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Numerical Analysis of the Gas Flow Distribution Characteristics in the Anode Flow Channel of Molten Carbonate Fuel Cell (MCFC) (용융탄산염 연료전지 Anode 유로 채널에서의 가스 유동 분포에 관한 수치해석적 연구)

  • Cho, Jun-Hyun;Ha, Tae-Hun;Kim, Han-Sang;Min, Kyoung-Doug;Park, Jong-Hoon;Chang, In-Gab;Lee, Tae-Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.11
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    • pp.834-839
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    • 2009
  • A three-dimensional computational fluid dynamics (CFD) analysis is performed to investigate flow characteristics in the anode channels and manifold of the internal reforming type molten carbonate fuel cell (MCFC). Considering the computational difficulties associated with the size and geometric complexity of the MCFC system, the polyhedral meshes that can reduce mesh connectivity problems at the intersection of the channel and the manifold are adopted and chemical reactions inside the MCFC system are not included. Through this study, the gas flow rate uniformity of the anode channels is mainly analyzed to provide basic insights into improved design parameters for anode flow channel design. Results indicate that the uniformity in flow-rate is in the range of ${\pm}$1% between the anode channels. Also, the mal-distributed inlet flow-rate conditions and the change in the size of the manifold depth have no significant effect on the flow-rate uniformity of the anode channels.

Study of Corrosion and Post Analysis for the Separator Channel of MCFC Stack after Cell Operation for 1200 hours (용융탄산염연료전지(MCFC) 스택의 1200시간 운전 후 분리판 채널부 표면 열화 분석 및 연구)

  • Cho, Kye-Hyun
    • Journal of the Korean institute of surface engineering
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    • v.40 no.3
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    • pp.149-158
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    • 2007
  • Of all components of MCFC(molten carbonate fuel cell), corrosion of separator is one of the most decisive factor for commercializing of MCFC. In order to provide better understanding of corrosion behavior and morphology for gas channel of separator plate, post-analysis after cell operation for 1200 hours at $650^{\circ}C$ was performed by optical microscope, SEM and EPMA. Intergranular corrosion was observed on gas channel of separator plate. Corrosion product layer was identified as Fe-oxide, Cr-oxide and Ni-oxide by EPMA, and oxide thickness was measured with a $60{\mu}m-150{\mu}m$. Also, gas channel of separator was damaged by severe intergrannular attack with post analysis in consistent with immersion test. Moreover, pitting on the channel plate was observed with a depth of $18{\sim}24{\mu}m$. The results of immersion method are well agreement with post analysis measurements.

Numerical analysis of the gas flow distribution characteristics in the anode flow channel of the molten carbonate fuel cell (MCFC) (용융탄산염 연료전지 anode 유로 채널에서의 가스 유동 분포에 관한 수치해석적 연구)

  • Cho, Jun-Hyun;Ha, Tae-Hun;Kim, Han-Sang;Min, Kyoung-Doug;Park, Jong-Hoon;Chang, In-Gab;Lee, Tae-Won
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3120-3124
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    • 2008
  • A three-dimensional computational fluid dynamics (CFD) analysis is performed to investigate flow characteristics in the anode channels and manifold of the internal reforming type molten carbonate fuel cell (MCFC). Considering the computational difficulties associated with the size and geometric complexity of the MCFC system, the polyhedral meshes that can reduce mesh connectivity problems at the intersection of the channel and the manifold are adopted and chemical reactions inside the MCFC system are not included. Through this study, the gas flow rate uniformity of the anode channels is mainly analyzed to provide basic insights into improved design parameters for anode flow channel design. Results indicate that the uniformity in flow-rate is in the range of ${\pm}1%$ between the anode channels. Also, the mal-distributed inlet flow-rate conditions and the change in the size of the manifold depth have no significant effect on the flow-rate uniformity of the anode channels.

