• Title/Summary/Keyword: nanoscience

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Influence of commercial detergents on UF membrane ageing: Case of drinking water

  • Moulin, P.;Regula, C.;Carretier, E.;Wyart, Y.;Sergent, M.;Gesan-Guiziou, G.;Ferry, D.;Vincent, A.;Boudot, D.
    • Membrane and Water Treatment
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    • v.4 no.1
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    • pp.27-51
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    • 2013
  • During cleaning steps, ultrafiltration membranes are mechanically and chemically stressed. This may result in membrane degradations and failures. In this paper, polysulfone membranes were used to evaluate membrane deteriorations by commercial detergents in static conditions. Ageing of the membrane was simulated by immersing samples in solutions containing commercial detergents with various concentrations, temperatures and times defined by experimental designs. Indeed, an innovative approach in the chemical membranes ageing researches, based on methodological tools, was used in order to achieve significant ageing experiments without using an accelerated ageing protocol. The macroscopic changes were monitored by permeability measurements and mechanical strength tests coupled with a microscopic characterization by ATR-FTIR and HRSEM. The present work details results obtained for three commercial detergents: an alkaline, an acidic and an enzymatic detergent. It was found that the detergents used in the industrial advised conditions (concentration, temperature and time of contact) were not detrimental for membrane properties (permeability and elongation at break) and so for the quality of the produced water. Over the industrial cumulated time of contact, different ageing effects can be observed and compared with the ones induced by NaOCl.

Influence of nano-silica on the failure mechanism of concrete specimens

  • Nazerigivi, Amin;Nejati, Hamid Reza;Ghazvinian, Abdolhadi;Najigivi, Alireza
    • Computers and Concrete
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    • v.19 no.4
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    • pp.429-434
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    • 2017
  • Failure of basic structures material is usually accompanied by expansion of interior cracks due to stress concentration at the cracks tip. This phenomenon shows the importance of examination of the failure behavior of concrete structures. To this end, 4 types of mortar samples with different amounts of nano-silica (0%, 0.5%, 1%, and 1.5%) were made to prepare twelve $50{\times}50{\times}50mm$ cubic samples. The goal of this study was to describe the failure and micro-crack growth behavior of the cement mortars in presence of nano-silica particles and control mortars during different curing days. Failure of mortar samples under compressive strength were sensed with acoustic emission technique (AET) at different curing days. It was concluded that the addition of nano-silica particles could modify failure and micro-crack growth behavior of mortar samples. Also, monitoring of acoustic emission parameters exposed differences in failure behavior due to the addition of the nanoparticles. Mortar samples of nano-silica particles revealed stronger shear mode characteristics than those without nanoparticles, which revealed high acoustic activity due to heterogeneous matrix. It is worth mentioning that the highest compressive strength for 3 and 7 test ages obtained from samples with the addition of 1.5% nano-silica particles. On the other hand maximum compressive strength of 28 curing days obtained from samples with 1% combination of nano-silica particles.

Effects of Antidementia on LMK02 in APP-transgenic Fly (장원환가감방(壯元丸加減方)인 LMK02가 아밀로이드 전구단백질(前驅蛋白質)으로 형질전환(形質轉換)된 초파리에 미치는 효과)

  • Kim, Sang-Tae;Kang, Hyung-Won;Han, Pyeong-Leem;Cho, Hyoung-Kwon;Kim, Tae-Heon;Lyu, Yeoung-Su;Son, Hyeong-Jin
    • Journal of Oriental Neuropsychiatry
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    • v.19 no.2
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    • pp.151-163
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    • 2008
  • Objective : Recent studies indicate that the deposition of beta-amyloid ($A{\beta}$) is related in the pathogenesis of Alzheimer's disease (AD), but the underlying mechanism is still not clear. Method : To investigate the potential cellular functions of APP and LMK02, we use transgenic drosophila as a model was treated with either LMK02, and the effect in APP expression was determined by climbing assay. LMK02 have been shown to be neuroprotective in fly model systems. We asked whether dietary supplementation with LMK02 would influence behavior and AD-like pathology in a transgenic fly model. Result LMK02 water extract have attenuated fly death in vivo. LMK02-treated fly increased percentage of flight ability more longly and survival ratio more than controls. APP-GRIM drosophila treated with LMK02 had significantly less accumulation of APP deposition in the eye and brain as compared to control drosophila. Conclusion : These results suggest that LMK02 prevent APP-induced neurotoxicity through attenuating flies death induced by APP, and may be useful as potential therapeutic agents for AD.

