• 제목/요약/키워드: n-heptane

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The Simultaneous Hydrocracking and Hydrodesulfurization over CoPtMo/LaY Catalyst (CoPtMo/LaY 촉매상에서 동시적인 수소화분해반응 및 수소첨가탈황반응)

  • 김문찬;김경림
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.2
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    • pp.171-178
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    • 1995
  • The hydrodesulfurization (HDS) of dibenzothiophene (DBT) were performed simultaneously over CoPtMo/LaY catalyst under high H$_{2}$ pressure. The structure and physical properties of this catalyst were characterized using XRD, IR and surface area analyzer. The origin of acid site was mainly Bronsted. The structures of impregnated molybdenum and platinum were deactivated by DBT to MoS$_{2}$ and PtS, respectively. The activities of the HDS and the hydrocracking increased with increasing temperature and pressure. They decreased with increasing the DBT mole ratio(DBT/n-heptane). They remained constant with increasing the H$_{2}$/H.C. mole ratio. With increasing pressure and DBT mole ratio, the products of secondary cracking increased. To perform simultaneous HDS and hydrocracking effectively, the optimum condition were 500.deg.C, 4MPa.

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Simulation Injection Mass with Variable Injection Condition in GDI Engine using AMESim (AMESim을 이용한, GDI 엔진에서 연료의 분사조건 변화에 따른 분사량 변화 예측)

  • Shin, Suk Shin;Song, Jingeun;Park, Jongho
    • Journal of ILASS-Korea
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    • v.18 no.1
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    • pp.61-65
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    • 2013
  • In case of GDI engine, shape of injected fuel and injection mass are one of the most important factors for good fuel efficiency and power. But it should be too inefficient and difficult to acquire injection mass data by experiment because condition in engine vary with temperature, pressure, and so on. So, this paper suggests the AMESim (Advanced Modeling Environment for Simulation of Engineering Systems) as simulation program to calculate injection mass. For both simulation and experiment, n-heptane is used as fuel. In AMESim, I modeled the GDI injector and simulated several cases. In experiment, I acquired the injection mass using Bosch method to apply ambient pressure. The AMESim show reasonable result in comparison with experimental data especially at injection pressure 15 MPa. Other conditions are also in good accord with experimental data but error is a little bit large because the injection mass is so low.

Ventilation Effects on Smoke Behavior in Rescue Station for Tunnel Fires (철도터널 화재시 구난역 내의 연기거동에 미치는 배연효과에 관한 수치연구)

  • Jang, Won-Cheol;Kim, Dong-Woon;Ryou, Hong-Sun;Lee, Seong-Hyuk
    • Proceedings of the KSR Conference
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    • 2008.06a
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    • pp.2130-2138
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    • 2008
  • The present study investigates the ventilation effects on smoke spreading characteristics in railway tunnels with the rescue stations. Experiments were carried out for n-heptane pool fires with a square length 4 cm at different fire locations, and the heat release rates (HRR) were obtained by the measurement of burning rates. In addition, using the commercial code (FLUENT), the present article presents numerical results for smoke behavior in railway tunnels with rescue station, and it uses the MVHS (Modified Volumetric Heat Source) model for estimation of combustion products resulting from the fire source determined from the HRR measurement. As a result, it is found that smoke propagation is prevented successfully by the fire doors located inside the cross-passages and especially, the smoke behavior in the accident tunnel can be controlled through the ventilation system because of substantial change in smoke flow direction in the cross-passages.

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Powder Injection Moulding of Mn-Zn Ferrite

  • Rodriguez-Senina, E.;Varez, A.;Levenfeld, B.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.763-764
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    • 2006
  • Ceramic Injection Moulding (CIM) technology has been successfully used for the fabrication of Mn-Zn Ferrite part. The binder was composed by polypropylene and paraffin wax. The optimal powder loading (58% vol.) was determined by means of rheological measurements. Threedifferent parts, toroids, bending and tensile probes were injected. Thermal and solvent-thermal debinding was designed based on DSC and TGA studies of the binder. The time of the debinding cycle was reduced using n-heptane to dissolve previously the paraffin wax. Final properties have been determined and compared with uniaxial pressure parts values. The densities obtained were slightly higher than those of uniaxial pressure parts and the magnetic properties presented similar values.

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Isolation of Fucosterol from Pelvetia siliquosa by High-speed Countercurrent Chromatography

  • Hwang, Seung Hwan;Jang, Jai Man;Lim, Soon Sung
    • Fisheries and Aquatic Sciences
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    • v.15 no.3
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    • pp.191-195
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    • 2012
  • We report here the use of high-speed countercurrent chromatography (HSCCC) in the preparative isolation and purification of the bioactive component, fucosterol, from Pelvetia siliquosa. A crude extract was obtained by ultrasonic extraction of powdered P. siliquosa using methylene chloride and was then subjected to separation and purification by HSCCC, coupled with evaporative light-scattering detection. Preparative HSCCC was performed successfully using a two-phase solvent system, n-heptane:methanol (3:2, v/v), to obtain 10.96 mg fucosterol with 96.8% purity from 50 mg of crude extract; the recovery rate was approximately 90.5%.

