specific inhibitor, DEVD-CHO. In another study, decreased nitric oxide (NO) production was also shown in A-431 cells treated with curcumin, which seems to be the result of the inhibition of the iNOS expression by curcumin, as in other cell lines. However, 24 h after treatment of curcumin there was increased NO production in A-431 cells. This observation has not yet been clearly explained. We assumed that the increased NO production may be related to denitrosylation of the enzyme catalytic site in caspase-3 when activated. Taken together, this study shows that the cell death of A-431 by curcumin is due to the induction of apoptosis, which involves caspase-3 activation.

• Journal of the Korean Chemical Society
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• v.48 no.1
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• pp.46-52
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• 2004

The effect of crystallinity on the structural stability of layered manganese oxide has been systematically investigated. While well-crystalline manganate was prepared by solid-state reaction-ion exchange method, nanocrystalline one was obtained by Chimie-Douce reaction at room temperature. According to micro-Raman and Mn K-edge X-ray absorption spectroscopic results, manganese ions in both the manganese oxides are stabilized in the octahedral sites of the layered lattice consisting of edge-shared MnO6 octahedra. The differential potential plot clarifies that the layered structure of nanocrystalline material is well maintained during electrochemical cycling, in contrast to the well-crystalline homologue. From the micro-Raman results, it was found that delithiation-relithiation process for well-crystalline material gives rise to the structural transition from layered to spinel-type structure. On the basis of the present experimental findings, it can be concluded that nanocrystalline nature plays an important role in enhancing the structural stability of layered manganese oxides.

• Applied Chemistry for Engineering
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• v.9 no.2
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• pp.278-285
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• 1998

In a fixed bed reactor, adsorption capacity of $SO_2$ in simulated flue gases was investigated with NMO(natural manganese ore), composed of various metal oxides, iron ore and $CuO/{\gamma}-Al_2O_3$ as adsorbents. The experiment carried out in a fluidized bed reactor with variables such as gas velocity, temperature and particle size. Iron ore was excluded in the fluidized bed reactor experiment for the lower adsorption capacity. The adsorption of $SO_2$ in metal oxide is a typical chemisorption because the adsorption capacity of all adsorbents increased with temperature. The effect of particle size on the adsorption capacity was varied with the ratio, $U_o/U_{mf}$ and the difference of $U_o-U_{mf}$. $U_o$ is the gas velocity, $U_{mf}$ is the minimum fluidization gas velocity. $U_o/U_{mf}$ and $U_o-U_{mf}$ explain the behavior of the gas and solids in the fluidized bed reactor. From the performance equation of the fluidized bed reactor, kinetic reaction rate constants were obtained by the non-linear least square method. The adsorption capacity of NMO proved the potential use of $SO_2$ adsorbents.

• Journal of Ocean Engineering and Technology
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• v.32 no.5
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• pp.380-385
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• 2018

With the tightening of environmental regulations (i.e., IMO Tier III), natural gas (NG) has been spotlighted as an eco-friendly fuel with few air pollutants other than nitrogen oxides (NOx) and sulfur oxides (SOx). For reasons of economic efficiency, it is mainly stored and transported in a liquid state at $-163^{\circ}C$, which is a cryogenic temperature, using a liquefied gas storage tank. Accordingly, it is necessary to reduce the boil-off gas (BOG) occurrence due to the heat flow according to the temperature difference between the inside and outside of the storage tank. Therefore, in this study, a BOG measurement test on an independent-type storage tank made up of SUS304L was carried out. The test results showed the tendency for BOG occurrence according to the temperature under different filling ratios.

• Nuclear Engineering and Technology
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• v.56 no.7
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• pp.2711-2717
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• 2024

The current work aims to fabricate metal oxide-doped (PbO, Fe₂O₃, MgO, and Al₂O₃, each of which boasts a purity of 99%) zinc barium borate glasses through the melt quenching technique at the 1000 ℃ melting temperature. The results showed that adding 5 mol.% of metal oxides PbO, Fe₂O₃, Al₂O₃, and MgO increases the density of the zinc barium borate glasses. Additionally, the fabricated glasses' mechanical properties were determined based on the Makishima-Mackenzie model, which proved that the highest mechanical properties were achieved for glasses doped with Al₂O₃ compounds. The mechanical moduli for the glasses doped with Al₂O₃ reach 80.95 GPa (Young), 59.90 GPa (bulk), 31.75 GPa (shear), and 102.23 GPa (longitudinal). Additionally, the Al₂O₃-doped glasses' microhardness reaches 4.77 GPa. Moreover, estimation of the fabricated glasses' gamma-ray shielding capacity utilized Monte Carlo simulation. The highest linear attenuation coefficients are 29.132, 19.906, 19.243, and 18.923 cm^-1 obtained at 0.033 MeV for glasses dopped by PbO, Fe₂O₃, MgO, and Al₂O₃, respectively. Therefore, glasses doped with 5 mol.% of PbO have high gamma-ray shielding capacities followed by glasses doped by Fe₂O₃.

• Journal of Hydrogen and New Energy
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• v.17 no.1
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• pp.109-116
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• 2006

The heat treatment characteristics of natural talc sample was investigated in diverse analytical view point. The mass decrease comes to heat treatment was resulted by the continuous and the discontinuous process and the obtained result show very similar two step profiles with 8.9 % mass decrease. The dehydroxylation of -OH groups contained talc crystal was analyzed by spectroscopic method and the crystallographic variations was also observed after heat treatment. According to XPS result, the magnesium hydroxide($Mg(OH)_2$) of untreated talc powder changed to magnesium oxides(MgO) after heat treatment.