• Title/Summary/Keyword: molar ratios

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Effects of Mixing Ratio of Urea and Mlelamine on Formaldehyde Emission and Bonding Properties of Plywoods Manufactured with Urea-Melamine Formaldehyde Adhesives (요소-멜라민 공축합 수지의 요소와 멜라민 혼합비율이 합판의 포름알데히드 방출과 접착성에 미치는 영향)

  • Park, Heon;Kang, Eun-Chang;Min, Kyeong-Heui
    • Journal of the Korea Furniture Society
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    • v.11 no.1
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    • pp.53-59
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    • 2000
  • This study was to measure formaldehyde emission and bonding strength of plywoods manufactured with urea-melamine formaldehyde adhesives, which were made from three different mixing ratios of urea and melamine, and with four different formaldehyde/urea-melamine molar ratios of 1.0,1.1,1.2 and 1.4. The results were as follows 1. Amount of formaldehyde emission was the lowest at the first method of molar ratio(F/(M+U)) 1.0. Amounts of formaldehyde emission of experimental manufactured adhesives were lower than that of commercial adhesive. 2. Bonding strength of dry specimen was the highest at the first method of molar ratio(F/(M+U)) 1.4. Dry bonding strength of molar ratio(F/(M+U)) 1.4 was similar to commercial adhesive. 3. Bonding strength of wet specimen was the highest at the second method of molar ratio(F/(M+U)) 1.4. Bonding strength of wet specimen used by the third method of molar ratio(F/(M+U)) 1.4 was almost equal to commercial adhesive.

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Relationship Between Chemical Properties of Forest soil Solutions and Element concentrations in Needles of Pinus thunbergii in Industral Complexes (공단 인접지역 해송 잎의 무기성분 함량과 산림 토양용액의 화학적 특성간의 관계)

  • Lee, Wi-Young;Yang, Jae E.;Park, Chang-Jin;Zhang, Yong-Seon;Ok, Yong-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.5
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    • pp.322-328
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    • 2004
  • Available nutrients in soil solution play key roles on the growth of plants, but the equilibria in soil solution can be disturbed by acid precipitation. In this study, we investigated the relationships between element concentrations in the needles of Pinus thunbergii and chemical properties of forest soil solutions in the industrial complexes as an effort to find the possible limiting factor(s) causing the forest decline. The Ca/Al molar ratios in needles of Pinus thunbergii collected from the control sites were 18. However, at Onsan and Ulsan industrial complexes, those were decreased to the ranges from 10 to 11 for the one-year old needles and from 9 to 10 for the two-year old needles. The Mg/Al molar ratios showed similar tendencies with the Ca/Al molar ratios of the needles of Pinus thunbergii. In the A horizon, there existed a significant correlation between Mg concentrations in the needles of Pinus thunbergii and Ca/Al molar ratio of forest soil solution. Calcium concentrations in the needles of Pinus thunbergii in the B horizon were also significantly correlated with Ca/Al molar ratios of forest soil solutions. The uptakes of Ca and Mg by Pinus thunbergii were mainly limited by Al in the soil solutions of the A horizon and by Mn and Al in the soil solutions of the B horizon.

Dietary Molar Ratios of Phytate : Zn and Phytate $\times$ Ca : Zn for Zn Nutrition Assessment in Koreans

  • Kwun, In-Sook;Kwon, Chong-Suk
    • Nutritional Sciences
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    • v.2 no.2
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    • pp.82-87
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    • 1999
  • Zinc nutriture in South Koreans was evaluated by estimating Zn, Ca, and phytate intake, and the molar ratios of phytate : Zn and the millimolar ratios of phytate $\times$ Ca Zn. food consumption data from the 95 National Nutrition Survey was used. For the present study, data from the nationwide, large city and urban area level were used. No standard deviation measures were provided in the 95 National Nutrition Survey : only mean values were reported. Nationwide daily intake of Zn and Ca were 10.1 mg/day and 426.5 mg/day, respectively. The estimated daily phytate intake was 1676.6 mg/day nationwide. The molar ratio of phvtate : Zn, the millimolar ratio of phytate $\times$ Ca : Zn and the phytate $\times$ Ca Zn mmol per 4.2 MJ (1000 kcal) were 15.9, 168.9 and 91.8 in nationwide, respectively. The major food groups for zinc intake were meat, poultry products (43%), and cereals and grain products (18%). Sixty two percent of Zinc was from animal food sources. Cereal and grain products supplied most of the phytate intake (46%), followed by seasonings, fruits, and legume products. The major food source of phytate was rice (39%) . The results of the present study suggest that Zn status of Koreans maybe influenced by high dietary intake of phytate and high molar ratios of phytate : Zn and phytate $\times$ Ca : Zn. These results raise concerns about Zn status of Koreans, who consume a diet higher in phytate than Western diets. further research is necessary to confirm whether such poorly available dietary Zn has any impact on the health of Koreans.

