• Food Science and Preservation
• /
• v.7 no.3
• /
• pp.256-261
• /
• 2000

Carrot, cucumber, spinach which contain carotenoid and chlorophyll pigment, and green tea which contain catechin were selected to natural materials. Although the yield of soybean curd with added natural materials were below than non-added soybean curd. Also, the additive natural materials in the soybean curd had no effect to the texture in soybean curd. The optimum concentration of added natural materials were high acceptability opposed to the non-containing soybean curd. The optimum concentration of added natural materials soybean curds was obtained : 4% of carrot, 10% of cucumber, 1.0% of spinach and 0.05% of green tea powder. And soybean curd with spinach and green tea addition had a longer shelf life because it prevented growing of bacteria in the early stage. Therefore, it could be possible to prevent the deterioration of soybean curd with added natural materials.

• Bulletin of the Korean Chemical Society
• /
• v.30 no.3
• /
• pp.556-560
• /
• 2009

Aggregation behavior of three kinds of benzindocarbocyanine dyes in aqueous methanol solution was studied by UV-Vis absorption spectrum. The results indicated that the three dyes all existed monomer-dimer equilibrium in aqueous methanol solution (concentration range $10^{−5}\;to\;10^{−6}$ M) at 25.0$\sim$41.0 ${^{\circ}C}$ for Dye 1, 28.0$\sim$49.0 ${^{\circ}C}$ for Dye 2 and 26.0$\sim$47.0 ${^{\circ}C}$ for Dye 3. The fundamental property of the three dyes as the dimeric association constant KD, the dimeric free energy ${\Delta$}G_D, the dimeric entropy ${\Delta$}S_D, and the dimeric enthalpy ${\Delta$}H_D were determined. The ${\Delta$}H_D of three dyes: Dye 1, Dye 2 and Dye 3 was -42.5, -15.1 and -18.9 kJ/mol, respectively. The experimental observations were the subject of a theoretical study including the ground-state geometries which were fully optimized using DFT at B3LYP/6-31G level. The effect of dye molecule structure on ${\Delta$}H_D was discussed by theoretical calculations.

• Korean Journal of Organic Agriculture
• /
• v.10 no.4
• /
• pp.37-45
• /
• 2002

This study was conduction to investigate the effects of natural materials such as $GB_{10}$ chitofarm, chaff charcoal, and chaff charcoal sap, on quality and yield of chinese cabbage, Natural materials were treated on seeds soil, and leaves. The total plant weight, head weight, head length, head width, leaf length, leaf width, and sugar content of chinese cabbage in treatment with natural materials showed significant difference compared with control. The yield of chinese cabbage in $GB_{10}$ soil treatment and 1% $GB_{10}$ leaf treatment was increased 53% compared with control. The total nitrogen $P_2O_5$, $K_2O$, CaO, MgO, $Na_2O$, and Mn in total plant were analyzed. The chemical components were increased in total plant of chinese cabbage treated with natural materials compared with control natural materials increased the quality of chinese cabbage.

• International Journal of Industrial Entomology and Biomaterials
• /
• v.35 no.2
• /
• pp.83-88
• /
• 2017

Silk is appealing materials for many biomedical applications involving tissue engineering and implantable devices, because of its biocompatibility, environmental stability, controlled proteolytic biodegradability and morphologic flexibility. Silk matrix is required for the treatment of a wide wound area, but the present silk matrix is made by the second processing, and thus, the labor and the cost are high. In this work, we investigated the optimal production condition of natural silk 3D matrix using the silkworms and invented Automatic Silk Matrix Making Machine (ASMMM) for natural silk 3D matrix production. As a result, we determined that optimal production condition for making A4 paper size natural silk 3D matrix was used Rough aquarelle paper on surface at $25^{\circ}C$ and 30 silkworm larvae. These results are expected to provide basic data for the efficient production of the natural silk 3D matrix, and it is suggested that the produced natural silk 3D matrix is useful as a medical biomaterials.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.08a
• /
• pp.251.2-251.2
• /
• 2013

Natural photosynthesis utilizes two proteins, photosystem I and photosystem II, to efficiently oxidize water and reduce NADP+ to NADPH. Artificial photosynthesis which mimics this process achieve water splitting through a two-step Z-schematic water splitting process using man-made synthetic materials for hydrogen fuel production. In this study, Z-scheme system was achieved from the hybrid materials which composed of hydrogen production part as photosystem I protein and water oxidizing part as semiconductor BiVO4. Utilizing photosystem I as the hydrogen evolving part overcomes the problems of existing hydrogen evolving p-type semiconductors such as water instability, expensive cost, few available choices and poor red light (>600 nm) absorbance. Some problems of photosystem II, oxygen evolving part of natural photosynthesis, such as demanding isolation process and D1 photo-damage can also be solved by utilizing BiVO4 as the oxygen evolving part. Preceding research has not suggested any protein-inorganic-hybrid Z-scheme composed of both materials from natural photosynthesis and artificial photosynthesis. In this study, to realize this Z-schematic electron transfer, diffusion step of electron carrier, which usually degrades natural photosynthesis efficiency, was eliminated. Instead, BiVO4 and Pt-photosystem I were all linked together by the mediator gold. Synthesized all-solid-state hybrid materials show enhanced hydrogen evolution ability directly from water when illuminated with visible light.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2004.04a
• /
• pp.27-30
• /
• 2004

