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Self-Organization of Dendron-Poly(ethylene glycol) Conjugates in an Aqueous Phase

  • Kim, Kyoung-Taek;Lee, Im-Hae;Park, Chiyoung;Song, Yu-Mi;Kim, Chul-Hee
    • Macromolecular Research
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    • v.12 no.5
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    • pp.528-533
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    • 2004
  • We have prepared amide dendrons having alkyl peripheral units and various focal moieties through a convergent synthetic approach. The amphiphilic properties, due to hydrophilic amide branches and the hydrophobic peripheral units, provide an opportunity for the amide dendrons to self-organize in water. The dendritic architecture itself is also one of the critical factors in the self-organization of the amide dendrons in water. In particular, function-alization was performed at the focal point to elucidate the relationship between the focal functionality and the self-organized structures of the dendritic building blocks in the aqueous phase. The dendron having a short poly(ethylene glycol) monomethyl ether (MeO-PEG) unit (M$\_$n/ =750) as the focal moiety formed a vesicular organization in water. As the size of the hydrophilic focal MeO-PEG increased to M$\_$n/ =2,000 and 5,000, the self-organized structures became rod-type and spherical micelles, respectively. Our observation of multiple morphologies for amide dendrons is in good agreement with previous reports that indicated that the micellar structures changed from vesicles to rod-types and then to spheres upon increasing the size of the hydrophilic moiety of the amphiphiles.

CO2 Removal using MEA (monoethanolamine) Impregnated Mesoporous Materials (MEA (monoethanolamine) 함침 메조포러스 물질을 이용한 CO2 회수)

  • Park, Ye-Won;Baek, Il-Hyun;Park, Sang-Do;Lee, Jae-Wook;Park, So-Jin
    • Korean Chemical Engineering Research
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    • v.45 no.6
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    • pp.573-581
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    • 2007
  • The present study deals with removal of $CO_2$ using various mesoporous materials impregnated with MEA (monoethanolamine). The mesoporous materials such as MCM-41, MCM-48 and SBA-15 were synthesised and then impregnated with 30, 50 and 70 wt% of MEA, respectively. XRD, FT-IR and SEM were used to evaluate the characterization of those. From the adsorption/desorption experiments for various materials, the adsorption capacity of these materials were found in the order of MCM-41> MCM-48> SBA-15. MCM-41 impregnated with 50 wt% of MEA showed the maximum adsorption capacity of $57.1mg-CO_2/gr-sorbent$ at $40^{\circ}C$. It is nearly 8 times higher than MCM-41 without impregnation of MEA. In the multiple cycle test of 20 times, MCM-41 impregnated with 50 wt% of MEA showed a constant adsorption capacity.

Cloning of the Large Subunit of Replication Protein A (RPA) from Yeast Saccharomyces cerevisiae and Its DNA Binding Activity through Redox Potential

  • Jeong, Haeng-Soon;Jeong, In-Chel;Kim, Andre;Kang, Shin-Won;Kang, Ho-Sung;Kim, Yung-Jin;Lee, Suk-Hee;Park, Jang-Su
    • BMB Reports
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    • v.35 no.2
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    • pp.194-198
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    • 2002
  • Eukaryotic replication protein A (RPA) is a single-stranded(ss) DNA binding protein with multiple functions in DNA replication, repair, and genetic recombination. The 70-kDa subunit of eukaryotic RPA contains a conserved four cysteine-type zinc-finger motif that has been implicated in the regulation of DNA replication and repair. Recently, we described a novel function for the zinc-finger motif in the regulation of human RPA's ssDNA binding activity through reduction-oxidation (redox). Here, we show that yeast RPA's ssDNA binding activity is regulated by redox potential through its RPA32 and/or RPA14 subunits. Yeast RPA requires a reducing agent, such as dithiothreitol (DTT), for its ssDNA binding activity. Also, under non-reducing conditions, its DNA binding activity decreases 20 fold. In contrast, the RPA 70 subunit does not require DTT for its DNA binding activity and is not affected by the redox condition. These results suggest that all three subunits are required for the regulation of RPA's DNA binding activity through redox potential.

Effect of Multiple Reflows on Mechanical and Electrical Properties of ENIG/Sn-3.5Ag/ENIG Ball Grid Array (BGA) Solder Joint (리플로우 횟수가 ENIG/Sn-3.5Ag/ENIG BGA 솔더 조인트의 기계적, 전기적 특성에 미치는 영향)

  • Sung, Ji-Yoon;Pyo, Sung-Eun;Koo, Ja-Myeong;Yoon, Jeong-Won;Noh, Bo-In;Won, Sung-Ho;Jung, Seung-Boo
    • Journal of the Microelectronics and Packaging Society
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    • v.16 no.1
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    • pp.7-11
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    • 2009
  • In this study, solder joints were made with Sn-3.5Ag (wt%) solder ball. Electroless nickel / immersion gold (ENIG) printed circuit board (PCB) substrates were employed in this work. The mechanical and electrical properties were measured as a function of the number of reflow. Die shear strength was measured with increasing reflow number. Until the forth or fifth reflow, shear force increased and after the fifth reflow the shear force of die decreased. The electrical resistivity of solder joint linearly increased with increasing reflow number.

