• Journal of ILASS-Korea
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• v.18 no.2
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• pp.94-99
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• 2013

The spherically-symmetric burning of an isolated droplet is a dynamic problem that involves the coupling of chemical reactions and multi-phase flow with phase change. For the improved understanding of these phenomena, this paper presents the numerical results on the n-heptane droplet combustion conducted at a 1 atm ambient pressure in three different initial droplet diameter ($d_0$). The main purpose of this study is to provide basic information of droplet burning, extinction and flame behavior of n-heptane and improve the ability of theoretical prediction of these phenomena. To achieve these, the numerical analysis was conducted in terms of normalized droplet diameter ($d/d_0$), flame diameter ($d_f$) and flame standoff ratio (FSR) under the assumptions that the droplet combustion can be described by both the quasi-steady behavior for the region between the droplet surface and the flame interface and the transient behavior for the region between the flame interface and ambient surrounding.

• Journal of ILASS-Korea
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• v.13 no.2
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• pp.91-98
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• 2008

In the present study, in order to understand the overall spray combustion characteristics of DME fuel as well as to identify the distinctive differences of DME combustion processes against the conventional hydrocarbon liquid fuels, the sequence of the comparative analysis have been systematically made for DME and n-heptane liquid fuels. To realistically represent the physical processes involved in the spray combustion, this studyemploys the hybrid breakup model, the stochastic droplet tracking model, collision model, high-pressure evaporation model, and transient flamelet model with detailed chemistry. Based on numerical results, the detailed discussions are made in terms of the autoignition, spray combustion processes, flame structure, and turbulence-chemistry interaction in the n-heptane and DME fueled spray combustion processes.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2000.11a
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• pp.39-48
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• 2000

• Applied Chemistry for Engineering
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• v.2 no.4
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• pp.411-420
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• 1991

The dehydrocyclization of n-heptane was studied over $Pt-Sn/{\gamma}-Al/_2O_3$ catalysts with varying Sn content in a fixed bed continuous flow reactor. The range of experimental conditions was at the temperature between 450 and $550^{\circ}C$, the pressure $20{\times}10^5-50{\times}10^5Pa$, the contact time 0.09 and 0.27 hr and the $H_2/H.C$. mole ratio 10. The conversion and selectivity of dehydrocyclization increased with increasing temperature, but decreased with increasing pressure. When we use Sn as a promoter, the selectivity of dehydrocyclization changesa a little, but the conversion was increased and the selectivity of isomerization increased a lot. The activation energy of dehydrocyclization of n-heptane was 34.5 kcal/mol over 0.6 wt % Pt-0.6 wt % $Sn/{\gamma}-Al_2O_3$.

• Journal of ILASS-Korea
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• v.21 no.1
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• pp.29-36
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• 2016

The effect of high ambient temperature and pressure conditions on the combustion performance of n-butanol, n-heptane and its mixing fuel (BH 20) were studied in this work. To reveal this, the closed homogeneous reactor model applied and 1000-1200 K of the initial temperature, 20-30 atm of initial pressure and 1.0 of equivalence ratio were set to numerical analysis. It was found that the results of combustion temperature was increased and the ignition delay was decreased when the ambient conditions were elevated since the combustion reactivity increased at the high ambient conditions. On the contrary, under the low combustion temperature condition, the combustion pressure was more influenced by the ambient temperature in the same ambient conditions. In addition, the total mass and the mass density of tested fuels were influenced by the ambient pressure and temperature. Also, soot generation of mixing fuel was decreased than n-heptane fuel due to the oxygen content of n-butanol fuel.

