• Title/Summary/Keyword: n-Undecane

Search Result 14, Processing Time 0.015 seconds

아까시나무와 밤나무 유래 propolis의 휘발성 향기 성분 특징

  • Song, Hyo-Nam;Kim, Yeong-Eon;Lee, Yeong-Cheol
    • Bulletin of Food Technology
    • /
    • v.12 no.4
    • /
    • pp.28-35
    • /
    • 1999
  • 밀원식물을 달리하여 채집된 두 종류의 국내산 propolis의 향기성분을 Aroma Scan과 GC/MS로 분석하였다. Aroma Scan으로 아까시나무와 밤나무 유래의 두 propolis는 서로 다른 향기를 지닌것을 확인하였다. GC/MS로 분석한 propolis의 향기 성분은 아까시나무 유래 propolis의 44종과 밤나무 유래 propolis의 47종을 포함한 총 55종이 검출되었다. Aldehydes 5종, alcohols 8종, ketones 5종, esters 3종, fatty acid 1종을 비롯하여 27종의 hydrocarbons과 2종의 terpenes 및 4종의 phenolic derivatives가 검출되었다. Benzaldehyde, cinnamyl alcohol, dudesmol 및 benzylbenzoate 등을 포함한 36종의 화합물은 두시료에서 공통적으로 검출되었고, geraniol과 n-undecane을 포함한 8종의 성분은 아까시나무 유래의 propolis에서만 확인되었으며, piperitenone과 valencene을 포함한 11종의 화합물은 밤나무 유래의 propolis에서만 검출되어 밀원식물에 따라 향기성분에 차이가 있는 것으로 나타났다.

  • PDF

Rancidity Analysis of Rapeseed Oil under Different Storage Conditions Using Mass Spectrometry-based Electronic Nose (질량분석기 기반-전자코를 이용한 저장중 유채유의 산패 분석)

  • Hong, Eun-Jeung;Lim, Chae-Lan;Son, Hee-Jin;Choi, Jin-Young;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
    • /
    • v.42 no.6
    • /
    • pp.699-704
    • /
    • 2010
  • Rapeseed oil was stored under different conditions such as in the dark, with UV treatment, and with prooxidantscytochrome C and copper ion. The rapeseed oils stored at different temperatures were analyzed by a mass spectrometrybased electronic nose and discriminant function analysis (DFA). Volatile components in the rapeseed oil increased with storage time, and the discriminant function first score (DF1) moved from a positive position to a negative position as storage time increased. Changes in DF1 were higher under UV treatment than under the dark condition (DF1: $r^2$=0.9481, F=307.03). The different DF1 values (F1) under the dark condition were 0.099, 0.187, and 0.278 as storage temperature increased. The different values under UV treatment were 0.554, 0.588, and 0.542, as storage temperature increased from 4 to $26^{\circ}C$. As concentrations of prooxidants copper ion and cytochrome C increased, amounts of volatile components also increased. These were confirmed by DFA. Furthermore, changes in responses at each ion fragment agreed with reported results for GC/MS, which formed after rancidity of the oil, including pentane, pentanal, 1-pentanol, hexanal, n-octane, 2-hexenal, heptanal, 2-heptenal, decane, 2-octenal, undecane, and dodecane.

Hydrocarbon Speciation in Low Temperature Diesel Combustion (저온 디젤 연소에서 발생하는 탄화수소 종 분석)

  • Han, Man-Bae
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.34 no.4
    • /
    • pp.417-422
    • /
    • 2010
  • Low temperature diesel combustion was achieved via a combination of late injection timing ($8.5^{\circ}$ CA BTDC to $0.5^{\circ}$ CA BTDC) and heavy exhaust gas recirculation (37% to 48%) with ultra low sulfur Swedish diesel fuel in a 1.7L common rail direct injection diesel engine. When injection timing is retarded at a certain exhaust gas recirculation rate, the particulate matter and nitrogen oxides decease simultaneously, while the hydrocarbon and carbon monoxide increase. Hydrocarbon speciation by gas chromatography using a flame ionization detector reveals that the ratio of partially burned hydrocarbon, i.e., mainly alkenes increase as the injection timing is retarded and exhaust gas recirculation is increased. The two most abundant hydrocarbon species are ethene which is a representative species of partially burned hydrocarbons, and n-undecane, which is a representative species of unburned hydrocarbons. They may be used as surrogate hydrocarbon species for performing a bench flow reactor test for catalyst development.