• 제목/요약/키워드: muscovite

검색결과 213건 처리시간 0.022초

페그마타이트에서 산출하는 전기석의 운모화작용: 고분해능 투과전자현미경(HRTEM) 연구 (Sericitization of Tourmaline in a Pegmatite: a HRTEM Study)

  • 안중호;이정후
    • 한국광물학회지
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    • 제9권1호
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    • pp.7-16
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    • 1996
  • Partially sericitized tourmaline from a pegmatite, Black Hills, South Dakota, U.S.A., was investigated using high-resolution transmission electron microscopy (HRTEM). Muscovite occurs as the only alteration product of tourmaline, and it is developed extensively as narrow veinlets along the {110} and {100} cleavage directions of tourmaline, indicating that a cleavage-controlled alteration mechanism was dominant. Muscovite was characterized mainly as two-layer polytypes with minor stacking disorder, but tourmaline is almost free of structural defects. HRTEM images of tourmaline-muscovite interfaces revealed that the interfaces between two minerals are composed of well-defined {110} and {100} boundaries of tourmaline. The (001) of muscovite is in general parallel to the c-axis of tourmaline, but tourmaline and replacing muscovite do not show specific crystallographic orientation relationship; muscovite consists of numerous 100-1000$\AA$ thick subparallel packets, and the angles between the (001) of muscovite and (110) of tourmaline is highly variable. Al/Si ratios of both minerals suggest that tourmaline to muscovite alteration by late magnetic fluids has been facilitated by their similar Al/Si ratio in the incipient alteration stage, in that the hydration reaction with preservation of Al and Si would require only addition of K+ and H2O. Aluminous minerals other than muscovite were not characterized as the alteration products of tourmaline, indicating that tourmaline reacted directly to muscovite; the tourmaline alteration apparently occurred by the presence of residual fluids in which K+ is available and silica was not undersaturated.

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백운모광의 품위향상에 관한 연구 (A study on the Beneficiation of Muscovite Ore)

  • 이재장;최수용
    • 산업기술연구
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    • 제9권
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    • pp.29-41
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    • 1989
  • A general study on the upgrading of mica minerals which are mainly found in pegmatite deposits was carried out for the purpose of developing a technique for recovering mica in form of comercial grade products. By the way the grade one of about 5~6% $K_2O$ still is not developed. The target of this research work is to be establish a process for the efficient concentration of muscovite, containing more than 10% $K_2O$. The tests are applied to incraese the recovery and grade of concentrates in term of variations of conditions. The test sample consists of mainly muscovite and gangue mineral such as quartz, pyrite and chlorite. Decantation and shaking table tests were ineffective to up-grade this low grade one, but flotation method gave satisfactory result. By means of grade one, but flotation method gave satisfactory result. By means of grindability tests, an optimum result could be obtained from the sample ground to -48mesh feed size. The flotation result indicates that the dodecyl ammonium chloride used as a cationic collector is effective on the negatively charged surface, while the sodium dodecyl sulfate as an anionic collector is effective on the positively charged surface. Muscovite was floated by petroleum sulfonate as well as amine type collector, it also floated by MIBC as well as pine oil frother under well condition. Fine muscovite concentrates of about 10.68% $K_2O$ was obtained with 22.4% yield, by decantation, the muscovite concentrates of 10.10% $K_2O$ was obtained with 23.54% yield, by table concentration, the muscovite concentrates of 11.51% $K_2O$ was obtained with 23.0% yield by flotation.

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대현광산 견운모의 생성과정과 화학조성 및 폴리타잎 (Mineralogical Study of Sericite in the Daehyun Mine: Formation, Chemistry and Polytype)