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Smart Roll Forming Based on Real-Time Process Data (실시간 공정데이터 기반의 스마트 롤포밍에 관한 연구)

  • Son, Jae-Hwan;Cho, Dong-Hyun;Kim, Chul-Hong
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.5
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    • pp.45-51
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    • 2018
  • Roll forming refers to the production of long plate-molded products, such as panels, pipes, tubes, channels, and frames, by continuously causing the bending deformation to thin plates using rotating rolls. As the roll forming method has advantages in terms of mass production because of its excellent productivity, the size of the roll forming industry has been continuously increasing and the roll forming method is increasingly being used in diverse industrial fields as a very important processing method. Furthermore, as the roll forming method mainly depends on the continuous bending deformation of the plate materials, the time and the cost of the heterogeneous materials developed in the process are relatively large when considered from the viewpoint of plastic working because many processes are continuously implemented. The existing studies on roll forming manufacturing have reported the loss of large amounts of time and materials when the raw materials or product types were changed; further, they have stated that the use of this method can hardly guarantee the uniformity of the formed shapes and the consistency in terms of size and cannot detect all the defects occurring during the mass production and related to the dimensions. Therefore, in this research, a real-time process data-based smart roll forming method that can be applied to multiple products was studied. As a result, a roll forming system was implemented that remembers and automatically sets the changes in the finely adjusted values of the supplied quantities of individual heterogeneous materials so that the equipment setting changing time for heterogeneous material replacements or changes in the products being produced can be shortened. It also secures the uniformity of the products so that more competitive and precise slide-rail products can be mass-produced with improvements in the quality, price, and productivity of the products.

Particle removal characteristics of high-velocity electrostatic mist eliminator (정전 고속 미스트 엘리미네이터의 포집 효율 특성)

  • Kim, Jin-seon;Kim, Hak-Joon;Han, Bangwoo;Woo, Chang Gyu;Kim, Yong-Jin;Lee, Sangrin;Moon, Sangchul
    • Particle and aerosol research
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    • v.14 no.4
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    • pp.121-133
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    • 2018
  • In this study, we developed a flat-plate type wet electrostatic precipitator that generates stable corona discharge compared to wire type discharge electrode. In order to compare the particle removal efficiency according to the shape of the discharge electrode such as the variation of the horizontal and vertical distance between spiked edges, and the variation of the height of discharge pin support were tested. As a result, when the horizontal distance between spiked edges was increased up to 36 mm, the vertical distance between spiked edges was increased up to 54 mm, and the height of the discharge pin support was increased up to 76 mm, the removal efficiency of PM10 was maintained at approximate 60.0%. Furthermore, the removal efficiency of particles over $5{\mu}m$ was about 80% or more. When the flow rate was 4 m/s, the gap between collection plates was 60 mm, and -14 kV was applied to the discharge electrode. The particle removal efficiency of the flat-plate type electrostatic precipitator was maintained when the horizontal and vertical distance between spiked edges, and the height of the discharge pin support was below a certain level. Those variables may be the important design factors for the shape of the discharge electrode. Therefore, when designing the electrostatic precipitator with multiple channels, the horizontal and vertical distance between spiked edges, and the height of discharge pin support must be selected in consideration of the weight of the discharge electrode and the processing cost.

A Study on the Microstructure and Anisotropic Mechanical Properties of Oxygen-Free Copper Fabricated by Equal Channel Angular Pressing (ECAP공법으로 제조된 무산소동의 미세조직 및 기계적 성질 이방성에 대한 고찰)

  • Lee, Jaekun;Hong, Younggon;Kim, Hyoungseop;Park, Sunghyuk
    • Journal of the Korea Institute of Military Science and Technology
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    • v.22 no.4
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    • pp.492-500
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    • 2019
  • Equal channel angular pressing(ECAP) is a severe plastic deformation technique capable of introducing large shear strain in bulk metal materials. However, if an ECAPed material has an inhomogeneous microstructure and anisotropic mechanical properties, this material is difficult to apply as structural components subjected to multi-axial stress during use. In this study, extruded oxygen-free copper(OFC) rods with a large diameter of 42 mm are extruded through ECAP by route Bc up to 12 passes. The variations in the microstructure, hardness, tensile properties, and microstructural and mechanical homogeneity of the ECAPed samples are systematically analyzed. High-strength OFC rods with a homogeneous and equiaxed-ultrafine grain structure are obtained by the repeated application of ECAP up to 8 and 12 passes. ECAPed samples with 4 and 8 passes exhibit much smaller differences in terms of the average grain sizes on the cross-sectional area and the tensile strengths along the axial and circumferential directions, as compared to the samples with 1 and 2 passes. Therefore, it is considered that the OFC materials, which are fabricated via the ECAP process with pass numbers of a multiple of 4, are suitable to be applied as high-strength structural parts used under multi-axial stress conditions.

