• 제목/요약/키워드: nano composites

검색결과 648건 처리시간 0.024초

Effect of CNT Diameter on Physical Properties of Styrene-Butadiene Rubber Nanocomposites

  • Park, Young-Soo;Huh, Mong-Young;Kang, Sin-Jae;Yun, Seok-Il;Ahn, Kay-Hyeok
    • Carbon letters
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    • 제10권4호
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    • pp.320-324
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    • 2009
  • We investigated the effect of diameter and content of carbon nanotubes (CNTs) on the physical properties of styrenebutadiene rubber (SBR)/CNTs nanocomposites. CNTs-reinforced SBR nanocomposites were prepared by the melt mixing process. CNTs with different diameters were synthesized by the chemical vapor deposition method (CVD). In this work, the mechanical property and other physical properties of SBR/CNTS nanocomposites were discussed as a function of the content and diameter of CNTs.

와이블 통계를 이용한 나노컴퍼지트 파괴강도의 평가 (Estimation of Breakdown Properties in Nano-composites using Weibull Statistics)

  • 이강원;이혁진;박희두;김종환;신종열;이충호;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.285-286
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    • 2008
  • Recently, epoxy based nano-composites are being increasingly investigated for their electrical properties, since the introduction of nano fillers demonstrate several advantages in their properties when compared with the similar properties obtained for epoxy systems with micrometer sized fillers. We calculated scale and shape parameter using dielectric strength. In this paper, it is investigated that the allowable' breakdown probability of specimens is stable at some value using Weibull statistics. Therefore we found that breakdown probability of specimens is stable until 20 [%].

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NITE-SiC 복합재료의 미세구조 특성에 미치는 섬유배열방향 영향 (Effects of Fiber Arrangement Direction on Microstructure Characteristics of NITE-SiC Composites)

  • 이영주;윤한기;박준수
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2006년 창립20주년기념 정기학술대회 및 국제워크샵
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    • pp.158-161
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    • 2006
  • SiC materials have been extensively studied for high temperature components in advanced energy conversion system and advanced gas turbine. However, the brittle characteristics of SiC such as law fracture toughness and law strain-to fracture impose a severe limitation on the practical applications of SiC materials. SiC/SiC composites can be considered as a promising candidate in various structural materials, because of their good fracture toughness. In this composite system, the direction of SiC fiber will give an effect to the mechanical properties. It is therefore important to control a properdirection of SiC fiber for the fabrication of high performance SiC/SiC composites. In this study, unidirection and two dimension woven structures of SiC/SiC composites were prepared starting from Tyranno SA fiber. SiC matrix was obtained by nano-powder infiltration and transient eutectoid (NITE) process. Effect of microstructure and density on the sintering temperature in NITE-SiC/SiC composites are described and discussed with the fiber direction of unidirection and two dimension woven structures.

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에폭시 기지 나노복합재료의 마모 특성 (Wear Properties of Epoxy Matrix Nanocomposites)

  • 김재동;김형진;고성위;김영식
    • 동력기계공학회지
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    • 제14권6호
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    • pp.83-88
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    • 2010
  • The wear behavior of epoxy matrix composites filled with nano sized silica particles is discussed in this paper. Especially, the variation of the coefficient of friction and the wear resistance according to the change of apply load and sliding velocity were investigated for these materials. Wear tests of pin-on-disc mode were carried out and the wear test results exhibited as following ; The epoxy matrix composites showed lower coefficient of friction compared to the neat epoxy through the whole sliding distance. As increasing the sliding velocity the epoxy matrix composites indicated lower coefficient of friction, whereas the neat epoxy showed higher coefficient of friction as increasing the sliding velocity. The specific friction work of both materials were increased with apply load. In case of the epoxy matrix composites, the running in periods of friction were reduced as increase in apply load. The epoxy matrix composites were improved the wear resistance by adding the nano silica particles remarkably. It is expected that the load carrying capacity of the epoxy matrix composites will be improved by increase of Pv factor.

중전기기용 Epoxy/SiO2 나노복합재료의 유전분산 연구 (Study on Dielectric Dispersion of Epoxy/SiO2 Nanocomposites using High Voltage Generator)

  • 안준호;박재준
    • 한국전기전자재료학회논문지
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    • 제20권4호
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    • pp.348-351
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    • 2007
  • Recently, Nanotechnology becomes a major issue in most part of industries. Nanotechnology is expected to develop various application products due to nano material mired composites is improved physical and electrical properties compared to conventional composites materials. Dielectric and insulation materials need to develop and improve like other field about nanotechnology. In this paper, we reported dielectric dispersion by size(no filler, $1.2{\mu}m$, 500 nm, 10 nm), frequencies(60, 120, 1 kHz), and temperatures($30{\sim}170^{\circ}C$). Dielectric constant of composites materials with filler shows higher than composites materials without filler and increased depending on rising temperatures in low frequency region. It was the effect that nano-filler and impurities in composites contributed to electrical conductivity. And dielectric properties depending on temperatures shows to change in low frequency region dramatically We analyzed interfacial polarization in low frequency region($10^{-2}$ Hz) and oriented polarization in high frequency region($10^{-5{\sim}6}$ Hz) on composites materials.