• Journal of the Korean Institute of Gas
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• v.20 no.2
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• pp.1-9
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• 2016

Combined removal of n-heptane and carbon monoxide (CO) using a plasma-catalytic process was investigated. The performance of the plasma-catalytic process was compared with that of the catalyst-alone process to characterize the decomposition of n-heptane and CO with the operation parameters such as the type of catalyst, reaction temperature, and discharge power. From several sets of experiments, it was found that the decomposition efficiency of n-heptane mainly depended on the specific input energy rather than the reactor temperature, whereas the oxidation of CO on both the energy density and the reaction temperature. The results conducted over several metal oxide catalysts exhibited that the decomposition efficiency of n-heptane was in the order: $Pd/{\gamma}-Al_2O_3$ > $Ru/{\gamma}-Al_2O_3{\approx}Ag/{\gamma}-Al_2O_3$. Especially, $Pd/{\gamma}-Al_2O_3$ catalyst did hardly generate CO as a byproduct during the decomposition of n-heptane under an appropriate condition, revealing $CO_2$ selectivity of nearly 100%. The CO oxidation efficiency was largely affected by the type of catalyst ($Pd/{\gamma}-Al_2O_3$ > $Ru/{\gamma}-Al_2O_3$ > $Ag/{\gamma}-Al_2O_3$). At temperatures below $180^{\circ}C$, the plasma-catalytic process was more effective in the oxidation of CO, while above $180^{\circ}C$, the catalytic process resulted in slightly higher CO oxidation efficiency.

• Journal of ILASS-Korea
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• v.16 no.4
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• pp.167-175
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• 2011

The HCCI engines have been known with high efficiency and low pollution and can be actualized as the new internal combustion engines. However, As for(??) the ignition and combustion depend strongly on the oxidation reaction of the fuel, so it is difficult to control auto-ignition timing and combustion duration. Purpose of this paper is creating the database for development of multi-dimensional simulation and investigating the influence of different molecular structure. In this research, the effect of n-heptane mole ratio in fuel (XnH) on the ignition delay from homogeneous charge compression ignition(HCCI) has been investigated experimentally. By varying the XnH, it was possible to ascertain whether or not XnH is the main resource of ignition delay. Additionally, the information on equivalence ratio for varying XnH was obtained. The tests were performed on a RCM (Rapid Compression Machine) fueled with n-heptane and iso-octane. The results showed that decreasing XnH (100, 30, 20, 10,0), the ignition delays of low temperature reaction (tL) and high temperature reaction (tH) is longer. And the temperature of reaction increases by about 30K. n-heptane partial equivalence ratio (fnH) affect on tL.and TL. When ${\phi}$nH was increased as a certain value, tL was decreased and TL was increased.

• Journal of ILASS-Korea
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• v.28 no.1
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• pp.32-42
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• 2023

In this study, spray characteristics of n-heptane and propane were investigated under different injection pressure using various imaging techniques such as Mie-scattering, DBI (diffuse back-illumination), and Schlieren imaging techniques. NI compact RIO system was used to control a test injector. Spray penetration length, length-to-width ratio and number of black pixels were calculated by using MATLAB software to compare spray characteristics of each fuel. Longer spray penetration length and higher length-to-width ratio were observed in propane spray because of flash boiling caused by high saturated vapor pressure. Spray collapse occurred in propane spray due to the high plume-to-plume interaction. Moreover, rapid evaporation occurred in propane spray, so that nozzle tip wetting could not be observed. Rapid evaporation of propane also caused fewer residual droplets compared to n-heptane spray. Therefore, propane is advantageous in reducing the generation of soot emission from large droplets that are not atomized. However, additional evaluation should be conducted considering combustion efficiency and the possibility of deposits by nozzle tip icing during fuel injection.

• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.245-248
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• 2014

• Fire Science and Engineering
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• v.31 no.3
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• pp.19-24
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• 2017

Flammable substances are used in laboratories and industrial process. The flash point (FP) is one of the most important physical properties used to determine the potential for characterizing the fire and explosion hazard of liquids. The FP data at 101.3 kPa were measured for the binary systems {toluene+ethylbenzene}, {methlycyclohenxane+ethylbenzene} and {n-heptane+ ethylbenzene}. The experiments were performed according to the standard test method (ASTM D 3278) using a SETA closed cup flash point tester. The measured FPs were compared with the values predicted using the following activity coefficient models: Wilson, Non-Random Two Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC). The average absolute deviation between the predicted and measured lower FP was less than 1.74 K.