  • 이병임;김수진
    • 한국광물학회지
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    • 제11권2호
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    • pp.69-84
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    • 1998
  • The Daehyun sericite deposit in socheon-myun, Bongwha-gun, Kyungsangbuk-do, Korea, has been formed by the hydrothermal alteration of the Hongjesa granite of Precambrian age, leaving the muscovite granite between ore body and the Hongjesa granite as the wall rock alteration zone. The process of sericitization of granitic rock as well as chemistry and structures of sericites were studied using polarizing microscope, X-ray diffractometer (XRD), electron probe microanalyzer (EPMA) and high resolution transmission electron microscope (HRTEM). There are two genetic types of sericites having different chemistry and structure. The early sericite is of 2M1 polytype and has octahedral composition close to muscovite. It has been formed from the primary muscovite, tourmaline and quartz under a relatively high temperature. The late sericite is of 1M, 2M1 and 3T polytypes and has phengitic composition. It has been formed form feldspar, biotite, muscovite and tourmaline under a relatively low temperature. Chemical analyses show t, the early sericite has less Mg+FeT content and lower Si/AlIV ratio in tetrahedral site than the late sericite.

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태백지역 만항층 셰일에서 산출되는 백운모-파이로필라이트 혼합상에 대한 연구 (A Study on the Muscovite-Pyrophyllite Mixed Phase in the Shale from the Manhang Formation, Taebaek Area)

  • 최승현;문향란;이영부;이정후
    • 한국광물학회지
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    • 제24권4호
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    • pp.313-320
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    • 2011
  • 강원도 태백지역에 분포하는 만항층 셰일의 운모류 층상규산염광물입자에 대한 EPMA 및 TEM 연구를 수행하였다. EPMA 분석에 의한 만항층 셰일 내 운모류 층상규산염광물의 평균 화학식은 $K_{1.35}(Fe_{0.18}Mg_{0.03}Al_{3.86})(Si_{6.55}Al_{1.45})O_{20}(OH)_4$이며, 이는 백운모의 이상화학식과 비교하면 층간 양이온인 K의 함량이 낮아서 일라이트에 가까운 조성을 갖는다. X-선 회절 분석에 의하면 만항층 셰일에서 파이로필라이트가 흔히 백운모와 함께 산출된다. TEM 격자상 관찰에 의하여 $10{\AA}$의 백운모와 $9.3{\AA}$의 파이로필라이트 층들이 단일 층 수준에서의 층간 혼합 및 층 내 혼합 현상이 동시에 관찰되었다. EPMA 분석에서 K 함량이 백운모에 비해 낮게 분석된 원인은 이처럼 입자 내에서 백운모와 파이로필 라이트가 밀접하게 공존하기 때문으로 판단된다.

백운모 내 리튬 함유에 대한 Fe 치환의 영향 (Effects of Fe Substitution on Lithium Incorporation into Muscovite)

  • 채진웅;권기덕
    • 한국광물학회지
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    • 제28권2호
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    • pp.127-133
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    • 2015
  • 리튬-함유 백운모는 삼팔면체 레피돌라이트(lepidolite)와 함께 화강암 페그마타이트 주변에서 발견되는 대표적인 리튬광물 중 하나이다. 백운모 결정구조를 고려하면 $Li^+$ 이온은 층간 $K^+$ 자리(Int)에 위치하거나 $Al^{3+}$ 팔면체층의 원자 빈자리(Sub)에 위치할 수 있지만, 실험만으로 백운모의 리튬 함유기작을 규명하는데 어려움이 있다. 이번 연구에서는 밀도범함수(density functional theory, DFT)를 사용하여 백운모 결정구조 내에 $Li^+$이 함유되는 위치와 이에 따른 미시적 구조 및 에너지 변화를 조사하였다. $Li^+$이 Int 또는 Sub에 위치할 경우, 운모의 결정상수, ab 면과 가지는 수산기의 각, 층간 거리 등 상당한 차이를 보여주었다. 뿐만 아니라, DFT 에너지 계산은 순수 백운모 구조에서는 $Li^+$$K^+$를 대신하여 Int에 위치하는 것이 Sub에 위치하는 것보다 더 낮은 에너지를 보여주었다. 그러나 팔면체층에 $Fe^{2+}$ 치환이 일어난 경우에는, $Li^+$이 Sub에 위치하는 것이 오히려 더 낮은 에너지를 보여주었다. 이번 DFT 연구결과는 기존의 $Li^-$함유 백운모 화학분석으로부터 발견한 $Fe^{2+}$$Li^+$의 상관관계를 설명해 줄 수 있으며, 백운모의 $Li^+$ 함유기작에서 팔면체층의 양이온 치환의 중요한 역할을 제시한다.

