• 제목/요약/키워드: morphology controlling

검색결과 181건 처리시간 0.028초

Porous bioactive glass ceramics for bone-tissue regeneration

  • 윤희숙;김승언
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 추계학술발표대회
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    • pp.7.2-7.2
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    • 2009
  • Nanoporous bioactive glass(NBG) ceramic with well interconnected pore structures were fabricated bytriblock copolymer templating and sol-gel techniques. Hierarchically porous BGbeads were also successfully synthesized by controlling the condition of solvent.The beads have hierarchically nano- and macro-pore structure with a sizesbetween several tens nanometers and several hundred micrometers. Both NBG andBG beads show superior bone-forming bioactivity and good in vitrobiodegradability. Biocompatibility both in vitro and in vivo were examed andwas revealed that it largely relies on the pore morphology as well ascomposition. Our synthetic process can be adapted for the purpose of preparingvarious bioceramics, which have excellent potential applications in the fieldof biomaterials such as tissue engineering and drug storage.

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천연 및 인공해수를 이용하여 제작한 환경친화적인 전착코팅막의 형성 특성 (Formation Characteristics of Environment Friendly Electrodeposit Films Formed in Natural and Synthetic Seawater Conditions)

  • 이명훈;이찬식
    • Journal of Advanced Marine Engineering and Technology
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    • 제28권6호
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    • pp.1000-1009
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    • 2004
  • The environment friendly calcareous deposit films were formed on steel plates by electrodeposition technique in natural seawater and synthetic solutions such as dissolved $\textrm{Mg}^{2+}$ and $\textrm{Ca}^{2+}$ ions at various potential conditions. The influence of potential conditions on composition ratio, structure and morphology of the electrodeposited films were investigated by scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray diffractor (XRD). Accordingly, this study was provided a better understanding of the composition between the growth of $\textrm{Mg(OH)}_2$ and that of $\textrm{CaCO}_3$ during the formation of calcareous deposit films on steel substrate under cathodically electrodeposition in synthetic and natural seawater. The results showed that the formation of good overall calcareous deposited film in seawater can be achieved by controlling the Ca/Mg ratio according to interfacial pH with the effective use of the electro deposition technique.

Synthesis of Ultra-long Hollow Chalcogenide Nanofibers

  • 좌용호
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.3.1-3.1
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    • 2011
  • Nanoengineered materials with advanced architectures are critical building blocks to modulate conventional material properties or amplify interface behavior for enhanced device performance. While several techniques exist for creating one dimensional heterostructures, electrospinning has emerged as a versatile, scalable, and cost-effective method to synthesize ultra-long nanofibers with controlled diameter (a few nanometres to several micrometres) and composition. In addition, different morphologies (e.g., nano-webs, beaded or smooth cylindrical fibers, and nanoribbons) and structures (e.g., core-.shell, hollow, branched, helical and porous structures) can be readily obtained by controlling different processing parameters. Although various nanofibers including polymers, carbon, ceramics and metals have been synthesized using direct electrospinning or through post-spinning processes, limited works were reported on the compound semiconducting nanofibers because of incompatibility of precursors. In this work, we combined electrospinning and galvanic displacement reaction to demonstrate cost-effective high throughput fabrication of ultra-long hollow semiconducting chalcogen and chalcogenide nanofibers. This procedure exploits electrospinning to fabricate ultra-long sacrificial nanofibers with controlled dimensions, morphology, and crystal structures, providing a large material database to tune electrode potentials, thereby imparting control over the composition and shape of the nanostructures that evolved during galvanic displacement reaction.

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Plasma source와 RF power에 따른 NiO박막의 우선배향성 및 표면형상 (The Evolution of Preferred Orientation and Morphology of NiO Thin Films under Variation of Plasma Source and RF Power)

  • Hyunwook Ryu;Park, Jinseong
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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    • pp.121-121
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    • 2003
  • NiO thin films are very attractive for use as an antiferromagnetic layer, p-type transparent conducting films, in electrochromic devices and functional sensor layer for chemical sensors, due to their excellent chemical stability, as well as optical, electrical and magnetic properties. In addition, (100)- and (111)-oriented NiO films can be used as buffer layers on which to deposit other oriented oxide films, such as c-axis-oriented perovskite-type ferromagnetic films and superconducting films, because of the similarity in symmetry of oxygen ion lattice and lattice constants between the NiO films and the oriented oxide films. Thus, controlling the crystallographic orientation and surface roughness of the NiO films for a buffer layer are very important.

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양극산화 알루미나 주형 기반의 전해 증착법을 이용한 구리 나노선의 합성 및 특성 연구 (Synthesis and Characterization of Cu Nanowires Using Anodic Alumina Template Based Electrochemical Deposition Method)

  • 이영인;좌용호
    • 한국분말재료학회지
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    • 제19권5호
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    • pp.367-372
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    • 2012
  • Single crystalline Cu nanowires with controlled diameters and aspect ratios have been synthesized using electrochemical deposition within confined nanochannels of a porous anodic aluminium oxide(AAO) template. The diameters of nano-sized cylindrical pores in AAO template were adjusted by controlling the anodization conditions. Cu nanowires with diameters of approximately 38, 99, 274 nm were synthesized by the electrodeposition using the AAO templates. The crystal structure, morphology and microstructure of the Cu nanowires were systematically investigated using XRD, FE-SEM, TEM and SAED. Investigation results revealed that the Cu nanowires had the controlled diameter, high aspect ratio and single crystalline nature.