Improved Thermal Conductivities of Epoxy Resins Containing Surface Functionalized BN Nanosheets

  • Weng, Ling;Wang, HeBing;Zhang, Xiaorui;Liu, Lizhu;Zhang, Hexin
    • Nano
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    • 제13권11호
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    • pp.1850133.1-1850133.9
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    • 2018
  • The hexagonal boron nitride nanosheets (BN) were firstly treated by silane coupling agents 3-aminopropyltriethoxysilane (KH550) and 3-glycidoxypropyl-trimethoxysilane (KH560) to introduce some amino and epoxy (EP) groups on the BN surface. These modified BN nanosheets were incorporated into an EP matrix to prepare BN@KH560/EP composites with excellent thermal conductivity and electrical insulation properties. Results showed that the thermal conductivity of BN@KH560/EP composite with 20 vol% BN dosage was found to be 0.442 W/($m{\cdot}K$), which was 81% higher than that of pure EP resin. Both BN/EP composites treated by KH550 and KH560 showed rather good electrical insulation properties, although the dielectric constant of BN@KH550/EP composites were slightly higher than BN@KH560/EP composites. Moreover, BN@KH560/EP composites also showed better thermal and mechanical properties than that of BN@KH550/EP composites.

나일론66/MWCNT 복합체 물성 및 유변학적 특성 연구 (Study on the Physical and Rheological Properties of Nylon66/MWCNT Composites)

  • 김도의;김연철
    • 공업화학
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    • 제24권2호
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    • pp.214-218
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    • 2013
  • 나일론66에 다중벽 탄소나노튜브(multi-walled carbon nano tube, MWCNT)를 1, 3, 5, 7 wt% 첨가하여 이축압출기(twin screw extruder)를 이용하여 나일론66/MWCNT 복합체를 제조하였다. MWCNT의 함량에 따른 열적특성, 분산성, 유변 학적 특성 및 충격특성을 DSC, TGA, X선 회절 분석기(XRD), 전자주사현미경(SEM), 동적유변측정기(ARES) 그리고 Izod 시험기를 이용하여 분석하였다. 나일론66에 MWCNT를 첨가할 때 나일론66의 비등온결정화에 영향을 주는 것을 DSC를 이용하여 확인하였다. 나일론66/MWCNT 복합체의 경우 낮은 전단속도 영역에서 복합점도 및 복합점도에 대 한 주파수 의존성을 나타내는 전단박하(shear thinning)가 증가하였으며, MWCNT 함량이 증가할수록 증가폭이 크게 나타났다. 또한 복합체의 G'-G" plot의 기울기가 감소하는 현상으로부터 탄성특성 증가를 확인하였다. 기계적 물성으 로 Izod 충격강도를 분석하였고, 3 wt% MWCNT가 첨가될 때 60%의 충격강도 개선을 확인하였다. SEM을 이용하여 나일론66내의 MWCNT의 분산성을 확인하였다.

B-stage 레진 필름의 카본나노튜브 분산도 평가 및 제조공정 최적화 (Carbon Nano Tube Dispersion Evaluation in B-stage Resin Films)

  • 오영석;박태훈;변준형;이진우;김병선;조치룡
    • Composites Research
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    • 제29권6호
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    • pp.353-357
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    • 2016
  • B-stage 레진 필름에 탄소나노튜브(CNT) 등을 균일하게 분포시킨 뒤에 기타의 보강섬유 층과 함께 여러 겹으로 적층하여 하이브리드 형태의 복합재료를 만드는 방법은 유용하다. 본 연구에서는 CNT가 포함된 에폭시 레진으로부터 shear mixing 및 Three-roll mill 공정을 이용하여 B-stage 레진 필름을 제작하였다. 두 공정을 통해 형성된 CNT/레진 복합재 필름의분산도를 파단면의 SEM 관찰을통해분석하였다. 보다 효율적인 공정을 위해 Calendering pass 횟수에 따른 분산도를 평가하였다. Pass의 횟수에 따른 샘플을 제조하고 CNT 분산도는 SEM 이미지를 통해 확인하고, 전기 전도도 측정을 통해 분석하였다. 추가적으로 gap mode, force mode를 통해 제작한 각각의 샘플의 전기 전도도를 측정하여 CNT 분산도를 분석하였고 이를 통해 최적공정을 도출하였다.

Preparation, Characterizations and Conductivity of Composite Polymer Electrolytes Based on PEO-LiClO4 and Nano ZnO Filler

  • ElBellihi, Abdelhameed Ahmed;Bayoumy, Wafaa Abdallah;Masoud, Emad Mohamed;Mousa, Mahmoud Ahmed
    • Bulletin of the Korean Chemical Society
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    • 제33권9호
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    • pp.2949-2954
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    • 2012
  • Nano ZnO with an average size of 8 nm was prepared by thermal decomposition of zinc oxalate at $450^{\circ}C$. A series of based composite polymer electrolyte PEO-$LiClO_4$ and nano ZnO as a filler have been synthesized using solution cast technique, with varying the filler ratio systematically. XRD, DSC and FTIR studies have been conducted to investigate the structure and interaction of different groups in the composite polymer electrolyte. Effect of nano ZnO ceramic filler concentration on the structure of composites and their electrical properties (DC-conductivity, AC-conductivity, dielectric constant, dielectric loss and impedance) at different frequencies and temperatures was studied. Melting temperature ($T_m$) of PEO decreased with the addition of both $LiClO_4$ salt and nano ZnO filler due to increasing the amorphous state of polymer. All composite samples showed an ionic conductivity. The maximum room temperature ionic conductivity is found for $(ZnO)_{0.5}(PEO)_{12}(LiClO_4)$ composite sample. All the results are correlated and discussed.