• 한국재료학회지
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• 제25권5호
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• pp.247-252
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• 2015

The effect of precursor concentration on the structural, morphological, and optical properties of $TiO_2$nano-flowers was investigated in this study. An increase in crystallite size was observed with an increase in the concentration of the precursor (titanium butoxide). The FE-SEM micrographs of the as-prepared samples show a three-dimensional flower-like morphology. The flowers consist of several nanorods coming out of a single core and have very sharp edges. Also, the variation in the aspect ratio of the nanostructure was observed with the concentration of the precursor. The photocatalytic properties of the samples show that the sample that has a high aspect ratio (AR~9) has a much better photocatalytic activity compared to the nano-crystal with a low aspect ratio (AR~6.1). It is believed that the excellent photocatalytic performance and short time synthesis of $TiO_2$nano-flowers using the microwave hydrothermal method can have potential applications in the field of photocatalysis.

• Journal of Electrochemical Science and Technology
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• 제2권3호
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• pp.180-185
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• 2011

The layered lithium-manganese oxide ($Li_2MnO_3$) as a cathode material of lithium ion secondary batteries was prepared and characterized the physico-chemical and electrochemical properties. The morphological and structural changes of MnO(OH) and $Li_2MnO_3$ are closely connected to the changes of electrochemical properties. The crystallinity of $Li_2MnO_3$ is enhanced as the annealing temperature increase, but its capacity is reduced due to the easier structural changes of less crystalline $Li_2MnO_3$ than highly crystalline one. Moreover, the addition of buffer material such as MnO(OH) into cathode causes to reduce the morphological and structural changes of layered $Li_2MnO_3$ and increase the discharge capacity and cycleability.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 춘계학술발표대회
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• pp.34.2-34.2
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• 2009

The silver sulphide (Ag2S) thin films have been chemically deposited from an alkaline medium (pH 8 to 10) by using a silver nitrate and thiourea as a Ag and S ion precursor sources. Ethylene Damine tetraacetic acid (EDTA) was used as a complexing agent. The effect of annealing atmosphere such as Ar, N2+H2S and O2 on the structural, morphological and optical properties of Ag2S thin films has been studied. The annealed films were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical absorption techniques for the structural, morphological, and optical properties, respectively. XRD studies reveal that the as-deposited thin films are polycrystalline with monoclinic crystal structure, is converted in to silver oxide after air annealing. The surface morphology study shows that grains are uniformly distributed over the entire surface of the substrate. Optical absorption study shows the as-deposited Ag2S thin films with band gap energy of 0.92eV and after air annealing it is found to be 2.25 eV corresponding to silver oxide thin films.

• 열처리공학회지
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• 제10권1호
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• pp.47-54
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• 1997

Flake graphite cast irons with the high damping capacity have been used for the control of vibration and noise occuring in the members of various mechanical structures under vibrating conditions. However, the damping capacity which is morphological characteristics of graphite is one of the important factors in reducing the vibration and noise, but hardly any work has deal with this problem. Therefore, the authors have examined the damping capacity of various cast irons with alloying elements and studied the influences of the matrix, mechanical properties and morphological characteristics of graphite. The main results obtained are as follows: Effects of Ni on the damping capacities and mechanical properties are investigated in 3.9%C-0.3% Cu gray cast iron. At 0.2% Ni content, specific damping capacity showed the maximum value, and decreased with further increase in Ni content, Graphite continuity also showed same behavior. This indicates that the specific damping capacity has a close relation with graphite continuity. On the other hand, the damping capacity in pearlite matrix showed superior to that in ferrite. In contrast, with increasing the Ni content, both tensile strength and hardness increased due to the decrease of graphite length and eutectic cell size.

• 한국자원식물학회지
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• 제23권3호
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• pp.214-222
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• 2010

Many research results have indicated that many kinds of useful ingredients are rich in buckwheat, which have high nutritional values and medicinal properties, so, buckwheat has been cultivated around Asia and Europe. In this paper, genetic diversity of common and tartary buckwheat germplasms were studied based on morphological and molecular markers in order to provide useful information for conservation and utilization of buckwheat genetic resources. The length, width, thick, value and weight of the seed of the common and tartary buckwheat were measured and analyzed by the statistics methods. The result has shown that there are morphological variation both in common buckwheat and tartary buckwheat seeds collected from different regions. It also has shown that the morphological variation of tartary seeds was significantly correlated to geographical regions. The nuclear ribosomal internal transcribed spacers (ITS) of the tartary buckwheat collected from different countries were cloned, sequenced and statistically analyzed. The data showed that ITS sequences were informative to analyze the phylogeny of the tartary buckwheat and the data also showed that the genetic distances varied among different tartary buckwheat seeds collected from different countries.

