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CO2 Removal using MEA (monoethanolamine) Impregnated Mesoporous Materials  

Park, Ye-Won (Greenhouse Gas Research Center)
Baek, Il-Hyun (Greenhouse Gas Research Center)
Park, Sang-Do (Carbon Dioxide Reduction & Sequestration R&D Center, Korea Institute of Energy Research)
Lee, Jae-Wook (Department of Biochemical Engineering, Chosun University)
Park, So-Jin (Department of Bio-Applied Chemistry, Chungnam National University)
Publication Information
Korean Chemical Engineering Research / v.45, no.6, 2007 , pp. 573-581 More about this Journal
Abstract
The present study deals with removal of $CO_2$ using various mesoporous materials impregnated with MEA (monoethanolamine). The mesoporous materials such as MCM-41, MCM-48 and SBA-15 were synthesised and then impregnated with 30, 50 and 70 wt% of MEA, respectively. XRD, FT-IR and SEM were used to evaluate the characterization of those. From the adsorption/desorption experiments for various materials, the adsorption capacity of these materials were found in the order of MCM-41> MCM-48> SBA-15. MCM-41 impregnated with 50 wt% of MEA showed the maximum adsorption capacity of $57.1mg-CO_2/gr-sorbent$ at $40^{\circ}C$. It is nearly 8 times higher than MCM-41 without impregnation of MEA. In the multiple cycle test of 20 times, MCM-41 impregnated with 50 wt% of MEA showed a constant adsorption capacity.
Keywords
Carbon Dioxide; MEA (monoethanolamine); Mesoporous Material; Removal;
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Times Cited By KSCI : 2  (Citation Analysis)
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1 Kim, Y. S. and Ko, H. S., 'Preparation and Characterization of Surface Modified Mesoporous Silicate as $CO_{2}$ Adsorbents,' Appl. Chem., 9(2), 297-240(2005)
2 Macario, A., Katovic, A., Giordano, G., Iucolano, F. and Caputo, D., 'Synthesis of Mesoporous Materials for Carbon Dioxide Sequestration,' Micro. Meso. Mater., 81, 139-147(2005)   DOI   ScienceOn
3 Lee, I. H., Kim, S. I. and Park, J. Y., 'Methane Recovery and Carbon Dioxide Striooing by MEA Solution the Autocirculation Bubble Life Column Reactor,' Ind. Chem., 18(3), 239-244(2007)   DOI
4 Xu, X., Song, C., Miller, B. G. and Scaroni, A. W., 'Adsorption Separation of Carbon Dioxide from Flue Gas of Natyral Gas-Fired Boiler by a Novel Nanoporous Molecular Basket Adsorbent,' Fuel process. Tech., 86, 1457-1472(2005)   DOI   ScienceOn
5 Knofel, C., Descarpentries, J., Benxaouia, A., Zelenak, V., Mornet, S., Llewellyn, P. L. and Hornebecq, V., 'Functionalised Micro-/mesoporous Silica for the Adsorption of Carbon Dioxide,' Micro. Meso. Mater., 99, 79-85(2007)   DOI   ScienceOn
6 Jung, H. J., Cha, J. H., Lee, T. J. and Sur, G. S., 'A Study on the Polyethylenimine/MCM-41 Composite,' Appl, Chem., 7(2), 471-474(2003)
7 Brunauer, S., Emmett, P. and Teller, E., 'Adsorption of Gases in Multimolecular Layer,' Arner. Chem. Soc., 60, 309(1938)   DOI
8 Park, H. K., Park, H. J. and Kang, B. S., 'Statue of $CO_{2}$ Recovery Technology,' DCER Techinfo part I, 3(7), 100-113(2004)
9 Jeon, H. J., 'Principle of Catalyst,' Hanlimwon Co.(2002)
10 Lee, J. W., Shim, W. G. and Moon, H., 'Adsorption Equilibrium and Kinetics for Capillary Condensation of Trichloroethylene on MCM-41 and MCM-48,' Micro. Meso. Mater., 73, 109-119(2004)   DOI   ScienceOn
11 Battett, E. P., Joynez, L. G. and Halenda, P. P., 'The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms,' J. Amer. Chem. Soc., 73, 373(1951)   DOI
12 Cho, S. H., 'Principle and Application of Adsorbent,' Jigumoonwha Co.(2006)
13 Drage, T. C., Smith, K. M., Arenillas, A., Blackman. J. M. and Sanpe, C. E., 'Development of Strategies for the Regeneration of Polyethylenimine Based $CO_{2}$ Adsorbents,' Prepr. Pap.-Am. Chem. Soc., Div. Fuel Chem., 51(1), 112(2006)
14 Drage, T. C., Arenillas, A., Smith, K. and Snape, C. E., 'Comparison of Pre and Post-combustion $CO_{2}$ Adsorbent Technologies,' GHGT, 8(2006)
15 Hiyoshi, N., Yogo, K. and Yashima, T., 'Adsorption Characteristics of Carbon Dioxide on Organically Functionalized SBA-15,' Micro. Meso. Mater., 84, 357-365(2005)   DOI   ScienceOn
16 Kim, J. M., 'Synthsis and Application of Mesoporous Materials', Physic and Advanced Technology, July/August, 12-17(2004)
17 Xu, X., Song, C. and Andresen, J. M., 'Preparation and Characterization of Novel $CO_{2}$ Molecular Basket Adsorbents Based on Polymer-modified Mesoporous Molecular Sieve MCM-41', Micro. Meso. Mater., 62, 29-45(2003)   DOI   ScienceOn
18 Ruihong, Z., Fen. G., Yongqi, H. and Huanqi, Z., 'Self-assembly Synthesis of Organized Mesoporous Alumina by Pricipitation Method in Aqueous Solution,' Micro. Meso. Mater., 93, 212-216(2006)   DOI   ScienceOn
19 Lee, J. W., Shim, W. G. and Moon, H., 'Application of Mesoporous MCM-48 and SBA-15 Materials for the Separation of Biochemicals Dissolved in Aqueous Solution,' Korean J. Chem. Eng., 21(1), 246-251(2004)   DOI
20 Vinu, A., Mori, T. and Ariga, K., 'New Families of Mesoporous Materials,' Science Tech.. Adv. Mater., 7, 753-771(2006)   DOI   ScienceOn
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