• 제목/요약/키워드: nano composites

검색결과 644건 처리시간 0.021초

Electrical and Thermal Characterization of Organic Varnish Filled with ZrO2 Nano Filler Used in Electrical Machines

  • Selvaraj, D. Edison;Vijayaraj, R.;Sugumaran, C. Pugazhendhi
    • Journal of Electrical Engineering and Technology
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    • 제10권4호
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    • pp.1700-1711
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    • 2015
  • In the last decade it has been witnessed significant developments in the area of nano particles and nano scale fillers on electrical, thermal, and mechanical properties of polymeric materials such as resins, varnishes, enamel and bakelites. The electric and thermal properties were more important in the electrical equipments for both steady state and transient state conditions. This paper deals with the characterization of the electric and thermal properties of the pure varnish and zirconia (ZrO2) filler mixed varnish. The electric properties such as dielectric loss (tan δ), dielectric constant (ε), dielectric strength and partial discharge voltage were analyzed and detailed for different samples. It was observed that zirconia nano filler mixed varnish has the superior dielectric and thermal properties when compared to those of standard varnish. It has shown that at power frequency the 1wt% nano composite sample has the higher permittivity value when compared to other samples. It has been examined that the 1wt% sample was having higher inception and extinction voltages when compared to other samples. It has been observed that 1wt% sample has higher dielectric strength when compared with other samples. There has been an improvement of thermal property by adding few weight percent of zirconia nano fillers. There was not much variation in glass transition among the nano mixed composites. The weight loss was improved at 1wt% of the zirconia nano fillers.

나노 MMT-폴리머 복합체를 이용한 폴리머 콘크리트의 강도 특성 (Properties on the Strength of Polymer Concrete Using Nano MMT-UP Composite)

  • 조병완;문린곤;박승국
    • 대한토목학회논문집
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    • 제26권4A호
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    • pp.761-766
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    • 2006
  • 폴리머 복합체는 우수한 강도와 내구성으로 건설현장에서 프리캐스트 부재 및 보수, 보강재로서 널리 쓰이고 있어 폴리머 복합체의 경제성 및 성능 향상에 관한 연구가 이루어지고 있다. 폴리머 나노 복합체는 나노미터 수준의 크기를 가진 Clay 등의 무기 물질을 나노분산 상으로 폴리머에 균일 혼합시킨 것으로 산업적 응용가능성 면에서 뿐만 아니라 재료 및 공학분야에서도 많은 관심을 가지고 있다. 그리고 기존의 복합체 보다 1/10 혹은 그 이상의 낮은 함량의 분산상만으로도 더 우수한 강도와 역학적 특성 및 열안정성을 나타낸다. 본 실험에서는 폴리머 복합체의 성능을 향상시키고자 유기화된 몬모릴로나이트(MMT)와 유기화 되지 않은 몬모릴로나이트(MMT)를 사용하여 박리된 MMT-UP 나노 복합체를 제조하였다. XRD와 TEM실험결과, Cloisite 30B-UP 나노 복합체에서 층과 층 사이가 $100{\AA}$ 이상 떨어져 단일층으로 분산되었기 때문에 박리가 되었음을 알 수 있었다. 또한 역학적 특성은 기존복합체보다 인장강도와 인장탄성계수을 비교하였을 때 매우 향상됨을 알 수 있었고 열적 특성도 기존복합체보다 우수한 함을 나타내었다. 박리정도가 우수한 MMT-UP 복합체로 제조한 폴리머 콘크리트에서도 순수한 UP를 사용한 것보다 역학적 특성이 두드러졌다. 또한 폴리머 콘크리트의 강도와 탄성계수는 MMT-UP 복합체의 인장강도 및 인장탄성계수와 상관성을 갖는 것으로 판단된다.

TiO2 나노입자의 크기와 함량이 TiO2/Epoxy 복합재료의 기계적 물성에 미치는 영향 (Effect of TiO2 Particle Size and Content on the Mechanical Properties of TiO2/Epoxy Composites)

  • 김부안;문창권
    • 동력기계공학회지
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    • 제21권1호
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    • pp.11-17
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    • 2017
  • This study is about the mechanical properties of epoxy composite reinforced with nano $TiO_2$ particle. Tensile strength, fracture toughness, vicker's hardness and Izod Impact test were carried out to investigate the effect of particle size and content of $TiO_2$ on the mechanical properties of $TiO_2$/epoxy composites. The results showed that the strength of the $TiO_2$/epoxy composites were higher than that of the pure epoxy. The best improvement of tensile strength was achieved in case of the particle size was 21 nanometer and the content was 3 weight percent. However, the Izod Impact value and the Vicker's hardness of $TiO_2$/epoxy composites showed no clear tendency.