석포(石浦)-덕구간(德邱間)에 분포(分布)하는 소위(所謂) 홍제사화강암(洪濟寺花崗岩)의 지질연대(地質年代)와 생성과정(生成過程)에 대(對)한 硏究(연구) (Geochronology and Petrogenetic processes of the so-called Hongjesa granite in the Seogpo-Deogku Area)

  • 김용준;이대성
    • 자원환경지질
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    • 제16권3호
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    • pp.163-221
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    • 1983
  • Main aspects of this study are to clarify geochronology and petrogenetic processes of the so-called Hongjesa granite, which is a member of various intrusive rocks exposed in the northeastern part of the Ryongnam Massif, one of the Precambrian basements of South Korea. In this study, the Hongjesa grainte is divided into four rock units based on the geologic age, mineralogical and chemical constituents, and texture: the Precambrian Hongjesa granite gneiss (Hongjesa granite Proper) and leucogranite gneiss, the Paleozoic gnessic two mica granite, and the Jurassic muscovite granite. The Hongjesa granite gneiss is identified by its grayish color, slight foliation, and porphyroblastic texture. The leucogranite gneiss is distinct by its light gray color, sand medium to coarse grained texture. The gneissic two mica granite is distinguished from others by its strong foliation, containing gray-colored feldspar phenocrysts with biotite and muscovite in varying amounts. The muscovite granite occurs as a small stock containing feldspar phenocrysts along margin of the stock. These granitic rocks vary widely in composition, reflecting the facts that they partly include highly metamorphosed xenolith and schlierens as relics of magmatic and anatectic processes. In particular, grayish porphyroblasts of microcline perthite is characteristic of the Hongjesa granite gneiss, whereas epidote and garnet occur in both the Hongjesa granite gneiss and leucogranite gneiss. These minerals are considered to be formed by potassic metasomatism and contamination of highly metamorphosed rocks deeply buried under the level of the Hongjesa granite emplacement. The individual synchronous granitic rocks plotted on Harker diagram show mostly similar trends to the Daly's values. The plots of the Hongjesa granite gneiss and gneissic two mica granite concentrate near the end part of the calc-alkalic rock series on the AMF diagrams, whereas those of the leucogranite gneiss and muscovite granite indicate the trend of the Skaergaard pluton. These granitic rocks plotted on a Q-Ab-Or diagram (petrogeny's residua system) fall well outside the trough of the system. This can be attributed to the potassic matasomatism of these rocks. On the ACF diagram, these rocks appear to be dominantly I-type prevailing over S-type. The K-Ar ages, obtained from a total of 7 samples of the leucogranite gneiss, gneissic two mica granite, muscovite granite, porphyritic alkali granite, and rhyolitic rock, in addition to the Rb/Sr ages of the Hongjesa granite gneiss by previous workers, permit the rock units to be arranged in the following chronological order: The middle Proterozoic Hongjesa granite gneiss (1714-1825 m.y.), the upper proterozoic leucogranite gneiss (875-880 m. y.), the middle Paleozoic gneissic two mica granite (384 m. y.) the upper Jurassic muscovite granite (147 m. y.), the Eocene alkali granite (52 m. y.), and the Eocene rhyolitic rock (45 m. y.). From the facts and data mentioned above, it is concluded that the so-called Hongjesa granite is not a single granitic mass but is further subdivided into the four rock units. The Hongjesa granite gneis, leucogranite gneiss, and gneissic two mica granite are postulated to be either magmatic or parautochtonous, intrusive, and the later muscovite granite is to be magmatic in origion.