Effects of environmental flow velocity on the evaporation of free droplets (자유액적의 증발에 미치는 분위기 속도의 영향)

  • Jeong, Seong-Sik;Ha, Jong-Ryul;Lee, Jung-Sun;Lee, Sang-Seok;Kawaguchi, O
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.6
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    • pp.2036-2045
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    • 1996
  • An experimental study has been performed to obtain the effect of relative velocity between droplet and environmental gas on the evaporation of a n-heptane free droplet of 180 $\mu$m in diameter flying in a hot and normal pressure air flow. Measurement of droplet diameter and velocity was conducted in a series of time by an electrically controlled optical system. From the experimental results, an empirical equation associated with the relation between evaporation rate constant and relative velocity was obtained.

Combustion Characteristics of the Miao-Gravity Condition (미소중력장에서의 연소특성 연구)

  • Lee, Keun-Oh;Lee, Kyeong-Ook
    • Journal of the Korean Society of Safety
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    • v.17 no.4
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    • pp.66-70
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    • 2002
  • The transient soot distributions within the region bounded by the droplet surface and the flame were measured using a full-filed light extinction technique and subsequent tomographic inversion using Abel transforms. The soot volume fraction results for n-heptane droplets represent the first quantitative assessment of the degree of sooting for isolated droplets burning under microgravity condition. The absence of buoyancy(which produces longer residence times) and the effects of thermophoresis produce a situation in which a significant concentration of soot is produced and accumulated into a soot-cloud. Results indicate that indeed the soot concentration within the microgravity droplet flames(with maximum soot volume fractions as high as ~60ppm) are significantly higher than corresponding values that are reports for normal-gravity flames. This increase in likely due to longer residence times and thermophoretic effects that manifested under microgravity conditions.

Fire Suppression Effect of PPV with Water Mist System (미세물분무를 이용한 PPV의 화재진압효과)

  • Kim, Sung-Won;Shin, Chang-Sub
    • Journal of the Korean Society of Safety
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    • v.18 no.4
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    • pp.71-77
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    • 2003
  • To inject fresh air into a fire room, Positive Pressure Ventilation (PPV) can be used and the blower of PPV increases inside pressure of the room. It makes high flow rate of products of combustion, smoke and heat from the structure, and it is very helpful to fireman on the fire extinguishing work. The flame moves to the direction of airflow and the temperature of flame can be decreased rapidly. In this experiment, a water mist system is applied to PPV to increase the effectiveness, and various effective factors are studied. n-Heptane and pine wood stick were used as fuel. Temperatures at the above and behind the combustion pan were strongly reduced by the water mist system and by the convective cooling with airflow. The smoke density was also decreased by PPV with water mist system and it can be explained by the absorption of smoke particles on the water mist droplet and by the strong exhausting effects of mobile fan.

Flame Extinguishing Characteristics of Clean Gaseous Agents and Effects of Additives (가스계 청정소화약제의 소화특성과 첨가제에 따른 영향)

  • Shin, Chang-Sub;Kim, Sung-Min
    • Journal of the Korean Society of Safety
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    • v.23 no.6
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    • pp.95-99
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    • 2008
  • Halon was known as a cause of the ozone layer destruction. In 1987, it was designated as one of the ozone-layer-destroying materials in the Montreal Protocol. Therefore substitutes of Halon agent has been developed including inert gas extinguish system, which is one of the most widely used fire extinguishing system. This study intended to increase the efficiency of inert gas extinguishing agent by using inert gas additives. As IG-541 shows high extinguishing power, the experiment was performed to measure the effects of gaseous additives to it. Cup-burner fire extinguishing apparatus was used with n-Heptane fuel. Among many of pure inert gaseous agents, Helium showed the most excellent extinguishing power. When Helium was added to IG-541, fire extinguishing power was increased and the concentration of oxygen in chimney also risen. By adding Helium to IG-541, the effectiveness of inert gas fire extinguishing system is able to be increased.

A Study on the Measurement of Flame Extinguishing Concentration of Halon Alternatives by New Test Equipment (할론대체물질의 새로운 불꽃소화농도 측정장치에 관한 연구)

  • 김재덕;임종성;이윤우;이윤용
    • Fire Science and Engineering
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    • v.8 no.1
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    • pp.3-8
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    • 1994
  • A new test system was established to measure the flame extinguishing concentration of Halon alternatives. The main characteristic of this system is to use the solid paraffin with a wick instead of liquid fuel, such as n-Heptane. Our results showed that the extinguishing concentration of compounds was lower than that of other existing data, but the trend was consistent with others. The flame extinguishing concentration of all tested compounds were not almost effected by gas flow velocity. The system produces good reliable data with a minimum error for measuring the flame extinguishing concentration. Therefore our new system can be utilized as a standard equipment to evaluate Halon alternatives.

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