• 제목/요약/키워드: nano-composite material

검색결과 379건 처리시간 0.028초

LDPE-나노 TiO2 복합 필름의 기능성 및 재질안정성 평가 (A Study of Functionality and Stability of LDPE-Nano TiO2 Composite Film)

  • 이우석;고성혁
    • 한국포장학회지
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    • 제23권2호
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    • pp.67-74
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    • 2017
  • In this work, the effects of nano $TiO_2$ on functionality and stability of low density polyethylene (LDPE) composite films were investigated for food packaging application. LDPE-nano $TiO_2$ composite films were prepared with various $TiO_2$ contents (0, 0.5, 1.0, 3.0 and 5.0wt%) by melt-extrusion and their basic properties such as crystallinity, chemical bonds and surface morphology were examined by XRD, FTIR and SEM. Ultraviolet (UV) light barrier property of as-prepared LDPE-nano $TiO_2$ composite films was also studied and the presence of nano $TiO_2$ resulted in significant improvement of UV light barrier compared to the pure LDPE film. To evaluate influence of nano $TiO_2$ on LDPE properties required as packaging material, thermal, mechanical, gas barrier and optical properties of LDPE-nano $TiO_2$ composite films were characterized with various analytical techniques including TGA, UTM, OTR, WVTR and UV-vis spectroscopy. As a result, except optical property of LDPE, no significant effects were found in other properties. Opacity of pure LDPE was greatly increased with increasing concentration of nano $TiO_2$.

방호·방폭 보강용 복합섬유 패널 제작을 위한 기초연구 (Basic Study on Fiber Composite Panel Production for Impact·Blast Resistant)

  • Kim, Woonhak;Kang, Seokwon;Yun, Seunggyu
    • 한국재난정보학회 논문집
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    • 제11권2호
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    • pp.235-243
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    • 2015
  • 콘크리트 구조물의 방호 방폭성능을 향상시키기 위한 보강방법으로 배면보강이나 콘크리트 재료의 물성보강에 따른 방법과, 구조 부재나 지지물 등을 추가로 설치하여 저항성능을 향상시키는 방법 등을 고려하였을 때 경제적인 측면과 구조적인 측면에서 효율성이 떨어진다. 본 논문에서는 패널의 각 단층 구성 재료에 고인장, 경량화, 부착성능, 내화성능 등을 향상시켜 단층 각각의 개별적인 특수 성능과 복합패널 구성물로서의 방호방폭 성능을 극대화 할 수 있는 섬유복합패널 외피와 충전제로서 나노복합소재 및 접착제에 대한 기초 연구를 수행하였다. 그 결과 섬유복합패널 외피(아라미드-폴리에스터 비 6:4, 6.5:3.5)의 최대 인장강도 2,348MPa, 최대 신율 1.8%의 값을 얻었고, 나노복합소재와 접착제를 혼합한 충전제의 최대 인장전단접착강도 4MPa을 얻었다. 또한 나노복합소재로 제작한 충전제는 보통포틀랜드시멘트의 30%의 경량화의 결과를 얻었다.

Removal of BP-3 Endocrine Disrupting Chemical (EDC) using cellulose acetate and ZnOnano particles mixed matrix membranes

  • Rajesha, B.J.;Chandan, H.R.;Sunil, K.;Padaki, Mahesh;Balakrishna, Geetha R.
    • Membrane and Water Treatment
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    • 제7권6호
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    • pp.507-520
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    • 2016
  • The effect of ZnO on cellulose acetate in the removal of benzophenone-3 (BP-3) was investigated. The benzophenone-3 (BP-3) which is an endocrine disrupting chemical (EDC) was completely removed (100%) from the drinking water using Cellulose Acetate (CA) and zinc oxide (ZnO) composite membranes. The membranes were prepared by DIPS method and the filtration experiments were conducted by dead end filtration unit. The macrostructure of the membrane were studied by ATR-IR and XRD Spectra's. Atomic force microscopy (AFM) and Scanning electron microscopy (SEM) were used to study the micro properties of the membranes. The laboratory experiments such as water uptake study and pure water flux performed to confirm the increasing hydrophilicity. The enhancing hydrophilicity was confirmed with respect to higher the concentration of nanoparticles. Evaluation of BP-3 removal was carried in different experimental conditions, such as, different Trans membrane pressure and different concentration of feed. The membrane with low pressure showed better performance by rejecting 100% of BP-3. However, 1 ppm, 3 ppm and 6 ppm of feed solution was used and among them 3 ppm of feed solution gives 100% rejection. The ZnO nanoparticales enhances the performance of CA membrane by showing maximum rejection.

Spectroscopic and Mechanical Properties of Nano Silica Rubber Composite Material

  • Lee, Jung Kyu;Park, Juyun;Kang, Yong-Cheol;Koh, Sung Wi
    • 통합자연과학논문집
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    • 제9권1호
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    • pp.62-66
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    • 2016
  • To manipulate the mechanical properties of acrylonitrile butadiene rubber (NBR), addition of nano-sized silica on rubber was performed and nano-silica NBR composite (NSR) materials were fabricated by press molding. The effect of volume fraction of silica in the NSR on the spectroscopic and mechanical properties has been studied.