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유성(儒城) 서북부(西北部) 우산봉(雨傘峰) 일대(一帶)에 분포(分布)하는 화강암(花崗巖) 복합체(複合體)의 암석학적(岩石學的) 연구(硏究) (Petrology of Granitic Complex Distributed in the Woosanbong area, northwestern part of Yuseong)

  • 김승호;이대성
    • 자원환경지질
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    • 제14권3호
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    • pp.123-142
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    • 1981
  • Granitic complex in the Woosanbong area is composed of schistose granite, two-mica granite, biotite granite, porphyritic granite and pink feldspar granite in order of intrusion. In their boundary aspects, the gradational change between porphyritic granite and pink feldspar granite is observed in field relations. All the granites of the complex are classified to quartz monzonite by the modal compositions following Bateman's classification (1961) with the exception of pink feldspar granite which belongs to granite according to the petrographical classification. The first three granites are characterized by highly development of vein and/or lens-like pegmatites in their bodies, and two others contain green hornblende uniquely. These leucocratic two-mica granite shows an unusual character in ratio of muscovite to biotite 1: 0.7 to 1:13, and contains dominantly microcline. The content of muscovite varies in places in the field. Under the polarizing microscope it is revealed that the muscovite flakes occur as the products altered from biotite partly or completely, and it usually associates with chlorite flakes nearby. These features, therefore, suggests that biotite probably has been altered to muscovite and chlorite by hydration during deuteric processes. At the same stage, sericitization of plagioclase by the hydrolytic decomposition, and transformation of orthoclase to microcline may be taken place. Accordingly, it is obviously permissible to consider the two-mica granite as a kind of 'apo-granite' by deuteric alterations during the consolidation of magma.

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전라북도 오수-진안 지역에 분포하는 변성퇴적암류에 대한 변성작용 (Metamorphism of the Meta-Sedimentary Rocks in the Osu-Jinan Area, Cheonrapuk-Do, Korea)

  • 안건상;김용준;신인현
    • 자원환경지질
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    • 제30권2호
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    • pp.163-174
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    • 1997
  • Precambrian metapelites and metapsammites of the Jinan-Osu area (so-called Seologri and Yongamsan Formation) consist of black slate, phyllite, mica schist, quartzite and rarely calc schist. They are intruded by Sunkagsan granite gneiss, Foliated granodiorite, Amphibolite, Sunchang foliated granite and Namwon granite. Mylonite texture, crenulation cleavage and minor shear zone are common. The meta-sedimentary rocks include various rock-fragments xenoliths in size (up to 3 cm) and rock-type. They have various porphyroblastic spots in size (up to 1 cm) and their mineral composition is different. The xenoliths are schists, granite and quartzite, which are rectangular or lens form and recrystallized muscovite, chlorite and quartz. Spots are andalusite and biotite aggregates extensively replaced by chlorite. The metamorphic terrain is divided into three zones of progressive metamorphism on the basis of mineral assemblage. They are chlorite zone, chloite-biotite zone and andalusite-biotite zone ascending order, from west to east approximately. Isograd reactions are phengitic muscovite + chlorite = less phengitic muscovite + biotite + quartz + $H_2O$ and muscovite + chlorite + quartz = andalusite + biotite + $H_2O$ between the chlorite zone and chlorite-biotite zone, and between the chloritebiotite zone and andalusite-biotite zone, respectively. Sample B6 (exposed near the Obong-ri) includes staurolites and greenish biotites, that is different in mineral assemblage and chemical composition from the meta-sedimentary rocks. Sample A12 (exposed near the Shinam-ri) has greenish white spots (up to 1 cm in diameter) mainly composed of Kfeldspar, quartz and sillimanite replaced by muscovite.

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순경(順鏡) 함주석(含朱錫) 페그마타이트의 K-Ar연령(年齡) (K-Ar age of the Tin-bearing Pegmatite In Sungyeong Mine)

