• Journal of Hydrogen and New Energy
• /
• v.15 no.1
• /
• pp.54-61
• /
• 2004

Temperature characteristics in a stack of molten carbonate fuel cell (MCFC) have been investigated with simulation based on the computational fluid dynamics (CFD) codes and experimental way. The MCFC has generally two stack structures when the natural gas is used as fuel; one is the external reforming type and the other is internal reforming type. Computer simulation at the external reforming stack suggests that the maximum temperature in the stack depends on the gas flow length. The 2 kW MCFC stack with 25 cm gas flow length showed about $675^\circ{C}$ of maximum temperature.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 2001.05a
• /
• pp.215-219
• /
• 2001

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.27 no.10
• /
• pp.1361-1369
• /
• 2003

Design performance of hybrid power generation systems, comprised of a gas turbine and an atmospheric pressure molten carbonate fuel cell, has been analyzed. Two different configurations were analyzed and performances were compared. A reference calculation was performed for the design condition of a system under development and simulated results agreed well with the published data. Performances were analyzed in terms of main design parameters including turbine inlet temperature, operating temperature of the fuel cell and pressure ratio. Also examined were the effects of fuel utilization factor and heat exchanger effectiveness. It was found that the relationship between the turbine inlet temperature and the fuel cell temperature should be critically examined to evaluate achievable design performance. Considering current state of the art technologies, a system with the combustor located before the turbine could achieve higher efficiency and specific power than the other system with the combustor located after the turbine.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.11b
• /
• pp.157-159
• /
• 2001

The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at $650^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)C03 melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way, Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(40vol%) was better excellent than the others.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.38 no.1
• /
• pp.31-39
• /
• 2014

The performance of fuel cell/gas turbine hybrid systems is highly affected by system configuration. In this study, the performance of a hybrid system combining a molten carbonate fuel cell (MCFC) and an indirectly fired gas turbine was predicted. Firstly, general performance trends of the hybrid system depending on major design parameters were examined. Then, the most feasible design options with the least impact on the MCFC stack design conditions were drawn. The economic advantage of the hybrid system over the basic MCFC only system was evaluated.

• Journal of Hydrogen and New Energy
• /
• v.22 no.5
• /
• pp.678-685
• /
• 2011

An Ejector enhances system efficiency, are easily operated, have a mechanically simple structure, and do not require a power supply. Because of these advantages, the ejector has been applied to a variety of industrial fields such as refrigerators, power plants and oil plants. In this work, an ejector was used to safely recycle anode tail gas in a 75-kW Molten Carbonate Fuel Cell (MCFC) system at KEPCO Research Institute. In this system, the ejector is placed at mixing point between the anode tail gas and the cathode tail gas or the fresh air. Commercial ejectors are not designed for the actual operating conditions for our fuel cell system. A new ejector was therefore designed for use beyond conventional operating limits. In the first place, a few sample ejectors were manufacured and the entrainment ratio was measured at a dummy stack. Through this experiment, the optimum ejector was chosen. The 75-kW MCFC system equipped with this optimum ejector was operated successfully.

• Journal of Environmental Science International
• /
• v.5 no.5
• /
• pp.593-603
• /
• 1996

A dual-porosity filmed agglomerate model for the porous cathode of the molten carbonate fuel has been investigated to predict the cell performance. A phenomenological treatment of molecular, kinetic and electrode parameters has been given. The major physical and chemical phenomena being modeled include mass transfer, ohmic losses and reaction kinetics at the electrode- electrolyte interface. The model predicts steady-state cell performance, given the above conditions that characterize the state of the electrode. Quasi-linearization and finite difference techniques are used to solve the coupled nonlinear differential equations. Also, the effective surface area of electrode pore was obtained by mercury porosimeter. The results of the investigation are presented in the form of plots of overpotential vs. current density with varied the electrode material, gas composition and mechanism. The predicted polarization curves are compared with the empirical data from 1 c$m^2$ cell. A fair correspondence is observed.

• Journal of Hydrogen and New Energy
• /
• v.10 no.2
• /
• pp.107-118
• /
• 1999

A 5-kW MCFC stack with $3,000cm^2$ electrode area was tested to investigate cell performance and operation characteristics. The stack performance was evaluated based on electrical output and I-V change. The stack showed high cell performance (7.6 kW) than the design performance and operated for more than 5,760 hours, but a significant temperature gradient inside the stack was observed. A 3-dimensional mathematical model for molten carbonate fuel cell (MCFC) was developed for the purpose of simulation of stack performance during the operation. The model was solved using PHOENICS, a computational fluid dynamics (CFD) code. The simulation result demonstrated a close prediction of the temperature gradient and stack performance.

• Journal of Hydrogen and New Energy
• /
• v.16 no.2
• /
• pp.170-179
• /
• 2005

Electrolyte loss is considered as one of the major obstacles limiting the life time of molten carbonate fuel cells (MCFCs). Unit cells with an effective area of 100 $cm^2$ were prepared and were operated to determine the optimum matrix thickness which contains the maximum amount of electrolyte without serious preformance loss caused by high resistance. Matrices with different thickness, 1.45, 1.8, and 2.3 mm, were used in unit cells and those cells were operared about 5000, 10000, and 4000 hrs. The unit cell used 1.8 mm thick matrix showed 0.85 V (at 150 mA/$cm^2$) as the intial performance and this cell voltage is not lower than the cell voltage obtained in the cell with 1 mm thick matrix. This cell was operated for 10000 hrs. The cell used 1.45 mm thick matrices showed 16.6 % in the electrolyte loss after 5000 hr operation. In the case of the cell with 2.3 mm thick matrix, the initial cell voltage was below 0.80 V (at 150 mA/$cm^2$). For thermal cycle test, the gas crossover amount of unit cell used 1.8 mm thick matrix was much less than that of the cell with 1.0 mm thick matrix.

• Journal of Hydrogen and New Energy
• /
• v.30 no.2
• /
• pp.147-154
• /
• 2019

In this study, effects of flow types and size of molten carbonate fuel cells (MCFCs) were investigated using CFD simulation. In the simulation, the current collector of MCFCs were assumed to be an porous media. With the area of $0.09m^2$, the effect of flow types such as Co-flow, Counter-flow, Cross-flow were studied. After that the effect of the size and flow direction was studied. Among three-flow types, MCFCs with co-flow type shows more uniform distribution and current density distribution.