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Anti-Oxidative Effect of Myrtenal in Prevention and Treatment of Colon Cancer Induced by 1, 2-Dimethyl Hydrazine (DMH) in Experimental Animals

  • Lokeshkumar, Booupathy;Sathishkumar, Venkatachalam;Nandakumar, Natarajan;Rengarajan, Thamaraiselvan;Madankumar, Arumugam;Balasubramanian, Maruthaiveeran Periyasamy
    • Biomolecules & Therapeutics
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    • v.23 no.5
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    • pp.471-478
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    • 2015
  • Colon cancer is considered as the precarious forms of cancer in many developed countries, with few to no symptoms; the tumor is often diagnosed in the later stages of cancer. Monoterpenes are a major part of plant essential oils found largely in fruits, vegetables and herbs. The cellular and molecular activities show therapeutic progression that may reduce the risk of developing cancer by modulating the factors responsible for colon carcinogenesis. Colon cancer was induced with DMH with a dose of (20 mg/Kg/body weight) for 15 weeks by subcutaneous injection once in a week. Myrtenal treatment was started with (230 mg/Kg/body weight) by intragastric administration, one week prior to DMH induction and continued till the experimental period of 30 weeks. The Invivo results exhibit the elevated antioxidant and lipid peroxidation levels in DMH treated animals. The Histopathological analysis of colon tissues well supported the biochemical alterations and inevitably proves the protective role of Myrtenal. Treatment with myrtenal to cancer bearing animals resulted in a remarkable increase in the inherent antioxidants and excellent modulation in the morphological and physiological nature of the colon tissue. It is thus concluded that myrtenal exhibits excellent free radical scavenging activity and anticancer activity through the suppression of colon carcinoma in Wistar albino rats.

Preparation of Self-Cleaning Coating Films with Nano- and Microstructure (나노마이크로 구조의 자기세정 기능성 코팅막의 제조)

  • Jeong, A-Rong;Kim, Jun-Su;Yun, Jon-Do
    • Korean Journal of Materials Research
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    • v.22 no.8
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    • pp.416-420
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    • 2012
  • Recently nanoscience and nanotechnology have been studied intensively, and many plants, insects, and animals in nature have been found to have nanostructures in their bodies. Among them, lotus leaves have a unique nanostructure and microstructure in combination and show superhydrophobicity and a self-cleaning function to wipe and clean impurities on their surfaces. Coating films with combined nanostructures and microstructures resembling those of lotus leaves may also have superhydrophobicity and self-cleaning functions; as a result, they could be used in various applications, such as in outfits, tents, building walls, or exterior surfaces of transportation vehicles like cars, ships, or airplanes. In this study, coating films were prepared by dip coating method using polypropylene polymers dissolved in a mixture of solvent, xylene and non-solvent, methylethylketon, and ethanol. Additionally, attempts were made to prepare nanostructures on top of microstructures by coating with the same coating solution with an addition of carbon nanotubes, or by applying a carbon nanotube over-coat on polymer coating films. Coating films prepared without carbon nanotubes were found to have superhydrophobicity, with a water contact angle of $152^{\circ}$ and sliding angle less than $2^{\circ}$. Coating films prepared with carbon nanotubes were also found to have a similar degree of superhydrophobicity, with a water contact angle of 150 degrees and a sliding angle of 3 degrees.

Effect of Hydrogen Addition on the Conversion of Hydrocarbon Gas to Pyrocarbon Nanoparticles (탄화수소가스 열분해법에 의한 탄소나노입자 생성에 있어서 수소의 영향에 관한 연구)

  • Kim, Soo Hyung
    • Korean Chemical Engineering Research
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    • v.46 no.6
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    • pp.1025-1028
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    • 2008
  • With the assistance of thermal pyrolysis process for hydrocarbon gases, the formation and growth of particulate carbon was systematically investigated as a function of temperature in the gas phase. The yield and average size of pyrocarbon particles were found to increase with increasing pyrolysis temperature. The difference in the yield of carbon particles generated by pyrolizing acetylene and ethylene gas posed a question about the role of hydrogen in the pyrolysis of hydrocarbon gases. In order to reveal the role of hydrogen, controlled amount of hydrogen was added to the acetylene pyrolysis, and then hydrogen addition was observed to suppress the formation and growth of carbon particles. One can control the size of pyrocarbon particles by controlling the hydrogen gas addition.

Integrated Optical Waveguide Isolator Based Multimode Interference Using Magnetooptic Characteristics (자기 광학적 특성을 이용한 다중 모드 간섭에 기반한 집적 광 도파로 아이솔레이터)

  • Yang, Jeong-Su
    • Journal of the Korean Magnetics Society
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    • v.15 no.2
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    • pp.148-152
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    • 2005
  • A novel interferometric isolator has been proposed and designed to fabrticate waveguide magnetooptic isolator operating at a wavelength of $1.55{\cal}um$. The device consists of MMI (multimode interference) couplers and has a magnetooptic guiding layer with different layer structure in arms of the inteferometer. The layer structures in the arms of inteferometer are $HfO_2/CeY_2Fe_5O_{12}/NOG$ and $SiO_2/CeY_2Fe_5O_{12}/NOG$, respectively. This configuration give rise to different nonreciprocal phase shift. In consequence, the isolator operates under a unidirectional magnetic field. The optimized structure of the isolator was determined by a 3D beam propagation method.