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The Control of Side Reactions in Bunsen Reaction Section of Sulfur-Iodine Hydrogen Production Process (황-요오드 수소 생산 공정의 분젠 반응 부분에서 부반응 제어)

  • Lee, Kwang-Jin;Hong, Dong-Woo;Kim, Young-Ho;Park, Chu-Sik;Bae, Ki-Kwang
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.6
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    • pp.490-497
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    • 2008
  • For continuous operation of the sulfur-iodine(SI) thermochemical cycle, which is expected practical method for massive hydrogen production, suggesting operation conditions at steady state is very important. Especially, in the Bunsen reaction section, the Bunsen reaction as well as side reactions is occurring simultaneously. Therefore, we studied on the relation between the variation of compositions in product solution and side reactions. The experiments for Bunsen reaction were carried out in the temperature range, from 268 to 353 K, and in the $I_2/H_2O$ molar ratio of $0.094{\sim}0.297$ under a continuous flow of $SO_2$ gas. As the result, sulfur formed predominantly with increasing temperature and decreasing $I_2/H_2O$ molar ratios. The molar ratios of $H_2O/H_2SO_4$ and $HI/H_2SO_4$ in global system were decreased as the more side reaction occurred. A side reactions did not appear at $I_2/H_2O$ molar ratios, saturated with $I_2$, irrespective of the temperature change. We concluded that it caused by the increasing stability of an $I_{2x}H^+$ complex and a steric hindrance with increasing $I_2/HI$ molar ratios.

Effects of Co/Al and Si/Al Molar Ratios on DTO (Dimethyl Ether to Olefins) Reaction over CoAPSO-34 Catalyst (CoAPSO-34 촉매상에서 DTO (Dimethyl Ether to Olefins) 반응에 미치는 Co/Al 및 Si/Al 몰 비의 영향)

  • Kim, Hyo-Sub;Lee, Su-Gyung;Choi, Ki-Hwan;Lee, Dong-Hee;Park, Chu-Sik;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.26 no.2
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    • pp.138-144
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    • 2015
  • Effects of Co/Al and Si/Al molar ratios of cobalt incorporated SAPO-34 catalysts (CoAPSO-34) on their catalytic lifetime were investigated in dimethyl to olefin (DTO) reaction. The property of CoAPSO-34 catalysts was characterized using XRD, SEM, $^{29}Si$ MAS NMR, and $NH_3$-TPD techniques. First, the lifetime of CoAPSO-34 prepared by varying Co/Al molar ratios was improved than that of using the SAPO-34 catalyst, and the optimal Co/Al molar ratio was 0.0025. The total acid site amounts increased from 0.432 to 1.111 mmol/g with increasing Si/Al molar ratios from 0.05 to 0.20 while fixing a Co/Al molar ratio of 0.0025. However, the catalysts with too high acid site amounts were deactivated rapidly with blockages of the pores due to the fast accumulation of polycyclic aromatic hydrocarbons in the cage. Therefore, the CoAPSO-34 catalyst with a proper Si/Al molar ratio of 0.10 was the most superior in terms of the lifetime, which was improved by about 87% as compared with that of the SAPO-34 catalyst.

