• Title/Summary/Keyword: n-volume

Search Result 2,310, Processing Time 0.034 seconds

Partial molal volumes of n-alkylamine hydrochlorides in methanol-water mixtures (메탄올-물 혼합액에서의 n-Alkylamine 염산염의 분 몰랄 부피)

  • Uhm, Tae-Sup;Yoon, Sang-Ki;Lee, Ik-Choon
    • Journal of the Korean Chemical Society
    • /
    • v.14 no.1
    • /
    • pp.51-59
    • /
    • 1970
  • The apparent molal volumes(${\phi}_v$) of the homologous salts $RNH_3Cl$, where R varies from methyl-($CH_{3^-}$) to n-butyl-(n-$C_4H_{9^-}$) in a series of methanol-water mixtures have been determined at 30$^{\circ}C$ by means of a float method to fifth decimal places down to 0.01 m. The values of ${\phi}_r$ extrapolated to infinite dilution give partial molal volumes $\bar{V}^{\circ}$which varies considerably in accordance with the solvent composition. that is, mole fraction of methanol. The experimental results are discussed in terms of the varying size and charge effect, hydrophobic nature of the solute species, and also the additivity relationship between successive homologous and the structure of the binary solvent. The results indicate that at 0.1 mole fraction methanol the enhanced structuredness of water cause a minimum in the partial molal volumes of cations $\bar{V}^{\circ}_+$, while at 0.4 mole fraction the solvent structure is such that the free volume is a minimum but the effect of electrostriction is a maximum.

  • PDF

Effect of Nitrogen Volume in Ar-N2 Shielding Gas on Microstructure and Hardness of GTA Welded Pure Ti (순 Ti GTA 용접부의 미세조직과 경도에 미치는 Ar-N2 보호가스 중 질소량의 영향)

  • An, Hyun-Jun;Jeon, Ae-Jeong;Hong, Jae-Keun;Jeong, Bo-Young;Lee, Jong-Sub;Kang, Chung-Yun
    • Journal of Welding and Joining
    • /
    • v.30 no.2
    • /
    • pp.70-75
    • /
    • 2012
  • In this study, effect of nitrogen volume in the shielding gas of Ar-$N_2$ mixing gas on the bead shape, hardness and microstructure of GTA welds of 3mm thick Commercial Pure Ti was investigated. As the nitrogen volume increased, the welding current for full penetration was reduced and hardness in the fusion zone significantly increased compared with that of the base metal, but there is no difference in the hardness of HAZ. Microstructure in the fusion zone with pure Ar gas changed from equiaxed alpha of the base metal to serrated alpha. On the other hand, microstructure using Ar-$N_2$ mixing gas changed to acicular alpha. With the increasing of nitrogen content, the amount of acicular alpha increased and the size of that was fine.

Difference in Volume Perception according to Cup Shape in Normal Weight and Overweight Female College Students (정상체중과 과체중 여대생을 대상으로 컵의 형태에 따른 인지량의 차이에 관한 연구)

  • Lee, Myung-Ok;Chang, Un-Jae
    • Journal of the Korean Dietetic Association
    • /
    • v.20 no.1
    • /
    • pp.63-69
    • /
    • 2014
  • The volume perception of water according to cup shape was examined in female college students divided into a normal weight group (<23 body mass index, n=51) and an overweight group (${\geq}$23 body mass index, n=48). The perceived water volume was recorded by participants after they observed the water volume in cups with different shape (highball and tumbler) and with different base height (high base and low base), which contained the same amount of water (150 ml). The normal weight group perceived a water volume of 238.5 ml (highball) and 201.6 ml (tumbler) for the high base cups. The overweight group perceived a volume of 245.6 ml (highball) and 188.8 ml (tumbler). For the low base cups, the normal weight group perceived a water volume of 207.8 ml (highball) and 104.1 ml (tumbler). The overweight group perceived a volume of 202.2 ml (highball) and 100.4 ml (tumbler). Both the normal weight and overweight groups perceived significantly more liquid in the highball cups compared to the tumbler cups. In addition, both groups perceived significantly more liquid in the high base cups compared to the low base cups. However, there were no significant differences in the estimated variance of perceived volume between the normal weight and overweight groups according to the cup shape and cup base height. In conclusion, cup shape and base height potentially affects volume perception. Therefore, modifying cup shape may be used in a weight control program to help control caloric beverage consumption.