  • 진명식;김성재
    • 자원환경지질
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    • 제21권2호
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    • pp.171-174
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    • 1988
  • 상동(上東) 광산(鑛山) 주위(周圍)에 분포(分布)되어 있는 순경(順鏡) 함주석(含朱錫)페그마타이트에서 백운모(白雲母) 및 사장석(斜長石)으로부터 변질(變質)된 견운모(絹雲母)를 채취(採取)하여, K-Ar법(法)으로 각(各) 광물(鑛物)의 연령(年齡)을 측정(測定)하였다. 백운모(白雲母)는 $1546.94{\pm}29.4\;Ma$, 그리고 견운모(絹雲母)는 $187.80{\pm}4.19\;Ma$로 밝혀졌다. 이 백운모(白雲母)의 연령(年齡)은 이 지역일대(地域一帶)에 분포(分布)되어 있는 다른 페그마타이트 내(內)의 백운모(白雲母)의 K-Ar 연령(年齡)보다는 젊은 것으로 나타났는데, 이는 페그마타이트내(內)에 있는 사장석(斜長石)이 견운모화(絹雲母化)될 때(약(約) 190Ma 경(頃)), 열수(熱水)의 열(熱)에 의(依)하여 백운모내(白雲母內)의 방사성원(放射性源) 알곤(40 Ar)이 일부(一部) 유실(流失)된 때문이라고 해석(解釋)된다.

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복운모 화강암의 암석화학적 특징 : 청산, 인제-홍천, 영주 및 남원지역의 예 (Petrological Characteristics of Two-Mica Granites : Examples from Cheongsan, Inje-Hongcheon, Yeongju and Namwon areas)

  • 좌용주
    • 암석학회지
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    • 제6권3호
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    • pp.210-225
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    • 1997
  • 청산, 인제-홍천, 영주 및 남원지역에 분포하는 복운모 화강암은 과알루미나질이며, 일반적으로 S-타입 및 티탄철석계열의 화강암류임을 나타내어, 지각물질로부터 유래된 마그마가 환원 환경에서 관입.고결하여 생성된 것이다. 인제-홍천과 남원 지역의 복운모 화강암은 각각 반상 흑운모 화강암과 높은 Ti/Mg 비의 흑운모 화강암으로부터 분화.파생된 잔류 마그마로부터 형성되었다. 청산과 영주지역의 복운모 화강암은 접촉하고 있는 반상 흑운모 화강암과, 화강섬록암과는 각각 성인적인 관련이 없을 것으로 판단된다. 남원과 영주지역 복운모 화강암은 비교적 물에 포화된 마그마로부터 형성되었고, 청산과 인제-홍천지역 복운모 화강암질 마그마는 물에 불포화 되었음이 나타난다. 한편, 물에 포화되었던 남원지역의 흑운모 화강암과 복운모 화강암에 있어 마그마 내의 물의 함량은 5.8wt.%이상으로 추정되고, 영주 목운모 화강암질 마그마의 경우 2.4~5.8wt.%정도의 물을 포함했을 것으로 생각할 수 있다. 인제-홍천과 영주지역의 복운모 화강암의 최소융해액 조성으로 구해지는 압력 (0.5~2kb)과 세립질 내지 극세립질의 암석 조직은 화강암질 마그마가 지각의 얕은 곳에서 관입.배태된 양상을 나타내며, 청산과 남원지역의 복운모 화강암의 경우 최소융해액 조성 압력(2~3 kb)과 세립~중립질 내지 조립질의 암석 조직으로부터 비교적 지하 심부에 관입.배태외었음을 알 수 있다. 화강암질 마그마의 고상선/백운모의 안정선의 교점으로부터 물에 포화된 마그마에서는 최소한 약 1.6kb (약 6km)이상의 압력에서 마그마기원의 1차 백운모가 정출될 수 있으며, 그 이하에서는 고상선 아래에서 교대작용으로 2차적인 백운모가 형성된다. 반면, 물에 불포화된 마그마에서 1차 백운모가 정출되기 위해서는 보다 놓은 압력이 요구된다. 백운모 형성에 대한 이 조건은 각 지역 복운모 화강암에 산출되는 백운모에 1차 백운모와 2차 백운모 양쪽이 나타남을 설명하기에 충분하다. 한편, 실험으로 구해진 백운모의 안정선의 적용에는 주의가 필요하고, 특히 순수한 합성 백운모 단성분을 이용한 실험의 경우 팔면체 배위에 Ti, Fe, Mg의 성분이 첨가됨에 따라 안정선이 높은 온도 영역으로 이동됨을 고려해야 한다.

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