• Title/Summary/Keyword: nanocomposite materials

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Characterization of Fe-Co Nanocomposite Powders Produced by Chemical Vapor Condensation Methods (화학기상응축법으로 제조한 Fe-Co 나노복합 분말의 미세구조와 자기적 특성)

  • ;Z. H. Wang;;;Z. D. Zhang
    • Journal of Powder Materials
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    • v.9 no.5
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    • pp.322-328
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    • 2002
  • Fe-Co nanocomposite powders with different composition were prepared by chemical vapor condensation (CVC) process and their characterizations were studied by means of X-ray diffraction, transmission electron microscopy, and vibrating sample magnetometer. The particles having the mean size of 5~25 nm consisted of metallic cores and oxide shells. The Co contents and particle size increased with increasing the carrier gas flow rate of Co precursor. The saturation magnetization and coercivity increased with increasing Co content. and the saturation magnetization maximized at the 40 wt.%Co. The Fe-Co nanocomposite powder oxidized at $400^{\circ}C$ showed the maximum coercivity of 1739 Oe.

Electrical Contact Property of W-Cu Materials Manufactured from Nanocomposite Powder (초미립 복합분말로 제조된 W-Cu재료의 전기접점 특성)

  • 김태형
    • Journal of Powder Materials
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    • v.1 no.2
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    • pp.174-180
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    • 1994
  • Electrical contact property of the W-20wt%Cu contact materials manufactured by liquid phase sintering of nanocomposite W-Cu powders was investigated and discussed in terms of microstructural development during performance test. Nanocomposite powders were prepared by hydrogen reduction of ball milled W-Cu oxide mixture. They underwent complete densification and microstructural homogenization during liquid phase sintering. As a consequence, the W-Cu contacts produced from nanocomposite powders showed superior contact property of lower arc erosion and stable contact resistance. This might be mostly due to the fact that the arc erosion by evaporation of Cu liquid droplets and surface cracking remarkably became weakened. It is concluded that the improvement of anti-arc erosion of the composite specimen is basically attributed to microstructural homogeneity.

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Effect of Plating Parameters on the Electrodeposition of Ni-alumina Nanocomposite

  • Gyawalia, Gobinda;Woo, Dong-Jin;Lee, Soo-Wohn
    • Journal of the Korean institute of surface engineering
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    • v.43 no.4
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    • pp.165-169
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    • 2010
  • $Ni-Al_2O_3$ nanocomposite coatings were fabricated by conventional electrodeposition technique using nickel sulfamate bath. Effect of plating parameters on electrodeposition of $Ni-Al_2O_3$ nanocomposite were studied. The properties of the nano composite were investigated by using SEM, XRD, and Vicker's microhardness test. The results demonstrated that $Al_2O_3$ incorporation in the composite coatings was found to be increased by increasing stir rate and $Al_2O_3$ content in plating bath. Microhardness of the composite coatings was also increased with increasing content of the nano particles in the plating bath. The surface morphologies of the nanocomposite coatings were found to be varied with varying pH, current densities as well as alumina content in the plating bath.

Electrical Conduction and Dielectric Properties of Epoxy/Organophilic Clay Nanocomposite

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.1
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    • pp.43-46
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    • 2013
  • In order to develop electrical insulation material, organically modified layered silicate was incorporated into an epoxy matrix to prepare nanocomposite. Transmission electron microscopy (TEM) observation showed that organophillic clay was in an exfoliated state, while hydrophilic clay was not dispersed into nanolayers within the epoxy matrix. Epoxy/organophilic clay (2.8 wt%) nanocomposite was mixed and cured at $150^{\circ}C$ for 4.5 hr. I-V characteristics, volume resistance and dielectric properties for the cured nanocomposite were estimated. Current density increased with increasing temperature, and volume resistance decreased with increasing temperature, in neat epoxy and epoxy/organophilic clay (2.8 wt%) nanocomposite. As frequency increased, the dielectric loss value decreased in the two systems.

Flexible and Transparent Reduced Graphene Oxide Nanocomposite Field-Effect Transistor for Temperature Sensing

  • Tran, QuangTrung;Ramasundaram, Subramanian;Hong, Seok Won;Lee, Nae-Eung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.387.1-387.1
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    • 2014
  • A new class of temperature-sensing materials is demonstrated along with their integration into transparent and flexible field-effect transistor (FET) temperature sensors with high thermal responsivity, stability, and reproducibility. The novelty of this particular type of temperature sensor is the incorporation of an R-GO/P(VDF-TrFE) nanocomposite channel as a sensing layer that is highly responsive to temperature, and is optically transparent and mechanically flexible. Furthermore, the nanocomposite sensing layer is easily coated onto flexible substrates for the fabrication of transparent and flexible FETs using a simple spin-coating method. The transparent and flexible nanocomposite FETs are capable of detecting an extremely small temperature change as small as $0.1^{\circ}C$ and are highly responsive to human body temperature. Temperature responsivity and optical transmittance of transparent nanocomposite FETs were adjustable and tuneable by changing the thickness and R-GO concentration of the nanocomposite.

