• Title/Summary/Keyword: nano-calcite

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Lateral Resolution Enhancement in Confocal Self-interference Microscopy with Commercial Calcite Plate

  • Kang DongKyun;Yoo HongKi;Lee SeungWoo;Gweon Dae-Gab
    • Journal of the Optical Society of Korea
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    • v.9 no.1
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    • pp.32-35
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    • 2005
  • In light microscopy, spatial resolution is limited by diffraction effect. Confocal microscopy has improved resolutions in both lateral and axial directions, but these are still limited by diffraction effect. Confocal self-interference microscopy (CSIM) uses interference between two perpendicularly polarized beams to enhance lateral resolution. In previous research, we proposed a calcite plate with its optic-axis perpendicular to the propagation angle and one of the boundary surfaces of the plate. This type of plate is not widely used to our knowledge. In this paper, we change the calcite plate to more common one, which is commercially available. This calcite plate has its optic axis in the plane of incidence. We analyze the characteristics of this calcite plate and numerically compare the performances of CSIM in previous research and CSIM with the commercial calcite plate. Numerical results show improved performance when using the commercial calcite plate

Assessment of the Mechanical Performance of Nano-Silica and Nano-Calcite Incorporated Limestone Calcined Clay Cement (LC3) Paste (나노실리카와 나노칼사이트 혼입 석회석 소성 점토 시멘트(LC3) 페이스트의 기계적 성능 평가)

  • Kim, Gyeong-Ryul;Cho, Seong-Min;Bae, Sung-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.151-152
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    • 2023
  • This study investigates the effect of nano-silica and nano-calcite on the hydration properties and mechanical performance of limestone calcined clay cement (LC3) paste. The pastes were synthesized by replacing limestone with nano-silica and nano-calcite in order to enhance the mechanical properties in both early and late stages of hydration. The nano-calcite enhanced the strength of LC3 pastes at 1 day of hydration, however, the strength decreased compared to the ordinary LC3 pastes afterwards due to excessive amount of carboaluminate produced in the pastes. On the other hand, nano-silica improved the mechanical properties of LC3 pastes at all ages of hydration. This is mainly due to the nucleation effect and pozzolanic reaction of nano-silica, affecting the early age and late ages of hydration, respectively. The nucleation effect of both nanomaterials were confirmed by the analysis of hydration heat, supporting the enhanced early age strength of nanomaterial incorporated LC3 pastes. Furthermore, the dense matrix was shown in the pore size distribution, and the increased C-S-H due to the pozzolanic reaction evidence the improved compressive and splitting tensile strength of nano-silica incorporated LC3 pastes.

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Accelerated Aging of Electric Arc Funace Slag with CO2 Nano Bubble by X-Ray Diffraction (X-선 회절 분석을 통한 CO2 나노버블수 침지 전기로 슬래그 촉진 에이징 검토)

  • Lim, Chang-Min;Im, Geon-Woo;Kim, Young-Min;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.61-62
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    • 2023
  • In this study, the steel slag was immersed in CO2 nano-bubble water by Electric arc funace it was accelerated aging was reviewed through XRD analysis. The main minerals of the electric furnace oxidized slag were spinel and gehlenite, and there was no change with the number of CO2 nano-bubbles. Minerals such as larnite, calcio-olivine, agnetite, calcite, and spinel were distributed in electrically reduced slag, and the content of calcite more than doubled with CO2 nano-bubble immersion. Therefore, it is judged that the acceleration aging of Electric arc funace reduced slag is effective according to the immersion of CO2 nano-bubble.

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Nanosized Calcite in the Chinese Loess (중국 뢰스의 나노 방해석)

  • Jeong, Gi-Young
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.4
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    • pp.255-260
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    • 2007
  • The loess on the Chinese loess plateau is not only the accumulation of Asian dust but also the source materials of Hwangsa. The eolian carbonates of the loess were dissolved and reprecipitated to form secondary pedogenic carbonates by the post-depositional weathering during the interglacial time. Mineralogical analysis shows that the secondary calcites are composed mostly of a nanosized fibrous calcite with rather constant width ($30{\sim}50nm$) and highly variable length. The nano calcite is the major authigenic mineral, which occurs as the fine-grained matrix of the loess and paleosol. The nano calcite was recently reported in the Hwangsa, where it was originated from the source regions of Chinese loess plateau.