An exact solution for mechanical behavior of BFRP Nano-thin films embedded in NEMS

  • Altabey, Wael A.
    • Advances in nano research
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    • 제5권4호
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    • pp.337-357
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    • 2017
  • Knowledge of thin films mechanical properties is strongly associated to the reliability and the performances of Nano Electro Mechanical Systems (NEMS). In the literature, there are several methods for micro materials characterization. Bulge test is an established nondestructive technique for studying the mechanical properties of thin films. This study improve the performances of NEMS by investigating the mechanical behavior of Nano rectangular thin film (NRTF) made of new material embedded in Nano Electro Mechanical Systems (NEMS) by developing the bulge test technique. The NRTF built from adhesively-bonded layers of basalt fiber reinforced polymer (BFRP) laminate composite materials in Nano size at room temperature and were used for plane-strain bulging. The NRTF is first pre-stressed to ensure that is no initial deflection before applied the loads on NRTF and then clamped between two plates. A differential pressure is applying to a deformation of the laminated composite NRTF. This makes the plane-strain bulge test idea for studying the mechanical behavior of laminated composite NRTF in both the elastic and plastic regimes. An exact solution of governing equations for symmetric cross-ply BFRP laminated composite NRTF was established with taking in-to account the effect of the residual strength from pre-stressed loading. The stress-strain relationship of the BFRP laminated composite NRTF was determined by hydraulic bulging test. The NRTF thickness gradation in different points of hemisphere formed in bulge test was analysed.

탄소 나노 재료 기반의 전기-화학적 구동기 (Nano Carbon Material Based Electrochemical Actuators)

  • 차주영;강인필
    • 한국정밀공학회지
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    • 제28권11호
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    • pp.1251-1258
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    • 2011
  • With the help of nanoscale materials like carbon nanotube (CNT), there is the potential to develop new actuators that will provide higher work per cycle than previous actuator technologies, and generate much higher mechanical strength. In this study, the electrochemical actuation characteristics of nano carbon materials were experimentally studied to develop electrochemical actuators. The electrochemical actuators were composed of aqueous NaCl electrolyte and their actuating electrodes were made of multi-walled carbon nanotube (MWCNT)/polystyrene composite and graphene respectably. Actuation is proportional to charging transfer rate, and the electrolysis with an AC voltage input has very complex characteristics. To quantify the actuation property, the strain responses and output model were studied based on electrochemical effects between the nano carbon films and the electrolyte.

Preparation and Characterization of Sulfated TiO2/zeolite Composite Catalysts with Enhanced Photocatalytic Activity

  • Zhao, Yuan;Li, JingXiu;Wang, Ling;Hao, Yanan;Yang, Lin;He, Pingting;Xue, JianJun
    • Nano
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    • 제13권10호
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    • pp.1850117.1-1850117.11
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    • 2018
  • Sulfated $TiO_2$ nanoparticles were successfully immobilized on zeolite through improving hydrolysis-deposition method. Microstructure, crystallization, surface state and surface area of composite catalysts were characterized by SEM, XRD, FTIR spectra, XPS and BET and the photocatalytic activity was evaluated by degradation of methyl orange under UV irradiation. We optimized these factors ($SO^{2-}_4$ ions, calcination temperature and loading amount of sulfated $TiO_2$) on photocatalytic activity and crystallization of composite photocatalysts. The results indicated that the $SO^{2-}_4$ ions are successfully immobilized on the surface of $TiO_2$, and sulfated $TiO_2$/zeolite show the highest photocatalytic activity for methyl orange at the $[SO^{2-}_4 ]/[Ti^{4+}]$ molar rate of 1:1, calcination temperature of $600^{\circ}C$ for 2 h, and sulfated $TiO_2$ loading amount of 40%, respectively.

Strain gradient based static stability analysis of composite crystalline shell structures having porosities

  • Fenjan, Raad M.;Faleh, Nadhim M.;Ridha, Ahmed A.
    • Steel and Composite Structures
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    • 재36권6호
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    • pp.631-642
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    • 2020
  • This paper studies nonlinear stability behavior of a nanocrystalline silicon curved nanoshell considering strain gradient size-dependency. Nanocrystallines are composite materials with an interface phase and randomly distributed nano-size grains and pores. Imperfectness of the curved nanoshell has been defined based on an initial deflection. The formulation of nanocrystalline nanoshell has been established by thin shell theory and an analytical approach has been used in order to solve the buckling problem. For accurately describing the size effects related to nano-grains or nano-pores, their surface energies have been included. Nonlinear stability curves of the nanoshell are affected by the size of nano-grain, curvature radius and nano-pore volume fraction. It is found that increasing the nano-pore volume fraction results in lower buckling loads.

치과 CAD/CAM용 복합소재를 이용한 치과보철물의 제작에 대한 연구 (A Study on Hybrid material of Making Dental restorations by CAD/CAM System)

  • 최범진
    • 대한심미치과학회지
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    • 제23권2호
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    • pp.86-94
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    • 2014
  • In recent years, perhaps the biggest driver in new material development is the desire to improve crown and bridge esthetics compared to the traditional PFM or all-metal restorations. As such, zirconia, leucite-containing glass ceramic and lithium disilicate glass ceramic have become prominent in the dental practice. Each material type performs differently regarding strength, toughness, ease of machining and the final preparation of the material prior to placement. For example, glass ceramic are typically weaker materials which limits its use to single-unit restorations. On the other hand, zirconia has a high fracture toughness which enables multi-unit restorations. This material requires a long sintering procedure which excludes its use for fast chair side production. Developed hybrid material of CAD/CAM is contained nano ceramic elements. This new material, called a Resin Nano Ceramic is unique in durability and function. The material is not a resin or composite. It is also not a pure ceramic. The material is a mixture of both and consists of ceramic. Like a composite, the material is not brittle and is fracture resistant. Like a glass ceramic, the material has excellent polish retention for lasting esthetics. The material is easily machined chair side or in a dental lab, polishes quickly to an esthetic finish and if necessary, can be useful restoratives.