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Analysis and Measurement of Effective Refractive Indices with Ion-exchanged Slab Waveguide (이온교환 평판도파로의 실효굴절율 측정 및 해석)

  • 천석표;박정일;박태성;정홍배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.73-76
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    • 1995
  • In this study, the slab waveguide was fabricated using potassium-nitride(KNO$_3$) or silver-nitride (AgNO$_3$) molten sources by ion-exchange process. The effective refractive indices of waveguide were measured by Prism-Coupling method. and The characteristics of waveguide(mode dispersion, effective diffusion depth. surface refractive index, diffusion coefficient, and refractive index profile etc,) were investigated by WKB method, In the case of potassium ion-exchange, the computer calculation showed that the refractive index profile of waveguide followed Gaussian function, the surface refractive index increased with ion-exchange time and the effective diffusion depth increased a little as ion-exchange time increased, while the surface refractive index of silver ion-exchanged waveguide decreased with ion-exchange time because of the ion depletion on the surface of waveguide, and the effective diffusion depth seriously with ion-exchange tim. Double ion-exchanged waveguide was fabricated by performing silver ion-exchange after potassium ion-exchange. Double ion-exchanged waveguide had a tight mode binding force since the surface refractive index was larger than single step ion-exchanged waveguide.

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The Effect of Coil Shape on the Electromagnetic Force in the Cylindrical Electromagnetic Pump Using Linear Traveling Traveling Magnetic Field (선형 이동 자기장을 사용한 원통형 전자기 펌프의 전자기력에 미치는 코일 모양의 영향)

  • 이경우;정순효;오영주;조영환;심재동
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.892-899
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    • 1995
  • A numerical simulation program based on the finite elerrent method is developed for calculating electromagnetic field of the cylindrical electromagnetic pump. The calculated results by the developed program show that Lorentz forces show maximum peak at an optimum length ($L_c$) of the induction coil. The value of $L_c$ depends on the radius of the molten metal when the skin depth is large. On the other hand, the value of $L_c$ depends on the skin depth when it is small.

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LARGE EDDY SIMULATION OF VORTEXING FLOW IN THE MOLD WITH DC MAGNETIC FIELD

  • Zhongdong Qian;Yulin Wu
    • Journal of computational fluids engineering
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    • v.10 no.1
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    • pp.56-62
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    • 2005
  • Large eddy simulation of vortexing flow of molten steel in the continuous casting mold with and without DC magnetic field was conducted. The influence of the position of magnetic field to the residence time and depth of the vortex was analyzed. The mechanism of the influence of magnetic field to the vortexing flow was found. The computational results show that the vortexing flow is the result of shearing of the two un-symmetric surface flows from the mold narrow faces when they meet adjacent to the SEN; the un-symmetric flow for turbulent vortex is caused by turbulent energy of the fluid and that for biased vortex is caused by biased flow and the turbulent energy of fluid; with the moving of the magnetic field from the centerline of the outlet of the SEN to the free surface, the surface velocity is decreased gradually and the depth of the turbulent vortex and the biased vortex is decreased, the residence time is increased with the magnetic field moves from DL=120mm to DL=60mm and then decreased; the turbulent vortex and the biased vortex can be eliminated when the magnetic field is located at the free surface.