Electrical Insulation Characteristics at Cryogenic Temperature for High Temperature Superconducting Cables

  • Okubo, Hitoshi;Hayakawa, Naoki
    • KIEE International Transactions on Electrophysics and Applications
    • /
    • v.4C no.1
    • /
    • pp.15-20
    • /
    • 2004
  • This paper discusses electrical insulation characteristics at cryogenic temperature, especially focusing on partial discharge (PD) inception characteristics, for high temperature superconducting cables. In liquid nitrogen (L$N_2$) / polypropylene (PP) laminated paper composite insulation system, PD inception strength (PDIE) was evaluated in terms of volume effect and V-t characteristics. Different kinds of butt gap condition were applied in the experiments, using parallel plane and coaxial cylindrical cable samples. Experimental results revealed that the volume effect on PDIE could be evaluated by the statistical stressed liquid volume (SSLV) taking account the discharge probability not only in the butt gap but also in the other thin layers between PP laminated papers. Furthermore, the indices n of V-t characteristics at PD inception were estimated to be 80∼110, irrespective of the butt gap condition.

Effects of Rice Straw as Bulking Materials on Aerobic Composting of Food Wastes (팽화재로서의 볏짚이 음식물쓰레기의 호기성 퇴비화에 미치는 영향)

  • 박석환
    • Journal of Environmental Health Sciences
    • /
    • v.28 no.2
    • /
    • pp.141-148
    • /
    • 2002
  • This study was performed to examine the effects of rice straw as bulking materials on temperature, pH, weight and volume reduction, porosity, C/N ratio, salinity, and conductivity in aerobic composting of food wastes. Volume ratios of food wastes to rice straw in reactor control, RS-1, RS-2, RS-2 and RS-4 were 4:0, 4:1. 4:2. 4:3 and 4:4, respectively. Reactors were operated for 24days with 1 hour stirring by lrpm and 2hours aeration per day. The values of pH of food wastes and rice straw were 4.39 and 7.4, respectively. The lowering of the volume ratio of food wastes to rice straw resulted in the high reaction temperature and the fast weight and volume reduction rates. C/N ratio in control was larger than that in rice straw containing reactors. Salinity and conductivity in reactors were condensed and increased by reaction days.

Piezoelectric Properties of O-3 Composite with $PbTiO_3$--Polymer ($PbTiO_3$-폴리머 O-3 복합 재료의 압전 특성에 관한 연구)

  • 김일호;박인길;이성갑;이영희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1988.10a
    • /
    • pp.50-53
    • /
    • 1988
  • Lead titanate powders were prepared by mixed-oxide and sol-gel method. O-3 composites were prepared with these powders using Eccogel polymer. According to the volume percent of the PbTiO$_3$ powders, dielectric, piezoelectric properties and poling conditions were investigated. Relative dielectric constants were exponentially increased with volume percent of PbTiO$_3$. Piezoelectric strain coefficients (d$_{33}$ ) were increased with volume percent of PbTiO$_3$. Figure of merit (d$_{h}$.g$_{h}$) for the O-3 composites prepared by the mixed-oxide and sol-gel method were 2728(x10$^{-15}$ $m^2$/N) and 3100(x10$^{-15}$ $m^2$/N) at 70 volume percent of PbTiO$_3$, respectively.ely.

  • PDF

Flood Impact Pressure Analysis of Vertical Wall Structures using PLIC-VOF Method with Lagrangian Advection Algorithm

  • Phan, Hoang-Nam;Lee, Jee-Ho
    • Journal of the Computational Structural Engineering Institute of Korea
    • /
    • v.23 no.6
    • /
    • pp.675-682
    • /
    • 2010
  • The flood impact pressure acting on a vertical wall resulting from a dam-breaking problem is simulated using a navier-Stokes(N-S) solver. The N-S solver uses Eulerian Finite Volume Method(FVM) along with Volume Of Fluid(VOF) method for 2-D incompressible free surface flows. A Split Lagrangian Advection(SLA) scheme for VOF method is implemented in this paper. The SLA scheme is developed based on an algorithm of Piecewise Linear Interface Calculation(PLIC). The coupling between the continuity and momentum equations is affected by using a well-known Semi-Implicit Method for Pressure-Linked Equations (SIMPLE) algorithm. Several two-dimensional numerical simulations of the dam-breaking problem are presented to validate the accuracy and demonstrate the capability of the present algorithm. The significance of the time step and grid resolution are also discussed. The computational results are compared with experimental data and with computations by other numerical methods. The results showed a favorable agreement of water impact pressure as well as the global fluid motion.