• Macromolecular Research
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• 제15권6호
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• pp.520-526
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• 2007

The effects of poly($({\varepsilon}$-caprolactone) (PCL) on poly(acrylonitrile-butadiene-styrene) (ABS) and polycarbonate (PC) blends were studied. Blends of ABS/PC (70/30, wt%) with PCL as a compatibilizer were prepared by a twin screw extruder. From the glass transition temperature $(T_g)$ results of the ABS/PC blends with PCL, the $T_g$(PC) of the ABS/PC (70/30) blends decreased with increasing PCL content. From the results of the morphology of the ABS/PC (70/30) blends with PCL, the phase separation between the ABS and PC phases became less significant after adding PCL in the ABS/PC blends. In addition, the morphological studies of the ABS/PC blends etched by NaOH indicated that the shape of the droplet was changed from regular round to irregular round by adding PCL in the ABS/PC blends. These results for the mechanical properties of the ABS/PC blends with PCL indicated that the tensile, flexural and impact strengths of the ABS/PC (70/30) blends peaked at a PCL content of 0.5 phr. From the results for the rheological properties of the ABS/PC (70/30) blends with PCL content, the storage modulus, loss modulus and complex viscosity increased at PCL content up to 5 phr. From the above results of the $T_g$, mechanical properties, morphology and complex viscosity of the ABS/PC blends with PCL, it was concluded that the compatibility was increased with PCL addition in the ABS/PC (70/30, wt%) blends and that the optimum concentration of PCL as a compatibilizer is 0.5 phr.

• 열처리공학회지
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• 제13권4호
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• pp.231-238
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• 2000

Flake graphite cast irons with the high damping capacity have been used for the control of vibration and noise occurring in the members of various mechanical structures under vibrating conditions. However, the damping capacity which is morphological characteristics of graphite is one of the important factors in reducing the vibration and noise, but hardly any work has deal with this problem. Therefore, the authors have examined the damping capacity of various cast irons with alloying elements and studied the influences of the matrix structures, mechanical properties and morphological characteristics of graphite. The main results obtained are as follows: Effects of pouring temperature on the damping capacities and mechanical properties were investigated in 3.6%C cast iron. At $1400^{\circ}C$, specific damping capacity showed the maximum value, and decreased with increase pouring temperature. Mechanical properties showed opposite trend with the damping capacity. And then, effects of Ni on the damping capacities and mechanical properties have been investigated in 3.6%C gray cast iron. At 0.2%Ni content, specific damping capacity showed the maximum value, and decreased with further increase in Ni content. Graphite length also showed same behavior. This indicates that the specific damping capacity has a close relation with graphite length. In case of Mo addition in 3.6%C-0.2%Ni cast iron, specific damping capacity and tensile strength was 27% and $20kgf/mm^2$ at 3.6%C-0.2%Ni-0.3%Mo cast iron respectively.

• 열처리공학회지
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• 제14권6호
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• pp.330-335
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• 2001

Flake graphite cast irons with the high damping capacity have been used for the control of vibration and noise occurring in the members of various mechanical structures under vibrating conditions. However, the damping capacity which Is morphological characteristics of graphite is one of the important factors in reducing the vibration and noise, but hardly any work has deal with this problem. Therefore, the authors have examined the damping capacity of various cast irons with alloying elements and studied the influences of the matrix structures, mechanical properties and morphological characteristics of graphite. The main results obtained are as follows: Effects of Sb on the damping capacities and mechanical properties have been investigated in 3.6%C-0.2%Ni gray cast iron. At 0.02%Sb, specific damping capacity showed the maximum value, and decreased with further increase in Sb content. Mechanical properties showed opposite trend with the damping capacity. And then, effects of Ti on the damping capacities and mechanical properties have been investigated in 3.6%C-0.2%Ni-0.02%Sb gray cast iron. Specific damping capacity increased with increase in Ti content. Graphite length also showed same behavior. Tensile strength increased with Ti content due to refinement of pearlite. In the case of 0.14%Ti addition in 3.6%C-0.2%Ni-0.02%Sb cast iron, specific damping capacity and tensile strength was 36% and 25 $kgf/mm^2$ which are higher than 32% and 15 $kgf/mm^2$ at 3.6%C-0.2%Ni cast iron respectively.

• 열처리공학회지
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• 제27권3호
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• pp.115-120
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• 2014

Microstructural features were comparatively investigated in AZ91 (Mg-9%Al-1%Zn) and AZ91-0.5%Sn alloys, in order to clarify the reason for the enhancement in room temperature tensile properties by the addition of small amount of Sn in Mg-Al-based alloy. In as-cast state, the Sn-containing alloy showed increased YS, UTS and elongation than the Sn-free alloy. The microstructural examination revealed that various factors including finer cell size, reduction of lamellar (${\alpha}+{\beta}$) phase and morphological change of bulky ${\beta}$ phase from partially divorced shape to fully divorced shape, are likely to be responsible for the improvement in tensile properties for the Sn-containing alloy. It is noted that two alloys showed similar tensile properties after solution treatment. This implies that microstructural evolution related to the ${\beta}$ phase plays a key role in better tensile properties in the Sn-containing alloy.

• 펄프종이기술
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• 제35권3호
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• pp.37-42
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• 2003

Physical properties of paper can be explained in terms of the changes in fiber's morphological properties. As the paper machine speed increases, the basis weight decreases and the mixing ratio of inferior recycled fibers increases, paper break becomes important than ever before. One of the objectives of this study is to analyze paper's physical, mechanical and fracture mechanical properties depending on softwood(SW) and hardwood(HW) mixing ratios and recycling. Fibers were refined by Valley beater to 450 mL CSF. Handsheets of 30 g/$\textrm{m}^2$ were prepared at different mixing ratios. Fracture toughness was measured as the amount of energy applied to cracked sample before total failure. Fracture toughness showed different trend to other strength properties. At the mixing ratio of SW 80: HW 20, papers showed the maximum fracture toughness. At this mixing ratio, flexible softwood fibers were mostly broken and stiff hardwood fibers were mostly pulled out.