Aluminum-Copper(II) Oxide Composite의 정전기에 의한 반응 특성 연구 (Reaction Characteristics Study of Aluminum-Copper(II) Oxide Composites Initiated by the Electrostatic Discharge)

  • 김민준;김성호;김자영;임예슬
    • 한국군사과학기술학회지
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    • 제21권5호
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    • pp.591-598
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    • 2018
  • The reaction characteristics of aluminum-copper(II) oxide composites initiated by the electrostatic discharge were studied as changing the aluminum particle size. Three different sizes of aluminum particles with nano-size copper(II)-oxide particle were used in the study. These composites were manufactured by two methods i.e. a shock-gel method and a self-assembly method. The larger aluminum particle size was, the less sensitive and less violent these composites were based on the electrostatic test. On the analysis of high speed camera about ignition appearances and burning time, the burning speed was faster when aluminum particle size was smaller.

하이브리드 전도성 Filler 섬유강화 복합재료의 전자파 차폐효과 (Electromagnetic Interference Shielding Effectiveness of Fiber Reinforced Composites Hybrid Conductive Filler)

  • 한길영;송동한;배지수
    • 한국해양공학회지
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    • 제23권3호
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    • pp.35-39
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    • 2009
  • The main objective of this study was to investigate fiber reinforced composite materials (FRCM) with electromagnetic shielding characteristics using aluminum (Al) film and copper (Cu) meshes. This study investigated the electromagnetic interference (EMI) shielding effectiveness (SE) of fiber reinforced composites filled with Al film, Cu meshes, and nano carbon black as hybrid conductive fillers to provide the electromagnetic shielding property of the fiber reinforced composites. The coaxial transmission line method of ASTM D 4935-89 was used to measure the EMI shielding effectiveness of composites in the frequency range of 300 MHz to 1.5 GHz. The variations of SE of FRCM with Al film, fine Cu, and general Cu meshes are described. The results indicate that the FRCM having Al film exhibited up to 75 dB of SE at 1.5 GHz.

Effects of maleic anhydride content on mechanical properties of carbon fibers-reinforced maleic anhydride-grafted-poly-propylene matrix composites

  • Kim, Hyun-Il;Han, Woong;Choi, Woong-Ki;Park, Soo-Jin;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
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    • 제20권
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    • pp.39-46
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    • 2016
  • In this work, the effects of maleic anhydride (MA) content on mechanical properties of chopped carbon fibers (CFs)-reinforced MA-grafted-polypropylene (MAPP) matrix composites. A direct oxyfluorination on CF surfaces was applied to increase the interfacial strength between the CFs and MAPP matrix. The mechanical properties of the CFs/MAPP composites are likely to be different in terms of MA content. Surface characteristics were observed by scanning electron microscope, Fourier transform infrared spectroscopy, and single fiber contact angle method. The mechanical properties of the composites were also measured by a critical stress intensity factor (KIC). From the KIC test results, the KIC values were increased to a maximum value of 3.4 MPa with the 0.1 % of MA in the PP, and then decreased with higher MA content.

전기저항 측정과 음향방출을 이용한 표면 처리된 탄소 나노튜브와 나노 섬유 강화 에폭시 복합재료의 비파괴적 손상 감지능 (Nondestructive Damage Sensitivity for Functionalized Carbon Nanotube and Nanofiber/Epoxy Composites Using Electrical Resistance Measurement and Acoustic Emission)

  • Kim, Dae-Sik;Park, Joung-Man;Kim, Tae-Wook
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2003년도 추계학술발표대회 논문집
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    • pp.42-45
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    • 2003
  • Nondestructive damage sensing and mechanical properties for acid-treated carbon nanotube (CNT) and nanofiber (CNF)/epoxy composites were investigated using electro-micromechanical technique and acoustic emission (AE). Carbon black (CB) was used to compare to CNT and CNF. The results were compared to the untreated case. The fracture of carbon fiber was detected by nondestructive acoustic emission (AE) relating to electrical resistivity under double-matrix composites test. Sensing for fiber tension was performed by electro-pullout test under uniform cyclic strain. The sensitivity for fiber damage such as fiber fracture and fiber tension was the highest for CNT/epoxy composites. Reinforcing effect of CNT obtained from apparent modulus measurement was the highest in the same content. For surface treatment case, the damage sensitivity and reinforcing effect were higher than those of the untreated case. The results obtained from sensing fiber damage were correlated with the morphological observation of nano-scale structure using FE-SEM. The information on fiber damage and matrix deformation and reinforcing effect of carbon nanocomposites could be obtained from electrical resistivity measurement as a new concept of nondestructive evaluation.

