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Observation of Carrier Multiplication via Internal Quantum Efficiency Exceeding 100% in PbS QDs Monolayer Solar Cells

  • Park, So Yeon;Chung, Hyun Suk;Han, Gill Sang;Su, Jang Ji;Jung, Hyun Suk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.467.1-467.1
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    • 2014
  • Quantum dots (QD) solar cells has received considerable attention due to their potential of improving the overall conversion efficiency by harvesting excess energy via multiple excitons generation (MEG). Although there have been many reports which show MEG phenomena by using optical measurement of quantum dots themselves, carrier multiplication in real QD photovoltaic devices has been sparsely reported due to difficulty in dissociation of excitons and charge collection. In this reports, heterojunction QD solar cells composed of PbS QD monolayer on highly crystalline $TiO_2$ thin films were fabricated by using Langmuir-Blodgett deposition technique to significantly reduce charge recombination at the interfaces between each QD. The PbS CQDs monolayer was characterized by using UV-vis, transmission electron microscopy (TEM) and atomic force microscopy (AFM). The internal quantum efficiency (IQE) for the monolayer QD solar cells was obtained by measurement of external quantum efficiency and determining light absorption efficiency of active layer. Carrier multiplication was observed by measuring IQE greater than 100% over threshold photon energy. Our findings demonstrate that monolayer QD solar cell structure is potentially capable of realizing highly efficient solar cells based on carrier multiplication.

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Substantial Enhancement of the Response and Sensing Speed of WO3 Nanotubes Toward NO2 Gas by Au-functionalization

  • Ko, Hyunsung;Park, Sangbo;Hong, Taeseop;Park, Sunghoon;Lee, Chongmu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.369.1-369.1
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    • 2014
  • Au-functionalized $WO_3$ nanotubes were synthesized using ZnO nanowire templates. Transmission electron microscopy revealed the Au nanoparticles on the outer surface of a typical $WO_3$ nanotube ranged from 5 to 25 nm. The multiple networked Au-functionalized $WO_3$ nanotube sensors showed responses of 820-3, 924% in the $NO_2$ concentration range of 1-5 ppm at $300^{\circ}C$. These responses were approximately 5-12 fold higher than those observed for pristine $WO_3$ nanotube sensors over the same $NO_2$ concentration range. A model describing the gas sensing mechanism of Au-functionalized $WO_3$ nanotubes is discussed.

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Effect of temperature on the rheological properties of dental interocclusal recording materials

  • Pae, Ahran;Lee, Ho-Rim;Kim, Hyeong-Seob
    • Korea-Australia Rheology Journal
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    • v.20 no.4
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    • pp.221-226
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    • 2008
  • The purpose of this study was to compare rheological properties of six dental interocclusal recording materials and to investigate the effect of temperature on the rheological properties during setting. Five polyvinylsiloxane materials and one polyether material were investigated in this study. The storage modulus (G') and the loss factor ($tan{\delta}$) were measured from 30s after mixing during setting, using the universal dynamic spectrometer. Viscoelastic properties were evaluated by means of G' and $tan{\delta}$ from 5 repeats at $21^{\circ}C$ and $33^{\circ}C$. Individual changes during setting were also evaluated. All data were statistically analyzed using one-way ANOVA and multiple comparison $Scheff{\acute{e}}$ test at the significance level of 0.05. The mean of G was checked at $t_{set}$ (the setting time provided from manufacturer) and $t_{300}$ (the end of experimental time) and the mean of $tan{\delta}$ was checked at to and $t_{set}$. Whereas the increase of the G' value showed generally exponential changes at $21^{\circ}C$, the change of the G' value at $33^{\circ}C$ displayed sigmoidal curves during setting. The change of loss factor $tan{\delta}$ during setting varied. Within the limitations of this study, dental interocclusal recording materials had different viscoelastic properties and most of the materials showed different fluidity at $21^{\circ}C$ and $33^{\circ}C$.