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Simulation and Modeling of Polyethylene/Clay Nanocomposite for Dielectric Application

  • Zazoum, Bouchaib;David, Eric;Ngo, Anh Dung
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.4
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    • pp.175-181
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    • 2014
  • In this paper, the simulation and modeling of a polyethylene/clay nanocomposite were undertaken to predict the nanocomposite's dielectric behavior and to help design a nanocomposite material with optimum electrical properties for electrotechnical or electronic applications. A 3-D simulation model using the finite elements method was employed in order to study the effective permittivity and electric field distribution of two-phase nanocomposite materials for ordered and random distributions of inclusions in a low-loss host matrix such as polyethylene. The influence of the dispersion of reinforcing particles, and of the permittivity and radius of the inclusions, was analysed. The simulation results were compared with alternative, known theoretical solutions obtained from classical models, and were found to be in good agreement. The numerical results also indicate that for fixed volume fractions of nanoparticles the effective permittivity of the mixture, for ordered and random distributions, does not vary with the degree of dispersion. The variation of the effective permittivity with the particle radius is shown, using numerical data, to agree with the analytical modules.

Preparation and Properties of Fireproofing Polyolefin Compound Using Nano Clay (Nano Clay를 이용한 난연성 Polyolefin Compound의 제조 및 특성에 관한 연구)

  • Kang, Doo-Whan;Huh, June
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.2
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    • pp.165-172
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    • 2003
  • Fireproofing polyolefin nanocomposite for the application of power distributing panel was prepared by compounding linear low density polyethylene(LLDPE), decabromodiphenyl oxide (DBDPO), $Sb_2O_3$ as flame retardant agents, and modified nano clay as filler. The optimized formulation ratio of compounds to prepare the fireproofing polyolefin nanocomposite was obtained. The flame retardant properties for nanocomposite prepared by compounding 22.5 phr of nano clay and 18 phr of DBDPO based on 100 phr of LLDPE were shown that the combustion time. 10${\sim}$18 s, combustion distance, 12${\sim}$15 mm and non-melt dropping characteristics. In particular. the content of DBDPO in nanocomposite could be decreased to 18 phr from 40 phr DBDPO for fireproofing composite containing 30 phr of clay. The electrical properties measured from tracking test, had an excellent antitracking properties by not showing the phenomenon of leakage current and sparking.

Electrical Characteristics and Fabrication of CNT/Cu Nanocomposite (CNT/Cu 나노복합체의 제조 및 전기적 특성평가)

  • Hong, Youn-Jeong;Kim, Hye-Jin;Lee, Kyu-Mann;Kim, In-Woo
    • Journal of the Semiconductor & Display Technology
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    • v.6 no.4
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    • pp.59-63
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    • 2007
  • The CNTs are the most extensively studied material which are characterized by the complete property of matter, structure, and the large thermal conductivity (thermal conductivity of CNTs ~>2000W/mK vs. thermal conductivity of Aluminum ~> 204W/mK). Thus, they are successfully applied to the various fields. However, due to the strong agglomeration caused by the van der waal's force, their applications are limited. In the present study, a new method for CNTs dispersion was developed by using the mechanical dispersion, acid treatment, and then Cu was coated. This process produces CNTs/Cu nanocomposite powders, whereby the CNTs are homogeneously located within the Cu powders. The electrical properties of the CNTs/Cu nanocomposite were investigated.

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Synthesis of Si Nanowire/Multiwalled Carbon Nanotube Core-Shell Nanocomposites (실리콘 나노선/다중벽 탄소나노튜브 Core-Shell나노복합체의 합성)

  • Kim, Sung-Won;Lee, Hyun-Ju;Kim, Jun-Hee;Son, Chang-Sik;Kim, Dong-Hwan
    • Korean Journal of Materials Research
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    • v.20 no.1
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    • pp.25-30
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    • 2010
  • Si nanowire/multiwalled carbon nanotube nanocomposite arrays were synthesized. Vertically aligned Si nanowire arrays were fabricated by Ag nanodendrite-assisted wet chemical etching of n-type wafers using $HF/AgNO_3$ solution. The composite structure was synthesized by formation of a sheath of carbon multilayers on a Si nanowire template surface through a thermal CVD process under various conditions. The results of Raman spectroscopy, scanning electron microscopy, and high resolution transmission electron microcopy demonstrate that the obtained nanocomposite has a Si nanowire core/carbon nanotube shell structure. The remarkable feature of the proposed method is that the vertically aligned Si nanowire was encapsulated with a multiwalled carbon nanotube without metal catalysts, which is important for nanodevice fabrication. It can be expected that the introduction of Si nanowires into multiwalled carbon nanotubes may significantly alter their electronic and mechanical properties, and may even result in some unexpected material properties. The proposed method possesses great potential for fabricating other semiconductor/CNT nanocomposites.

The Effect of Composition on Hydrogen Reduction Behavior of Ball-milled WO3-CuO Nanocomposite Powders (볼밀링한 WO3-CuO 나노복합분말의 조성에 따른 수소환원 거동)

  • Jung Sung-Soo;Kang Yun-Sung;Lee Jai-Sung
    • Journal of Powder Materials
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    • v.13 no.3 s.56
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    • pp.205-210
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    • 2006
  • The effect of Cu content on hydrogen reduction behavior of ball-milled $WO_3$-CuO nanocomposite powders was investigated. Hydrogen reduction behavior and reduction percent(${\alpha}$) of nanopowders were characterized by thermogravimetry (TG) and hygrometry measurements. Activation energy for hydrogen reduction of $WO_3$ nanopowders with different Cu content was calculated at each heating rate and reduction percent(${\alpha}$). The activation energy for reduction of $WO_3$ obtained in this study existed in the ranging from 129 to 139 kJ/mol, which was in accordance with the activation energy for $WO_3$ powder reduction of conventional micron-sized.