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Electro-Micromechanical 시험법과 음향방출을 이용한 탄소 나노튜브와 나노섬유 강화 에폭시 복합재료의 비파괴적 손상 감지능 (Nondestructive Damage Sensitivity of Carbon Nanotube and Nanofiber/Epoxy Composites Using Electro-Micromechanical Technique and Acoustic Emission)

  • Kim, Dae-Sik;Park, Joung-Man;Lee, Jae-Rock;Kim, Tae-Wook
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2003년도 춘계학술발표대회 논문집
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    • pp.117-120
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    • 2003
  • Electro-micromechanical techniques were applied using four-probe method for carbon nanotube (CNT) or nanofiber (CNF)/epoxy composites with their content. Carbon black (CB) was used to compare with CNT and CNF. The fracture of carbon fiber was detected by nondestructive acoustic emission (AE) relating to electrical resistivity for double-matrix composites test. Sensing for fiber tension was performed by electro-pullout test under uniform cyclic strain. The sensitivity for fiber damage such as fiber fracture and fiber tension was the highest for CNT/epoxy composites, and in CB case they were the lowest compared with CNT and CNF. Reinforcing effect of CNT obtained from apparent modulus measurement was the highest in the same content. The results obtained from sensing fiber damage were correlated with the morphological observation of nano-scale structure using FE-SEM. The information on fiber damage and matrix deformation and reinforcing effect of carbon nanocomposites could be obtained from electrical resistivity measurement as a new concept of nondestructive evaluation.

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ABS/Nickel 코팅 탄소섬유와 Epoxy/Copper-Nickel 직조 섬유 복합재료의 전자파차폐 효과 (Shielding Effectiveness of Electromagnetic Interference in ABS/Nickel Coated Carbon Fiber and Epoxy/Cu-Ni Fabric Nano Carbon Black Composites)

  • 한길영;정우철;양인영;선향선
    • 한국기계가공학회지
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    • 제11권6호
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    • pp.169-174
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    • 2012
  • Electromagnetic interference(EMI) shielding effectiveness(SE) was investigated in of woven fabric made of epoxy/copper-nickel fabrics and nickel coated carbon fiber reinforced acrylonitrile-butadiene-styrene(ABS) composites. The coaxial transmission line method was used to measure the EMI shielding effectiveness of the composites. We designed and constructed a measuring system, consisting of a network analyzer and a device that plays the serves as a sample holder and at the same time as a transmission medium of the incident electromagnetic wave. The measurement of SE were carried out frequency range from 100MHz to 2GHz. It is observed that the SE of the composits is the frequency dependent increase with the increase in nickel coated carbon fibre volume fraction. The nickel coating with 20wt% ABS composite was shown to exhibit up to 60dB of SE. The result that nickel coated carbon fibre ABS composite can be used for the purpose of EMI shielding as well as for some microwave applications.

Effect of Carbon Matrix on Electrochemical Performance of Si/C Composites for Use in Anodes of Lithium Secondary Batteries

  • Lee, Eun Hee;Jeong, Bo Ock;Jeong, Seong Hun;Kim, Tae Jeong;Kim, Yong Shin;Jung, Yongju
    • Bulletin of the Korean Chemical Society
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    • 제34권5호
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    • pp.1435-1440
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    • 2013
  • To investigate the influence of the carbon matrix on the electrochemical performance of Si/C composites, four types of Si/C composites were prepared using graphite, petroleum coke, pitch and sucrose as carbon precursors. A ball mill was used to prepare Si/C blends from graphite and petroleum coke, whereas a dispersion technique was used to fabricate Si/C composites where Si was embedded in disordered carbon matrix derived from pitch or sucrose. The Si/pitch-based carbon composite showed superior Si utilization (96% in the first cycle) and excellent cycle retention (70% after 40 cycles), which was attributed to the effective encapsulation of Si and the buffering effect of the surrounding carbon matrix on the silicon particles.