A Generalized Integrated Inventory Model for a Multi-Item and its Raw Materials (공급사슬에서 다완제품-원자재의 통합재고정책에 관한 연구)

  • Kim, Dae-Hong
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.35 no.4
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    • pp.83-97
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    • 2012
  • In this paper, we consider a single-manufacturer single-buyer supply chain problem where a single manufacturer purchases and processes raw materials into a family of items in order to deliver a family of items to a single buyer at a fixed interval of time for effective implementation of Just-In-Time Purchasing. An integrated multi-item lot-splitting model of facilitating multiple shipments in small lots between buyer and manufacturer is developed in a JIT Purchasing environment. Previous research on the integrated model assumed that the manufacturer orders raw materials m (integer) times for every production run (lot multiplier policy for the raw material). In this paper, we consider a generalized policy in the replenishment of raw materials, allowing lot multiplier policy and lot splitting policy. An iterative solution procedure is developed to find the order interval for finished goods and raw materials, and number of shipments between buyer and manufacturer. We show by numerical example that when the integrated policy is adopted by both buyer and manufacturer in a cooperative manner, both parties can benefit.

Cure Kinetics and Thermal Properties of Epoxy Resin Initiated by Methylanilinium Salts as a Latent Cationic Curing Agent (잠재성 양이온 경화제로서 methylanilinium 염에 의해 개시된 에폭시 수지의 경화 동력학 및 열적 특성)

  • 김택진;박수진;이재락
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.11a
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    • pp.34-37
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    • 2000
  • The effect of novel N-crotyl-N,N-dimethyl-4-methylanilinium hexafluroantimonate (CMH) curing agent on cure behavior and thermal properties of DGEBA epoxy cationic system was investigated. From DSC measurements of DGEBA/CMH system, it was shown that this system exhibits an excellent thermal latent characteristic in a given temperature and reveals complex cure behavior as indicated by multiple exotherms. The conversion and conversion rate of DGEBA/CMH system increased with increasing the concentration of initiator due to high activity of CMH. Viscoelastic properties during gel formation of DGEBA with CMH were investigated by rheological techniques under isothermal condition. The gel time obtained from the modulus crossover. point t(G')=G", was affected by high curing temperature and concentration of CMH, resulting in high degree of network formation in cationic polymerization. The thermal stabilities were discussed in terms of the activation energy for decomposition and thermal factors determined from TGA measurements.ents.

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CO Gas-Sensor Based on Pt-Functionalized Mg-Doped ZnO Nanowires

  • Jin, Chang-Hyun;Park, Sung-Hoon;Kim, Hyun-Su;An, So-Yeon;Lee, Chong-Mu
    • Bulletin of the Korean Chemical Society
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    • v.33 no.6
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    • pp.1993-1997
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    • 2012
  • Mg-doped ZnO one-dimensional (1D) nanostrutures were synthesized by using a thermal evaporation technique. The morphology, crystal structure, and sensing properties of the Mg-doped ZnO nanostructures functionalized with Pt to CO gas at $100^{\circ}C$ were examined. The diameters of the 1D nanostructures ranged from 80 to 120 nm and that the lengths were up to a few tens of micrometers. The gas sensors fabricated from multiple networked Mg-doped ZnO nanowires functionalized with Pt showed enhanced electrical response to CO gas. The responses of the nanowires were improved by approximately 70, 69, 111, and 81 times at CO concentrations of 10, 25, 50, and 100 ppm, respectively. Both the response and recovery times of the nanowire sensor for CO gas sensing were not nearly changed by Pt functionalization. It also appeared that the Mg doping concentration did not influence the sensing properties of ZnO nanowires as strongly as Pt-functionalization. In addition, the mechanism for the enhancement in the CO gas sensing properties of Mg-doped ZnO nanowires by Pt functionalization is discussed.

Additive Manufacturing of Various Ceramic Composition Using Inkjet Printing Process (잉크젯 프린팅을 이용한 연속 조성 세라믹 화합물 구조체 형성)

  • Park, Jae-Hyeon;Choi, Jung-Hoon;Hwang, Kwang-Taek;Kim, Jin-Ho
    • Korean Journal of Materials Research
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    • v.30 no.11
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    • pp.627-635
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    • 2020
  • 3D printing technology is a processing technology in which 3D structures are formed by fabricating multiple 2D layers of materials based on 3D designed digital data and stacking them layer by layer. Although layers are stacked using inkjet printing to release various materials, it is still rare for research to successfully form a product as an additive manufacture of multi-materials. In this study, dispersion conditions are optimized by adding a dispersant to an acrylic monomer suitable for inkjet printing using Co3O4 and Al2O3. 3D structures having continuous composition composed of a different ceramic material are manufactured by printing using two UV curable ceramic inks whose optimization is advanced. After the heat treatment, the produced structure is checked for the formation and color of the desired crystals by comparing the crystalline analysis according to the characteristics of each part of the structure with ceramic pigments made by solid phase synthesis method.

