• Elastomers and Composites
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• 제32권3호
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• pp.173-178
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• 1997

In this study, the ultrasonic irradiation in elevated pressure was used to alter the molecular weight and MWD of polystyrene. The high pressure reactor was filled with 0.5w/v% polystyrene solution, and then it was pressurized from 500psi to 4000psi. The ultrasound was irradiated in 10 minutes at each pressure, and the extract was collected and analyzed by GPC. Molecular weight distribution was predicted by log-normal and Schulz distribution function. The average molecular weight and polydispersity of polystyrene were decreased, as the pressure applied during the ultrasonic irradiation was increase. It was able to fractionate polymer material and control polydispersity by adjusting pressure in the ultrasonic irradiation.

• Ocean and Polar Research
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• 제38권4호
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• pp.295-301
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• 2016

The nomenclature of the sea nettle jellyfish from Korea was initially described as Dactylometra quinquecirrha Agassiz, 1862. However its identity has been questioned on the basis of its local distribution and molecular data. Here, we examined morphology and DNA sequences of nuclear rDNA using specimens collected from southern Korean waters in August 2014. Based on morphological characteristics (bell size, umbrella pattern, number of tentacles and lappets) and distribution locality, we reassign the Korean D. quinquecirrha to Chrysaora pacifica (Goette, 1886), and provide a re-description accordingly. The molecular identity of C. pacifica was further confirmed by comparison of nuclear ribosomal DNA sequences.

• 천문학회보
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• 제36권2호
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• pp.107.1-107.1
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• 2011

Density Probability Distribution Functions (PDFs) are a classic statistical way to study properties of Interstellar Medium (ISM) turbulence. In our three-dimensional MHD simulations, density PDFs of the position-position velocity (PPV) spaces are close to a log-normal distribution. the PDF widths depend on the plasma parameters such as magnetic strength and sonic Mach number. Futhermore, we compare these simulations results to Galactic molecular clouds observed by Jackson et. al (2006). By fitting of the velocity dispersion in the spectral line observation, volume density PDFs of the defined molecular clouds indicate that the sound speeds of the turbulences seem to have a few times larger than the simulation results. In order to understand the inconsistency with general characteristics of turbulence, we consider other simulations inducing the turbulent flow randomly at small driving scales. We find that the density PDF width decreases at more smaller driving scale. Finally, the simulations suggest that sources of ISM turbulence in Galactic molecular clouds can be important on small scales.

• 반도체디스플레이기술학회지
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• 제18권4호
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• pp.25-29
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• 2019

Microstructure pattern generation on light guides in backlight unit (BLU) is an essential process for designing flat panel display, but efficient designing algorithm is still limited to achieve uniform luminescence while maintaining fully random distribution to avoid interference effects. In this study, a molecular dynamics model based pattern generation algorithm has been developed. The proposed algorithm allows a fast and efficient distribution of patterns at specified density within the user-defined computational cells, and its efficiency and performance has been demonstrated with sample cases.

• Fisheries and Aquatic Sciences
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• 제12권3호
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• pp.194-202
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• 2009

Sulfated fucans are known to have both anti-thrombotic and anti-coagulant activities. In this study, the variation in platelet aggregation and anti-coagulant activities was investigated in vitro with regard to administered dose, molecular weight distribution, sulfate content, and sugar composition in two algal fucoidans from Eisenia bicyclis and Undaria pinnatifida sporophylls (Mekabu). The anti-coagulant activity largely correlated with sulfate content and with molecular weight distribution in a dose-dependent manner. However, both fucoidans demonstrated inhibitory responses to ADP-induced platelet aggregation in dose- and structure-dependent manners that contrasted with the anti-coagulant activity. Neither molecular weight distribution nor sulfate content greatly affected platelet-aggregation inhibition (PA-inhibition) by the fucoidan fractions, whereas anti-coagulant activity was sensitive to these structural factors. Interestingly, an E. bicyclis fucoidan fraction exhibited almost complete PA-inhibition at a treatment dose of 500 mg/mL while retaining weak anti-coagulant activity. In conclusion, these observations suggest that fucoidan may be a useful anti-thrombotic or anti-platelet agent in various arterial thrombotic disorders, including post-vascular intervention with controlled bleeding complications, due to its anti-coagulant modulating activity.

