• Title/Summary/Keyword: nano materials

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One-step liquid-phase fabrication of adhesive and protective inorganic layer for carbon nanotube field emitters

  • Jeong, Hae-Deuk;Kim, Ho-Young;Jeong, Hee-Jin;Jeong, Seung-Yol;Han, Joong-Tark;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03b
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    • pp.43-43
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    • 2010
  • we have investigated the field emission characteristics of the CNT/TEOS hybrid thin films fabricated by a spray method. It is found that the CNT/TEOS hybrid emitters show high current density, low turn on field, and long-term emission stability compared to the CNT emitters. These efficient field emission characteristics of the CNT/TEOS hybrid emitters are attributed to the TEOS sol, acting as a protection layer of nanotube emitter by surrounding the nanotube tip as well as a binder material to enhance the adhesion of nanotube emitters to the substrate. Therefore, the CNT/TEOS hybrid emitters could be utilized as an alternative for the efficient and reliable field emitters.

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Fabrication and Properties of Porous Ni Thin Films

  • Choi, Sun-Hee;Kim, Woo-Sik;Kim, Sung-Moon;Lee, Jong-Ho;Son, Ji-Won;Kim, Joo-Sun
    • Journal of the Korean Ceramic Society
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    • v.43 no.5 s.288
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    • pp.265-269
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    • 2006
  • We have deposited NiO films by RF sputtering on $Al_2O_3/SiO_2/Si$ and 100 nm-thick Gd doped $CeO_2$ covered $Al_2O_3/SiO_2/Si$ substrates at various $Ar/O_2$ ratios. The deposited films were reduced to form porous Ni thin fllms in 4% $H_2\;at\;400^{\circ}C$. For the films deposited in pure Ar, the reduction was retarded due to the thickness and the orientation of the NiO films. On the other hand, the films deposited in oxygen mixed ambient were reduced and formed porous Ni films after 20 min of reduction. We also investigated the possibility of using the films for the single chamber operation by studying the electrical property of the films in the fuel/air mixed environment. It is shown that the resistance of the Ni film increases quickly in the mixed gas environment and thus further improvements of Ni-base anodes are required for using them in the single chamber operation.

Aging Effect of Bio-inspired Artificial Basilar Membrane with Piezoelectric PVDF Thin Film

  • Kim, Wan Doo;Park, Su A;Kim, Sang Won;Kwak, Jun-Hyuk;Jung, Young Do;Hur, Shin
    • Elastomers and Composites
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    • v.50 no.4
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    • pp.292-296
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    • 2015
  • Biomimetic artificial basilar membrane being a core part of artificial cochlear requires performance evaluation through aging test. To evaluate the aging properties of PVDF piezoelectric membrane used for artificial basilar membrane, its mechanical properties such as tensile strength and elastic modulus and piezoelectric property such as piezoelectric constant were measured. The aging test conditions and acceleration constants were calculated based on Arrhenius model. The changes in tensile strengths and elastic moduli measured were less than 10~20% after aging test equivalent for 10 years. The piezoelectric constants were decreased drastically to 80% of its initial value in the early stage of the aging test and expected to decrease slowly down to 65% over 10 years. The experimental results show the reliability of totally implantable novel artificial cochlear and will contribute its commercialization.

Nano-porous Silicon Microcavity Sensors for Determination of Organic Fuel Mixtures

  • Pham, Van Hoi;Bui, Huy;Hoang, Le Ha;Nguyen, Thuy Van;Nguyen, The Anh;Pham, Thanh Son;Ngo, Quang Minh
    • Journal of the Optical Society of Korea
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    • v.17 no.5
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    • pp.423-427
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    • 2013
  • We present the preparation and characteristics of liquid-phase sensors based on nano-porous silicon multilayer structures for determination of organic content in gasoline. The principle of the sensor is a determination of the cavity-resonant wavelength shift caused by refractive index change of the nano-porous silicon multilayer cavity due to the interaction with liquids. We use the transfer matrix method (TMM) for the design and prediction of characteristics of microcavity sensors based on nano-porous silicon multilayer structures. The preparation process of the nano-porous silicon microcavity is based on electrochemical etching of single-crystal silicon substrates, which can exactly control the porosity and thickness of the porous silicon layers. The basic characteristics of sensors obtained by experimental measurements of the different liquids with known refractive indices are in good agreement with simulation calculations. The reversibility of liquid-phase sensors is confirmed by fast complete evaporation of organic solvents using a low vacuum pump. The nano-porous silicon microcavity sensors can be used to determine different kinds of organic fuel mixtures such as bio-fuel (E5), A92 added ethanol and methanol of different concentrations up to 15%.

A Study on Fire-Resistant Improvement of Concrete with nano size materials (나노소재를 이용한 콘크리트의 내화성능향상 연구)

  • Jo, Byung-Wan;Park, Jong-Bin;Choi, Hae-Yun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.481-484
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    • 2005
  • Recently, Since the advanced nano technology develops unique physical and chemical properties different from those of the conventional materials. Normal concretes mixed with nano size materials have been studied to improve the fire-resistance with high strength and lower heat conductivity. In this pilot study, the nano-particle contents in the specimens ($\Phi$10\times20 cm$) were 0, 2, 4, and 6$\%$ by weight of cement, and fire-temperatures 800$^{circ}C$ was considered. The results show that as the nano-particle contents increases, fire resistance of concrete are superior to those of the ordinary concrete. Also, the experimental results show that fire resistance of nano Aluminum hydroxide dispersed concrete are superior to those of the nano-SiO2 concrete.