Different types of hybrid negative materials on pitch based carbon and natural graphite for lithium ion batteries were studied. Two types of active materials were prepared, that is, pitch based graphite carbon, and pitch based carbon impregnating natural graphite. The specific capacity, capacity recovery in high temperature condition, and other electrochemical properties were achieved for these materials. We found that addition of natural graphite type to the pitch based carbon can significant1y improve the specific capacity and interfacial resistance. However, use of natural graphite will cause a serious capacity loss in the high temperature condition owing to its increasing interface resistance. The specific capacity ranged from 321 to 348 mAh/g and the maximum specific capacity was obtained in the case of pitch based carbon impregnating natural graphite.

• Food Science and Preservation
• /
• v.7 no.3
• /
• pp.249-255
• /
• 2000

Soybean curd has been known as one of the most favorite traditional Korean foods as well as being high in protein. Each concentration of added natural materials soybean curds was chosen as 4% of carrot, 10% of cucumber, 1.0% of spinach and 0.05% of green tea powder. The yield of soybean curd containing natural materials was similar to that of non-containing curd. According to add GDL as coagulant, the yield of soybean curd containing natural materials was the highest. The turbidity of added natural material soybean curds was the highest coagulated with $CaCl_2$, but soybean curd containing green tea had the highest turbidity in the coagulated with GDL. In the chromaticity and texture properties of the additive natural materials in yhe soybean curd, the variety of additives had no effect. In the composition of natural materials, the carotenoid and chlorophyll content of soybean curds were high with $MgCl_2$ and $CaCl_2$ but polyphenol was high use of $CaSo_4$ and GDL.

• Proceedings of the SAREK Conference
• /
• 2006.06a
• /
• pp.1174-1179
• /
• 2006

This study aims to reduce the pollutant emission for improving the IAQ by finishing with natural materials. To investigate the concentration of pollutants such as Vocs, HCHO, both the chamber experiment and field measurement were conducted. The results of the study can be summarized as flows. (1) According to the chamber experiment of pollutant-emitting porwer of diatomite materials showed that VOCs and formaldehyde emission rates were lower and satisfied to the most on the HB Grade. (2) The field measurement of pollutant-emitting concentration of clay materials were lower 35% than other materials. (3) The Vocs and formaldehyde were most emitted from furnitures and the emission rate were found to be proportional to indoor air temperature. To control the emitted pollutants efficiently, the reasonable selection of finishing with natural materials are required.

• Korean Journal of Materials Research
• /
• v.25 no.6
• /
• pp.279-287
• /
• 2015

In order to prepare anode materials for high power lithium ion secondary batteries, carbon composites were fabricated with a mixture of petroleum pitch and coke (PC) and a mixture of petroleum pitch, coke, and natural graphite (PC-NG). Although natural graphite has a good reversible capacity, it has disadvaantages of a sharp decrease in capacity during high rate charging and potential plateaus. This may cause difficulties in perceiving the capacity variations as a function of electrical potential. The coke anodes have advantages without potential plateaus and a high rate capability, but they have a low reversible capacity. With PC anode composites, the petroleum pitch/cokes mixture at 1:4 with heat treatment at $1000^{\circ}C$ (PC14-1000C) showed relatively high electrochemical properties. With PC-NG anode composites, the proper graphite contents were determined at 10~30 wt.%. The composites with a given content of natural graphite and remaining content of various petroleum pitch/cokes mixtures at 1:4~4:1 mass ratios were heated at $800{\sim}1200^{\circ}C$. By increasing the content of petroleum pitch, reversible capacity increased, but a high rate capability decreased. For a given composition of carbonaceous composite, the discharge rate capability improved but the reversible capacity decreased with an increase in heat treatment temperature. The carbonaceous composites fabricated with a mixture of 30 wt.% natural graphite and 70 wt.% petroleum pitch/cokes mixture at 1:4 mass ratio and heat treated at $1000^{\circ}C$ showed relatively high electrochemical properties, of which the reversible capacity, initial efficiency, discharge rate capability (retention of discharge capacity in 10 C/0.2 C), and charge capacity at 5 C were 330 mAh/g, 79 %, 80 %, and 60 mAh/g, respectively.

• Korean Journal of Materials Research
• /
• v.16 no.11
• /
• pp.692-697
• /
• 2006

Deodorization of natural zeolites have been improved not only for polar but also for non-polar pollutants by sucessive ion exchanges of H and Ag ions starting from Korean natural zeolite with high adsorption capacity. The modified zeolites with $TiO_2$ coating on the surface revealed high deodorization and photocatalytic decomposition effects. Further modification was made with $10{\sim}20nm$ silica nano particles coating on the surface, the resulting composite particles of $SiO_2/TiO_2/modified$ natural zeolite revealed not only comparable deodorization but also better durability and resisatnce to color change compared to the $TiO_2$/modified natural zeolite without much compensation of photocatalytic decomposition effect, when the composite particles were exposed to the polypropylene non-woven fiber coated with organic binder. It is expected for the composite particle prepared here to be used as indoor building materials for indoor air quality control.