CONTROL OF LASER WELD KEYHOLE DYNAMICS BY POWER MODULATION

  • Cho, Min-Hyun;Dave Farson
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.600-605
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    • 2002
  • The keyhole formed by high energy density laser-material interaction periodically collapses due to surface tension of the molten metal in partial penetration welds. The collapse sometimes traps a void at the bottom of the keyhole, and it remains as welding defects. This phenomenon is seen as one cause of the instability of the keyhole during laser beam welding. Thus, it seems likely that improving the stability of the keyhole can reduce voids and uniform the penetration depth. The goal of this work is to develop techniques for controlling laser weld keyhole dynamics to reduce weld defects such as voids and inconsistent penetration. Statistical analysis of the penetration depth signals in glycerin determined that keyhole dynamics are chaotic. The chaotic nature of keyhole fluctuations and the ability of laser power modulation to control them have been demonstrated by high-speed video images of laser welds in glycerin. Additionally, an incident leading beam angle is applied to enhance the stability of the keyhole. The quasi-sinusoidal laser beam power of 400Hz frequency and 15$^{\circ}$ incident leading beam angle were determined to be the optimum parameters for the reduction of voids. Finally, chaos analyses of uncontrolled signals and controlled signals were done to show the effectiveness of modulation on the keyhole dynamics. Three-dimensional phase plots for uncontrolled system and controlled system are produced to demonstrate that the chaotic keyhole dynamics is converted to regular periodic behavior by control methods: power modulation and incident leading beam angle.

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The Effects of VAR Processing Parameters on solidification Microstructures in Ti Alloys by Computer Simulation (열전달 해석을 이용한 VAR 공정 변수가 티타늄 합금 잉고트 응고 조직에 미치는 영향 연구)

  • Kim, Jong-Hwan;Lee, Jae-Hyeon;Heo, Seong-Gang;Hyeon, Yong-Taek;Lee, Yong-Tae
    • Korean Journal of Materials Research
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    • v.12 no.5
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    • pp.398-406
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    • 2002
  • VAR process is required to control its various operating parameters. Heat transfer simulation has been accomplished to understand development of solidification micro and macro-structures during VAR process in Ti alloys. Optimum VAR process parameters could be also estimated in this study. It was found that macro-structures were closely related to the shape and depth of liquid pool, and solidification parameters, such as temperature gradient, heat flux, solid fraction. The cooling rates were higher at bottom, top, and center part respectively. As cooling rates increased, the $\alpha$ phase decreased in length, width and fraction. In order to evaluate which parameter affects the result of heat transfer calculation most sensitively, the sensitivities of input parameters to the simulation result were examined. The pool depth and cooling rate showed more sensitive to the temperature of the molten metal, heat transfer coefficient, and liquidus respectively. Also, these thermal properties became more sensitive at higher temperatures.

Cavity Design Method for Injection-Molded Spur Gears

  • Kim, Choong-Hyun;Lee, Sung-Chul;Ahn, Hyo-Sok;Chong, Tae-Hyong
    • Journal of Mechanical Science and Technology
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    • v.14 no.1
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    • pp.65-71
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    • 2000
  • Mold cavities of gears should be made larger than the product specification since plastics shrink when changing from a molten to a solid state. For injection molded spur gears, two design methods for the compensation of shrinkage are widely used. One is the module correction method and the other is the pressure angle correction method. Both methods are based on the assumption that shrinkage occurs toward the center of a molded gear. This paper deals with the shrinkage rate and proposes a method of designing gear cavity derived from the measured shrinkage rates which govern the outside diameter, the tooth depth and the tooth thickness of a molded gear. The proposed method imposes no restriction on the shrinkage direction and provides a cavity with all of the fundamental gear design parameters.

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The effect of Reductants on the electro-boronizing (전해침붕처리에서 환원제 첨가의 영향)

  • 최진일
    • Journal of the Korean institute of surface engineering
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    • v.28 no.2
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    • pp.110-118
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    • 1995
  • The effect of reductants (Ti, Si, Al, Mn, Fe) addition into molten Borax has been studied on oxidation resistance and the growth of boronized layer formed during electro-boronizing on the substrate such as carbon steel and STS 430. Experiments have been carried out at the current density of 0.5 A/$\cm^2$ and in temperature range of 600~$1000^{\circ}C$ for 1~5 hours. The penetrated depth of the boron increased with addition of reductants (Ti, Si, Al) and decreased with addition of Mn and Fe. But excessive addition of reductants inhibited the boronizing due to an increase in viscosity of electrolyte. Oxidation resistance of the boronized carbon steel was improved but that of the boronized STS 430 decreased.

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