200 MeV Ag15+ ion beam irradiation induced modifications in spray deposited MoO3 thin films by fluence variation

  • Rathika, R.;Kovendhan, M.;Joseph, D. Paul;Vijayarangamuthu, K.;Kumar, A. Sendil;Venkateswaran, C.;Asokan, K.;Jeyakumar, S. Johnson
    • Nuclear Engineering and Technology
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    • v.51 no.8
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    • pp.1983-1990
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    • 2019
  • Spray deposited Molybdenum trioxide (MoO3) thin film of thickness nearly 379 nm were irradiated with 200 MeV Ag15+ ion beam at different fluences (Ø) of 5 ×1011, 1 × 1012, 5 × 1012 and 1 × 1013 ions/㎠. The X-ray diffraction (XRD) pattern of the pristine film confirms orthorhombic structure and the crystallinity decreased after irradiation with the fluence of 5 × 1011 ions/㎠ due to irradiation induced defects and became amorphous at higher fluence. In pristine film, Raman modes at 665, 820, 996 cm-1 belong to Mo-O stretching, 286 cm-1 belong to Mo-O bending mode and those below 200 cm-1 are associated with lattice modes. Raman peak intensities decreased upon irradiation and vanished completely for the ion fluence of 5 ×1012 ions/㎠. The percentage of optical transmittance of pristine film was nearly 40%, while for irradiated films it decreased significantly. Red shift was observed for both the direct and indirect band gaps. The pristine film surface had densely packed rod like structures with relatively less porosity. Surface roughness decreased significantly after irradiation. The electrical transport properties were also studied for both the pristine and irradiated films by Hall effect. The results are discussed.

Tailoring the properties of spray deposited V2O5 thin films using swift heavy ion beam irradiation

  • Rathika, R.;Kovendhan, M.;Joseph, D. Paul;Pachaiappan, Rekha;Kumar, A. Sendil;Vijayarangamuthu, K.;Venkateswaran, C.;Asokan, K.;Jeyakumar, S. Johnson
    • Nuclear Engineering and Technology
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    • v.52 no.11
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    • pp.2585-2593
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    • 2020
  • Swift heavy ion (SHI) beam irradiation can generate desirable defects in materials by transferring sufficient energy to the lattice that favours huge possibilities in tailoring of materials. The effect of Ag15+ ion irradiation with energy 200 MeV on spray deposited V2O5 thin films of thickness 253 nm is studied at various ion doses from 5 × 1011 to 1 × 1013 ions/㎠. The XRD results of pristine film confirmed orthorhombic structure of V2O5 and its average crystallite size was found to be 20 nm. The peak at 394 cm-1 in Raman spectra confirmed O-V-O bonding of V2O5, whereas 917 cm-1 arise because of distortion in stoichiometry by a loss of oxygen atoms. Raman peaks vanished completely above the ion fluence of 5 × 1012 ions/㎠. Optical studies by UV-Vis spectroscopy shows decrement in transmittance with an increase in ion fluence up to 5 × 1012 ions/㎠. The red shift is observed both in the direct and indirect band gaps until 5 × 1012 ions/㎠. The surface topography of the pristine film revealed sheath like structure with randomly distributed spherical nano-particles. The roughness of film decreased and the density of spherical nanoparticles increased upon irradiation. Irradiation improved the conductivity significantly for fluence 5 × 1011 ions/㎠ due to band gap reduction and grain growth.

Photodissociation Dynamics of C2H4BrCl: Nonadiabatic Dynamics with Intrinsic Cs Symmetry

  • Lee, Kyoung-Seok;Paul, Dababrata;Hong, Ki-Ryong;Cho, Ha-Na;Jung, Kwang-Woo;Kim, Tae-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.2962-2968
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    • 2009
  • The photodissociation dynamics of 1,2-bromochloroethane ($C_2H_4BrCl$) was investigated near 234 nm. A two-dimensional photofragment ion-imaging technique coupled with a [2+1] resonance-enhanced multiphoton ionization scheme was utilized to obtain speed and angular distributions of the nascent Br($^2P_{3/2}$) and Br${\ast}($^2P_{1/2}$) atoms. The total translational energy distributions for the Br and Br${\ast}$ channels were well characterized by Gaussian functions with average translational energies of 100 and 84 kJ/mol, respectively. The recoil anisotropies for the Br and Br${\ast}$ channels were measured to be ${\beta}$ = 0.49 ${\pm}$ 0.05 for Br and 1.55 ${\pm}$ 0.05 for Br${\ast}$. The relative quantum yield for Br${\ast}$ was found to be ${\Phi}_{Br{\ast}}$ = 0.33 ${\pm}$ 0.03. The probability of nonadiabatic transition between A' states was estimated to be 0.46. The relevant nonadiabatic dynamics is discussed in terms of interaction between potential energy surfaces in Cs symmetry.