• Korean Journal of Materials Research
• /
• v.9 no.6
• /
• pp.556-563
• /
• 1999

The corrosion behavior of heat-resistant alloys, More 1 and Super 22H in molten salts of LiCl and $LiCl-Li_2$O was investigated in the temperature range of $650~850^{\circ}C$. In a molten salt of LiCl, a dense protective oxide scale of $LiCrO_2$ was formed, following growth of oxide scale with parabolic kinetics. But in a mixed molten salt of LiCl, a dense protective oxide scale of $LiCrO_2$ was formed, following growth of oxide scale with parabolic kinetics. But in a mixed molten salt of $LiCl-Li_2$O, a porous non-protective scale of Li\ulcorner(Cr, Ni, Fe)\ulcornerO$_2$was formed, following growth of oxide scale with linear kinetics. The corrosion rate increased slowly with the increase of temperature up to $750^{\circ}C$, but above $750^{\circ}C$ rapid increase in corrosion rate observed. The corrosion behavior of Super 22H alloy was similar to that of More 1 alloy, but Super 22H showed higher corrosion resistance than More 1.

• Journal of Korea Foundry Society
• /
• v.24 no.1
• /
• pp.3-9
• /
• 2004

Die casting is "a process in which molten metal is injected at high velocity and pressure into a mold(die) cavity". Casting with smooth surfaces, high dimensional precision, complicated shapes, and reduced weight can be obtained using this process. But this process is susceptible to casting defects such as porosities, scattered chilled layers, hard spots, etc. For preventing casting defects, we developed "low-velocity high pressure die casting technology", "squeeze die casting technology", "heat insulating sleeve lubricant technology", and "direct pouring technology". The "direct pouring technology" is useful for producing molten metal without oxide contamination. It consists of a pumping system which supplies pure molten metal to the die casting machine. By using this technology, we have successfully reduced oxide contamination in castings to 1/20 of that of our previous castings.

• Korean Journal of Materials Research
• /
• v.14 no.4
• /
• pp.251-259
• /
• 2004

In the development of the advanced spent fuel management process based on the molten salt technology, it is essential to choose the optimum material for the process equipment handling molten salt. Corrosion behavior of Ni 200 and Ni-base alloys in molten salt of LiCl-$Li_2$O under oxidation atmosphere was investigated in the temperature range of $650～800^{\circ}C$ for 24～312 hrs. The order of corrosion rate was Ni 200 > Inconel 690 > Inconel 601 > Inconel 600. Inconel 600 alloy showed the highest corrosion resistance among the examined alloys, but Ni 200 exhibited the highest corrosion rate. Corrosion products of Inconel 600 and Inconel 601 were $Cr_2$$O_3$ and $NiFe_2$$O_4$. In case of Inconel 690, a single layer of $CrO_2$$O_3$ was formed in the early stage of corrosion and an outer layer of $NiFe_2$O$_4$ and inner layer of $Cr_2$$O_3$ were formed with increase of corrosion time. Inconel 600 showed local corrosion behavior and Inconel 601, 690 showed uniform corrosion behavior.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2013.05a
• /
• pp.109-110
• /
• 2013

Medium carbon steel was aluminized by hot dipping into molten Al or Al-1%Si baths. After hot-dipping in these baths, a thin Al-rich topcoat and a thick alloy layer rich in $Al_5Fe_2$ formed on the surface. A small a mount of FeAl and $Al_3Fe$ was incorporated in the alloy layer. Silicon from the Al-1%Si bath was uniformly distributed throughout the entire coating. The hot dipping increased the microhardness of the steel by about 8 times. Heating at $700-1000^{\circ}C$ however decreased the microhardness through interdiffusion between the coating and the substrate. The oxidation at $700-1000^{\circ}C$ in air formed a thin protective ${\alpha}-Al_2O_3$ layer, which provided good oxidation resistance. Silicon was oxidized to amorphous silica, exhibiting a glassy oxide surface.

• Journal of Korea Foundry Society
• /
• v.25 no.1
• /
• pp.36-39
• /
• 2005

The thermodynamic analysis of deoxidation in molten coppyr by Fe has been made. Equilibrium oxygen solubility saturated with FeO in Cu-Fe-O system has been derived without and with consideration of the solute interaction between Fe and O. The derived relationship of oxygen contents with Fe has been compared with the experimental results done by Kulkarni and the minimum oxygen solubility could be predicted by a simple first order interaction method, Wagner model.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 1999.05a
• /
• pp.96-96
• /
• 1999

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2000.11a
• /
• pp.87-87
• /
• 2000

• Proceedings of the Korean Nuclear Society Conference
• /
• 1999.10a
• /
• pp.287.1-287
• /
• 1999

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2018.05a
• /
• pp.106-107
• /
• 2018

• Journal of Korea Foundry Society
• /
• v.18 no.5
• /
• pp.439-449
• /
• 1998

Formation of oxide inclusions in the molten aluminium alloys during solidification is investigated. The oxidation tendency of both Al-4.5wt%Cu and Al-7wt%Si alloys is increased with melt temperature, particularly over $700^{\circ}C$. However, an Al-5wt%Mg alloy exhibits a decreasing mode over $800^{\circ}C$. The oxidation behavior with holding time shows the S curve shape for all of the alloys. It is shown that the mechanism of oxidation of Al-5wt%Mg alloy has a two step process different from that of Al-4.5wt%Cu and Al-7wt%Si alloys. The species and morphology of oxide inclusions in each alloy is also shown. The microstructure was more coarsened during solidification when the melt contains a large amount of oxide inclusion than when it doesn't. This result can be explained in terms of both the hindrance of heat extraction by oxide film formed on the aluminium melt and the difference of heat capacity between the aluminium melt and oxide inclusion during solidification.