Grinding Kinetics of Calcite, Pyrophyllite and Talc During Stirred Ball Milling - Consideration of Selection Function (교반 볼밀에 의한 방해석, 납석, 활석의 분쇄 시 분쇄속도론에 관한 연구 - 선택함수의 고찰)

  • Choi, Hee-Kyu;Kim, Seong-Soo;Hwang, Jin-Yeon
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.135-145
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    • 2007
  • The needs for the ultra fine particles have been increased in preparation field of raw powders such as fine ceramics and high functional products. In this study, a series of wet grinding experiments were carried out on inorganic powders such as calcite, pyrophyllite and talc by a stirred ball mill. The particle size distribution of ground products of each test material fur a given grinding time was found to be expressed by the grinding rate (selection function) which was obtained from the grinding kinetics analysis. The median diameter decreased from 6.49 to $0.47{\mu}m$ in calcite, and decreased from 3.91 to $1.14{\mu}m$ in pyrophyllite. However, in talc, median diameter was decreased a little bit from 10.30 to $6.67{\mu}m$. The grinding rate changing on calcite and pyriphyllite were similar at the same conditions. However, in the case of talc, it was observed that the grinding rate was not increased compared to other samples.

Evaluation of Solid Surface Properties by Analysis of Liquid Penetration Rate into Powder Beds (분체층 내 액체 침투속도 해석에 의한 분체 표면성질의 평가)

  • Ha, Jong-Hak;Kim, Seong-Soo;Wang, Lin;Choi, Hee-Kyu
    • Korean Journal of Materials Research
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    • v.18 no.3
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    • pp.128-136
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    • 2008
  • Evaluation of the solid surface properties by an analysis of the liquid penetration rate into powder beds is very important in applications of powder products. The penetration rate is related the surface property in powder beds. In order to analyze the surface property of powders, the contact angle values of several powders were obtained using the Washbun equation and the Wicking method. The surface free energy value ${\gamma}S$ was divided into a polar component ${\gamma}S^p$ and a dispersion component ${\gamma}S^d$. Inorganic powders such as calcite were used as test samples. The effects of the particle size and the type of experimental liquid on the penetration rate were measured. It was confirmed that the surface free energy of the grinding sample is smaller than that of the classification sample.

High-pressure synchrotron X-ray diffraction study of tremolite and actinolite in various fluids

  • Kong, Mihye;Vogt, Thomas;Lee, Yongjae
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1218-1224
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    • 2018
  • Pressure-dependent structural and morphological changes of two amphibole minerals, tremolite and actinolite, were investigated up to 7.0 GPa using synchrotron X-ray powder diffraction underthree different pressure transmission media (PTM): water (W), $CO_2$ and silicone oil (SI). The elastic response of tremolite and actinolite are found to be dependent on the PTM used. When using water (W) as PTM, tremolite and actinolite show normal volume contractions with bulk moduli of 74(1) and 78(1) GPa, respectively. When using $CO_2$ as PTM, we observe the formation of calcite from tremolite above 3.8(1) GPa, whereas actinolite did not show any carbonation reaction. Under silicone oil PTM, we observe modulated volume contraction behaviors in both samples, compared to water and $CO_2$ PTM, with bulk moduli in the order of 90(1) and 94(4) GPa for tremolite and actinolite, respectively.

Chemical Properties of Converter Slag according to CO2 Nanobubble Acceleration Aging Time (CO2 나노버블 에이징 시간에 따른 전로슬래그의 화학적 특성)

  • Lim, Chang-Min;Im, Geon-Woo;Kim, Young-Min;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.91-92
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    • 2023
  • In this study, the chemical composition of converter slag according to CO2 nanobubble promotion aging time was examined. The CO2 nanobubble water immersion time was 0, 12, 24, 36, 48 hours, and then dried and pulverized to perform XRD analysis. As a result, the longer the sample was immersed in CO2 nanobubble water, the higher the amount of calcite produced, and the change after 36 hours was minimal.

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