Nanocrystalline Materials-an Overview

  • Suryanarayana, C.
    • 한국분말재료학회지
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    • 제3권4호
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    • pp.233-245
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    • 1996
  • Nanocrystalline materials, with a grain size of typically <100 nm, are a new class of materials with properties vastly different from and often superior to those of the conventional coarse-grained materials. These materials can be synthesized by a number of different techniques and the grain size, morphology, and composition can be controlled by controlling the process parameters. In comparison to the coarse-grained materials, nanocrystalline materials show higher strength and hardness, enhanced diffusivity, improved ductility/toughness, reduced, density, reduced elastic modulus, higher electrical resistivity, increased specific heat, higher coefficient of thermal expansion, lower thermal conductivity, and superior soft and hard magnetic properties. Limited quantities of these materials are presently produced and marketed in the US, Canada, and elsewhere. Applications for these materials are being actively explored. The present article discusses the synthesis, structure, thermal stability, properties, and potential application of nanocrystalline materials.

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양극산화 알루미나 주형 기반의 전해 증착법을 이용한 니켈 나노선의 합성 및 특성 연구 (Synthesis and Characterization of Nickel Nanowires by an Anodic Aluminum Oxide Template-Based Electrodeposition)

  • 임효령;좌용호;이영인
    • 한국분말재료학회지
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    • 제22권3호
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    • pp.216-220
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    • 2015
  • Vertically oriented nickel nanowire arrays with a different diameter and length are synthesized in porous anodic aluminium oxide templates by an electrodeposition method. The pore diameters of the templates are adjusted by controlling the anodization conditions and then they are utilized as templates to grow nickel nanowire arrays. The nickel nanowires have the average diameters of approximately 25 and 260 nm and the crystal structure, morphology and microstructure of the nanowires are systematically investigated using XRD, FE-SEM and TEM analysis. The nickel nanowire arrays show a magnetic anisotropy with the easy axis parallel to the nanowires and the coercivity and remanence enhance with decreasing a wire diameter and increasing a wire length.

Organic Thin-Film Transistors with Screen Printed Silver Source/Drain Electrodes

  • Kim, Sam-Soo;Kim, Min-Soo;Choi, Gyu-Seok;Kim, Heon-Gon;Kim, Yong-Bae;Lee, Dong-Gu;Roh, Jae-Seong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1305-1307
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    • 2007
  • We show that the electrical properties of organic thinfilm transistors(OTFTs) can be enhanced by controlling the morphology of interface between screen printed electrodes and gate dielectrics. Modified surface of the insulator layer($SiO_2$) affect on the interface energy of electrode on $SiO_2$ layer. Contact angle measurement and FT-IR spectrum shows that the interface is properly modified. OTFTs device with high efficiency has been realized through modification of interface layer.

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EL시스템의 Rhodamine 유도체화합물의 표면특성 (The Microscopic Surface Properties of Rhodamine Derivatives in EL System)

  • 박수길;조성렬;손원근;조병호;임기조;이주성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.265-268
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    • 1997
  • Electroluminescent(EL) devices are constructed using multilayer organic thin film. A cell structure of glass substrate/Indium-Tinoxide/TPD as a hole transporting layer/Alq3+Rhodamine 101 perchrolate(Red3) as an emitting layer/Alq3 as an electrron transporting layer/Al as an electrode was employed. Optimal thickness of emitting layer in EL cell was performed from the viewpoint of the electronics properties of emitting layers. The general vapor-deposition method was used to control the thickness of omitting layer in EL devices and electro-optical characteristics were measured. It is clarified that controlling thickness of emitting layer in vapor-deposition film had an effect on the change of carrier injection and EL spectrum. The intensity of red omission with luminance of 81cd/$m^2$ was achived at 11V driving voltage. The surface morphology of emitting layer in EL devices was investigated.

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Solution-Phase Synthesis of Shape-Controlled Metal Nanocrystals

  • 임병권
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 춘계학술발표대회
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    • pp.21.1-21.1
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    • 2011
  • Controlling the morphology of a metal nanocrystal is critical to modern materials chemistry because its physical and chemical properties can be easily and widely tuned by tailoring the size and shape. Combined with ease of synthesis and processing, metal nanocrystals with desired morphologies and thus properties are promising candidates for a wide variety of applications in catalysis, sensing, imaging, electronics, and photonics, and medicine. In this talk, I would like to introduce my recent research results on the shape-controlled synthesis of metal nanocrystals using a simple aqueous method. This water-based system provides a number of merits such as simplicity, convenience, and the potential for large-scale production and enables us to synthesize metal nanocrystals with a rich variety of shapes such as truncated octahedron, cubes, bars, octahedrons, and thin plates. The ability to control the shape of metal nanocrystals provides a great opportunity to systematically investigate their catalytic and optical properties.

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