The Effects of information security perceptions of collaborative system managers on intention to use SBOM(Software Bill Of Materials) : Focusing on the Theory of Planned Behavior (협업시스템 담당자의 정보보안 인식이 SBOM(Software Bill Of Materials) 도입 의도에 미치는영향: 계획된 행동이론을 중심으로)

  • Noh Hyeyoung;Lee Sin-Bok
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.5
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    • pp.463-474
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    • 2023
  • Advances in technology have made it easier for organizations to share information and collaborate. However, collaboration systems where multiple entities share and access information are vulnerable to security. The concept of Software Bill Of Materials (SBOM) has emerged as a way to strengthen information security by identifying and transparently managing the components of software programs. To promote the adoption of SBOM in Korea, this study investigated the intention to use of collaboration system managers. This study was based on the theory of planned behavior and the integrated technology acceptance theory. The results of this study confirmed that performance expectations from SBOM adoption were an important variable for intention to use, and positive attitudes toward security also had an indirect effect through performance expectations. We found that SBOM adoption has an important causal relationship with performance due to the fact that it is targeted at enterprises, and that positive attitudes toward security and social climate can have a strong effect on intention to use.

IN VITRO STUDY ON EXOTHERMIC REACTION OF POLYMER-BASED PROVISIONAL CROWN AND FIXED PARTIAL DENTURE MATERIALS MEASURED BY DIFFERENTIAL SCANNING CALORIMETRY

  • Ko, Mun-Jeung;Pae, Ahran;Kim, Sung-Hun
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.6
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    • pp.690-698
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    • 2006
  • Statement of problems. The heat produced during polymerization of polymer-based provisional materials may cause thermal damage to the vital pulp. Purpose. This study was performed to evaluate the exotherm reaction of the polymerbased provisional materials during polymerization by differential scanning calorimetry and to compare the temperature changes of different types of resins. Material and methods. Three dimethacrylate-based materials (Protemp 3 Garant, Luxatemp Plus, Luxatemp Fluorescence) and five monomethacrylate- based material (Snap, Alike, Unifast TRAD, Duralay, Jet) were selected. Temperature changes of polymer-based provisional materials during polymerization in this study were evaluated by D.S.C Q-1000 (TA Instrument, Wilmington, DE, USA). The following three measurements were determined from the temperature versus time plot: (1) peak temperature, (2) time to reach peak temperature, (3) heat capacity. The data were statistically analyzed using one-way ANOVA and multiple comparison Bonferroni test at the significance level of 0.05. Results. The mean peak temperature was $39.5^{\circ}C({\pm}\;1.0)$. The peak temperature of the polymer-based provisional materials decreased in the following order: Duralay > Unifast TRAD, Alike > Jet > Luxatemp Plus, Protemp 3 Garant, Snap, Luxatemp Fluorescence. The mean time to reach peak temperature was 95.95 sec $({\pm}\;64.0)$. The mean time to reach peak temperature of the polymer-based provisional materials decreased in the following order: Snap, Jet > Duralay > Alike > Unifast TRAD > Luxatemp Plus, Protemp 3 Garant, Luxatemp Fluorescence. The mean heat capacity was 287.2 J/g $({\pm}\;107.68)$. The heat capacity of the polymer-based provisional materials decreased in the following order: Duralay > TRAD, Jet, Alike > Snap, Luxatemp Fluorescence, Protemp 3 Garant, Luxatemp Plus. Conclusion. The heat capacity of materials, determined by D.S.C., is a factor in determining the thermal insulating properties of restorative materials. The peak temperature of PMMA was significantly higher than others (PEMA, dimethacrylate). No significant differences were found among PEMA (Snap) and dimethacrylate (P >0.05). The time to reach peak temperature was greatest with PEMA, followed by PMMA and dimethacrylate. The heat capacity of PMMA was significantly higher than others (PEMA, dimethacrylate). No significant differences were found among PEMA and dimethacrylate (P >0.05).

Fabrication of the Imaging Lens for Mobile Camera using Embossing Method (엠보싱 공법에 의한 카메라 모듈용 광학렌즈 성형기법에 대한 연구)

  • Lee, C.H.;Jin, Y.S.;Noh, J.E.;Kim, S.H.;Jang, I.C.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.05a
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    • pp.79-83
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    • 2007
  • We have developed a compact and cost-effective camera module on the basis of wafer-scale replication technology. A multiple-layered structure of several aspheric lenses in a mobile camera module is first assembled by bonding multiple glass-wafers on which 2-dimensional replica arrays of identical aspheric lenses are UV-embossed, followed by dicing the stacked wafers and packaging them with image sensor chips. We have demonstrated a VGA camera module fabricated by the wafer-scale replication processing with various UV-curable polymers having refractive indices between 1.4 and 1.6, and with three different glass-wafers of which both surfaces are embossed as aspheric lenses having 200 um sag-height and aspheric-coefficients of lens polynomials up to tenth-order. We have found that precise compensation in material shrinkage of the polymer materials is one of the most technical challenges, in order to achieve a higher resolution in wafer-scaled lenses for mobile camera modules.

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