The Characteristics of Mechanical Properties and Fatigue Crack Propagation of Fire Resistance Steel for Frame Structure (구조용 내화강의 기계적 성질과 피로균열전파 특성에 관한 연구)

  • Kim, Hyeon-Su;Nam, Gi-U;Gang, Chang-Ryong
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.25 no.1
    • /
    • pp.54-60
    • /
    • 2001
  • This study is to investigate the mechanical properties and the fatigue crack propagation of fire resistance steel for frame structure as the chemical composition was changed by addition of N, B and rolled end temperature was varied. We used two kinds of specimen, the one is parallel and the other is perpendicular to the rolling directions. As rolled end temperature increased, volume fraction of ferrite and pearlite decreased, but volume fraction of baintie and grain size increased. Micro-hardness decreased as rolled end temperature increased, but tensile and yield strength increased. Volume fraction of ferrite and pearlite decreased by addition of N. But volume fraction of bainite, tensile and yield strength increased. Microstructure was changed to martensite by addition of B, and tensile and yield strength increased. Fatigue life of TL direction specimen was shorter than that of LT direction specimen. There was no significant effect to fatigue crack propagation rate by addition of N and changing rolling condition, but fatigue life was increased by addition of B.

Characteristic Evaluation Based on the Heat Treatment Conditions of Super Duplex Stainless Steel with 0.2% N as an Additive - Part 1: Mechanical Properties and Microstructure (0.2% N을 첨가한 수퍼 2상 스테인리스강의 열처리 조건에 따른 특성 평가 - 제1보: 기계적 특성 및 미세조직)

  • Ahn, Seok-Hwan;Kang, Heung-Joo;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
    • /
    • v.22 no.4
    • /
    • pp.46-50
    • /
    • 2008
  • Super duplex stainless steel has along life in severe environments because of its strength and corrosion resistance. If 0.2$\sim$0.3% Nitrogen in aninterstitial solid solution is added, the austenite structure is reinforced. This improves the solid solution hardening and the anticorrosionability. In this study, the mechanical properties and structures of the super duplex stainless steel with the 0.2% N additive were investigated to determine the effect of various volume fractions on the austenite phase. The various volume fractions and distributions of the austenite structure in the applied test specimens were obtained by changing the heat treatment temperature and cycle. The characteristics by amounts of the $\sigma$ phase obtained from the precipitation heat treatment were alsoinvestigated. From the results, when the austenite volume fraction increases, the tensile strength decreases and elongation increases. And the $\sigma$ phase was rapidly increased by increasing the heat treatment time. When the volume fraction of the $\sigma$ phase increased, tensile strength increased.

pH- and Temperature-Sensitive Bifunctional Hydrogels of N-Isopropylacrylamide and Sulfadimethoxine Monomer

  • Lee, Jin-Woo;Lee, Doo-Sung;Kim, Sung-Wan
    • Macromolecular Research
    • /
    • v.11 no.3
    • /
    • pp.189-193
    • /
    • 2003
  • pH- and temperature-sensitive bifunctional hydrogels composed of N-isopropylacrylamide (NiPAAm) and a sulfadimethoxine monomer (SDM) derived from sulfadimethoxine were prepared. These hydrogels exhibit simultaneous pH- and temperature-induced volume-phase transitions. The pH-induced volume-phase transition behavior is produced by the ionization/deionization of SDM and is very sharp. In the high pH region, the ionization of SDM induces swelling of the hydrogels. In the low pH region, the deionization of SDM induces deswelling of the hydrogels. The temperature-induced volume-phase transition behavior of the bifunctional hydrogels exhibits negative thermosensitivity because of the NiPAAm component. The hydrogels swell even at low pH as the temperature decreases. The hydrogels swell at low temperature and high pH, and deswell at high temperature and low pH. The volume of the hydrogels dependl on the balance of the swelling and deswelling produced by the two competing stimuli, pH and temperature.