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The Fabrication of Implant Core Coated with Ti Balls (Ti ball이 coating된 임플란트 core의 제조)

  • Choi, D.J.;Park, D.G.;Park, S.B.;Park, S.S.;Turaev, F.R.;Roh, J.S.;Kim, S.J.;Woo, H.S.;Kim, S.E.;Lee, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.21 no.2
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    • pp.94-100
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    • 2008
  • The implant prototypes with various porosities were fabricated by Spark Plasma Sintering of atomized spherical titanium balls. The interface was observed by optical microscope. Sintering temperature and holding time were selected at the point of big change of Z-axis ratio during sintering. These experiments show that Spark Plasma Sintering of spherical titanium balls can be efficiently used to produce implants surfaced with titanium balls with various porosities in a short time less than 120 seconds by manipulating the current condition such as z-axis, temperature and balls size.

Synthesis of Nano Sized Cobalt Powder from Cobalt Sulfate Heptahydrate by Liquid Phase Reduction (액상환원공정을 이용한 황산코발트로부터의 코발트 나노분말 합성)

  • An, Se-Hwan;Kim, Se-Hoon;Lee, Jin-Ho;Hong, Hyun-Seon;Kim, Young-Do
    • Korean Journal of Materials Research
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    • v.21 no.6
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    • pp.327-333
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    • 2011
  • Nanostructured cobalt materials have recently attracted considerable attention due to their potential applications in high-density data storage, magnetic separation and heterogeneous catalysts. The size as well as the morphology at the nano scale strongly influences the physical and chemical properties of cobalt nano materials. In this study, cobalt nano particles synthesized by a a polyol process, which is a liquid-phase reduction method, were investigated. Cobalt hydroxide ($Co(OH)_2$), as an intermediate reaction product, was synthesized by the reaction between cobalt sulphate heptahydrate ($CoSO_4{\cdot}7H_2O$) used as a precursor and sodium hydroxide (NaOH) dissolved in DI water. As-synthesized $Co(OH)_2$ was washed and filtered several times with DI water, because intermediate reaction products had not only $Co(OH)_2$ but also sodium sulphate ($Na_2SO_4$), as an impurity. Then the cobalt powder was synthesized by diethylene glycol (DEG), as a reduction agent, with various temperatures and times. Polyvinylpyrrolidone (PVP), as a capping agent, was also added to control agglomeration and dispersion of the cobalt nano particles. The optimized synthesis condition was achieved at $220^{\circ}C$ for 4 hours with 0.6 of the PVP/$Co(OH)_2$ molar ratio. Consequently, it was confirmed that the synthesized nano sized cobalt particles had a face centered cubic (fcc) structure and with a size range of 100-200 nm.

Friction Behavior of High Velocity Oxygen Fuel (HVOF) Thermal Spray Coating Layer of Nano WC-Co Powder

  • Cho, T.Y.;Yoon, J.H.;Kim, K.S.;Fang, W.;Joo, Y.K.;Song, K.O.;Youn, S.J.;Hwang, S.Y.;Chun, H.G.
    • Journal of the Korean institute of surface engineering
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    • v.40 no.4
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    • pp.170-174
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    • 2007
  • High Velocity Oxygen Fuel (HVOF) thermal spray coating of nano size WC-Co powder (nWC-Co) has been studied as one of the most promising candidate for the possible replacement of the traditional hard plating in some area which causes environmental and health problems. nWC-Co powder was coated on Inconel 718 substrates by HVOF technique. The optimal coating process obtained from the best surface properties such as hardness and porosity is the process of oxygen flow rate (FR) 38 FMR, hydrogen FR 57 FMR and feed rate 35 g/min at spray distance 6 inch for both surface temperature $25^{\circ}C\;and\;500^{\circ}C$. In coating process a small portion of hard WC decomposes to less hard $W_2C$, W and C at the temperature higher than its decomposition temperature $1,250^{\circ}C$ resulting in hardness decrease and porosity increase. Friction coefficient increases with increasing coating surface temperature from 0.55-0.64 at $25^{\circ}C$ to 0.65-0.76 at $500^{\circ}C$ due to the increase of adhesion between coating and counter sliding surface. Hardness of nWC-Co is higher or comparable to those of other hard coatings, such as $Al_2O_3,\;Cr,\;Cr_2O_3$ and HVOF Tribaloy 400 (T400). This shows that nWC-Co is recommendable for durability improvement coating on machine components such as high speed spindle.

Pt nanoparticles-coated Carbon nanofiber for FED application

  • Lee, Won-Woo;Choi, Young-Min;Ryu, Beyong-Hwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1590-1592
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    • 2007
  • In this study, we prepared CNF (carbon nanofiber) by the solvothermal method for FED (field emission display) applications. We controlled several conditions to synthesize effective CNF for field emission applications. Nano-sizesd Pt nanoparticles were coated on the CNF. In this study, we have applied Pt nanoparticles- coated CNF which can be produced in mass, to field emission application.

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Permittivities of the Carbon Nano Fiber/Epoxy Composite According to the Dispersion Methods (분산 방법에 따른 카본 나노 섬유/에폭시 복합재료의 유전율)

  • 김태욱;김진봉;공진우;정재한;김준현
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.55-58
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    • 2003
  • This paper presents a study on the permittivities of the carbon nano fiber/epoxy composite at microwave frequency. The permittivities of composite materials depend on the concentrations and the dispersion methods of the carbon nano fibers. The experimental values of complex permittivities were obtained for the specimen made by dispersion method using ethyl alcohol as dispersion media and compared with the results by simple mechanical mixing method.

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