• Carbon letters
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• 제13권3호
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• pp.133-138
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• 2012

According to kinetic mechanisms, liquid phase polymerization and solid phase polymerization are different in acrylonitrile (AN) polymerization, and so the relationship between the contribution ratio and molecular weight distribution (MWD) was obtained through theoretic analysis. The precipitation homopolymerization of AN was carried out in a mixture solution of dimethyl sulfoxide (DMSO) and water at $50{\sim}65^{\circ}C$ using ${\alpha}$,${\alpha}^{\prime}$-azobisisobutyronitrile as an initiator. The contribution ratio decreased and approached 0; the MWD also decreased and approached 2 with the increase of the $H_2O$/DMSO ratio from 10/90 to 90/10. The experimental data were found to coincide well with the theoretical equation derived from the mechanisms.

• Macromolecular Research
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• 제14권6호
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• pp.640-645
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• 2006

Polyethylene of bimodal molecular weight distribution was irradiated with an electron beam. The thermal and mechanical properties were examined by DSC, small and wide angle X-ray scattering and static tensile test according to the crystal morphology of the irradiated samples. The crystal morphology change upon irradiation, as revealed by wide angle X-ray scattering, correlated well with the changes in melting enthalpy, whereas the lamellar thickness and the amorphous gap thickness remained virtually unchanged at irradiation doses up to 500 kGy. Crosslinks in the crystal domains became evident at an energy level of 250 kGy, resulting in reduced crystallinity and crystal size of the (110) and (200) planes. The samples became stiff and brittle with increased irradiation dose, which seem to be more relevant to the amount of cross links than the crystal morphology changes.

• 한국식품과학회지
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• 제21권4호
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• pp.486-491
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• 1989

단립종인 천마벼, 중립종인 용문벼, 장립종인 Mahatma등 3품종 설에 대한 취반미의 텍스쳐 특성과 아밀로오스의 분자량 분포를 rheometer와 겔 크로마토그래피 방법을 통하여 연구하였다. Mahana 품종 쌀로 만든 밥은 천마벼나 용문벼로 만든 밥보다 경도가 컸고 부착성이 낮았다. 가용성 아밀로오스는 경도와 정의 상관관계가 있었으나 총 아밀로오스 함량이나 불용성 아밀로오스 함량과는 뚜렷한 상관관계를 보이지 않았다. 분리한 아밀로오스의 ${\beta}-amylolysis$ limit는 $77.2{\sim}78.5%$였으며 iodine binding capacity는 $16.5{\sim}18.2%$였다. 겔 크로마토그래피에 의하여 분리한 아밀로오스의 분자량 분포는 천마벼, 용문벼, Mahatma의 순으로 컸다.

• 한국물환경학회지
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• 제24권6호
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• pp.682-689
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• 2008

The purpose of this study was to find out the variation between molecular size distribution (MSD) of natural organic matter (NOM) in raw waters after different water treatment processes like conventional process (coagulation, flocculation, filtration) followed by advanced oxidation process (ozonation, GAC adsorption). The MSD of NOM of Suji pilot plant were determined by Liquid Chromatography-Organic Carbon Detection (LC-OCD) which is a kine of high-performance size-exclusion chromatography (HPSEC) with nondispersive infrared (NDIR) detector and $UV_{254}$ detector. Five distinct fractions were generally separated from water samples with the Toyopearl HW-50S column, using 28 mmol phosphate buffer at pH 6.58 as an eluent. Large and intermediate humic fractions were the most dominant fractions in surface water. High molecular weight (HMW) matter was clearly easier to remove in coagulation and clarification than low molecular weight (LMW) matter. Water treatment processes removed the two largest fractions almost completely shifting the MSD towards smaller molecular size in DW. No more distinct variation of MSD was observed by ozone process after sand filtration but the SUVA value were obviously reduced during increase of the ozone doses. UVD results and HS-Diagram demonstrate that ozone induce not the variation of molecular size of humic substance but change the bond structure from aromatic rings or double bonds to single bond. Granular activated carbon (GAC) filtration removed 8~9% of organic compounds and showed better adsorption property for small MSD than large one.

• 산업기술연구
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• 제10권
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• pp.9-13
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• 1990

The approximation of the radial distribution functions(RDF) of mixture plays an important role in deriving the mixing rules for the corresponding states principle(CSP). The mean density approximation(MDA), one of the most successful approximations, fails to predict the radial distribution functions when the size ratio in terms of the Lennard-Jones size parameters is greater than 1.5. To get a better prediction of important structural integrals over the radial distribution functions that arise in the asymmetrical attraction contribution of the perturbaton theory, the new type of mean density approximation(NTMDA) is proposed. With this NTMDA, quite reliable results for those integrals for systems with comparatively large ratio of the size parameters are obtained.