Synthesis of High Purity Nano-Silica Using Water Glass (물유리를 이용한 고순도 나노실리카 제조)

  • Choi, Jin Seok;Lee, Hyun-Kwuon;An, Sung Jin
    • Korean Journal of Materials Research
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    • v.24 no.5
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    • pp.271-276
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    • 2014
  • Silica nano-powder (SNP) is an inorganic material able to provide high-performance in various fields because of its multiple functions. Methods used to synthesize high purity SNP, include crushing silica minerals, vapor reaction of silica chloride, and a sol-gel process using TEOS and sodium silicate solution. The sol-gel process is the cheapest method for synthesis of SNP, and was used in this study. First, we investigated the shape and the size of the silica-powder particles in relation to the variation of HCl and sodium silicate concentrations. After drying, the shape of nano-silica powder differed in relation to variations in the HCl concentration. As the pH of the solution increased, so did the density of crosslinking. Initially, there was NaCl in the SNP. To increase its purity, we adopted a washing process that included centrifugation and filtration. After washing, the last of the NaCl was removed using DI water, leaving only amorphous silica powder. The purity of nano-silica powder synthesized using sodium silicate was over 99.6%.

Bayesian model updating for the corrosion fatigue crack growth rate of Ni-base alloy X-750

  • Yoon, Jae Young;Lee, Tae Hyun;Ryu, Kyung Ha;Kim, Yong Jin;Kim, Sung Hyun;Park, Jong Won
    • Nuclear Engineering and Technology
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    • v.53 no.1
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    • pp.304-313
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    • 2021
  • Nickel base Alloy X-750, which is used as fastener parts in light-water reactor (LWR), has experienced many failures by environmentally assisted cracking (EAC). In order to improve the reliability of passive components for nuclear power plants (NPP's), it is necessary to study the failure mechanism and to predict crack growth behavior by developing a probabilistic failure model. In this study, The Bayesian inference was employed to reduce the uncertainties contained in EAC modeling parameters that have been established from experiments with Alloy X-750. Corrosion fatigue crack growth rate model (FCGR) was developed by fitting into Paris' Law of measured data from the several fatigue tests conducted either in constant load or constant ΔK mode. These parameters characterizing the corrosion fatigue crack growth behavior of X-750 were successfully updated to reduce the uncertainty in the model by using the Bayesian inference method. It is demonstrated that probabilistic failure models for passive components can be developed by updating a laboratory model with field-inspection data, when crack growth rates (CGRs) are low and multiple inspections can be made prior to the component failure.

Japan's Export Regulations and Korea's Investment Attraction Strategy: Focusing on the Parts and Materials Industry

  • Lee, Min-Jae;Jung, Jin-Sup;Lee, Jeong-Eun
    • Journal of Korea Trade
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    • v.24 no.3
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    • pp.55-72
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    • 2020
  • Purpose - In this paper, we provide recommendations for Korea's long-term direction and strategic measures to attract inward foreign direct investment (FDI) in response to Japan's export regulations. In doing so, we analyze the current situation and characteristics of trade between Korea and Japan, focusing on the parts and materials industry, which is particularly affected by Japan's trade regulations. Design/methodology - Based on the analysis of five successful inward FDI cases (e.g. Toray, IGK, Delkor, GlobalWafers, DuPont) and statistic trend review in the parts and materials industry, we consider various factors pertaining to successful inward FDI in Korea and propose valuable investment attraction strategies. Findings - For a successful investment attraction strategy, we studied some statistical trends in the internal and external environments of the parts and materials industry and successful investment attraction cases in Korea. We have found that in order to increase the probability of success in attracting investment, we need a mid-to long-term strategy considering multiple factors such as "Production-oriented, Demand-linked, Global Value Chain (VGC) linked, and Policy-linked investment attraction." Originality/value - We suggest several specific measures and important strategic implications for the Korean government and firm's managers to attract inward FDI successfully.