Optimized biodiesel yield in a hydrodynamic cavitation reactor using response surface methodology

  • Neeraj Budhraja;R.S. Mishra
    • Advances in Energy Research
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    • v.8 no.4
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    • pp.233-241
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    • 2022
  • Biodiesel is a non-polluting and non-toxic energy source that can replace conventional diesel. However, the higher production cost and raw material scarcity became challenges that obstruct the commercialization of biodiesel production. In the current investigation, fried cooking oil is used for biodiesel production in a hydrodynamic cavitation reactor, thus enhancing raw material availability and helping better waste oil disposal. However, due to the cavitation effect inside the reactor, the hydrodynamic cavitation reactor can give biodiesel yield above 98%. Thus, the use of orifice plates (having a different number of holes for cavitation) in the reactor shows more than 90% biodiesel yield within 10 mins of a time interval. The effects of rising temperature at different molar ratios are also investigated. The five-hole plate achieves the highest yield for a 4.5:1 molar ratio at 65℃. And the similar result is predicted by the response surface methodology model; however, the optimized yield is obtained at 60℃. The investigation will help understand the effect of hydrodynamic cavitation on biodiesel yield at different molar ratios and elevated temperatures.

Studies on the formation of Copper Compelxes of Sulfa-Drug. (Sulfa제-Cu 착화합물의 형성에 관하여)

  • 이왕규
    • YAKHAK HOEJI
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    • v.7 no.1
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    • pp.13-17
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    • 1963
  • The purpose of this work is to investigate the molar ratio, the precipitation condition and the color of copper sulfa-drugs complexes. The colors of the complexes are observed at every precipitation condition is obtained as pH 7-9. The determination of the molar ratio of complexes is able to be carried out by way of gravimetric method and solvent extraction method. The molar ratios of sulfa-drugs and copper in identified complexes are 2:1 when utilizing both methods.

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Adhesion Properties of Urea-Melamine-Formaldehyde (UMF) Resin with Different Molar Ratios in Bonding High and Low Moisture Content Veneers

  • Xu, Guang-Zhu;Eom, Young-Geun;Lim, Dong-Hyuk;Lee, Byoung-Ho;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.2
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    • pp.117-123
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    • 2010
  • The objective of this research was executed to investigate the effect of molar ratio of formaldehyde to urea and melamine (F/(U+M)) of urea-melamine-formaldehyde (UMF) resin on bonding high and low moisture content veneers. For that purpose, UMF resin types with 5 different F/(U+M) molar ratios (1.45, 1.65, 1.85, 2.05, and 2.25) synthesized were used in present study. First, their curing behavior was evaluated by differential scanning calorimetry. Second, their adhesion performance in bonding high and low moisture content veneers was evaluated by probe tack and dry and wet shear strength tests. Curing temperature and reaction enthalpy decreased with the increase of F/(U+M) molar ratio. And the dry and wet shear strengthsof plywood manufactured from low moisture content veneers were higher than thoseof plywood manufactured from high moisture content veneers. Also, the maximum initial tack force on the low moisture content veneer was higher than that on the high moisture content veneer.

Risk of lingual nerve injuries in removal of mandibular third molars: a retrospective case-control study

  • Tojyo, Itaru;Nakanishi, Takashi;Shintani, Yukari;Okamoto, Kenjiro;Hiraishi, Yukihiro;Fujita, Shigeyuki
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.41
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    • pp.40.1-40.7
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    • 2019
  • Background: Through the analysis of clinical data, we attempted to investigate the etiology and determine the risk of severe iatrogenic lingual nerve injuries in the removal of the mandibular third molar. Methods: A retrospective chart review was performed for patients who had undergone microsurgical repair of lingual nerve injuries. The following data were collected and analyzed: patient sex, age, nerve injury side, type of impaction (Winter's classification, Pell and Gregory's classification). Ratios for the respective lingual nerve injury group data were compared with the ratios of the respective data for the control group, which consisted of data collected from the literature. The data for the control group included previous patients that encountered various complications during the removal of the mandibular third molar. Results: The lingual nerve injury group consisted of 24 males and 58 females. The rate of female patients with iatrogenic lingual nerve injuries was significantly higher than the control groups. Ages ranged from 15 to 67 years, with a mean age of 36.5 years old. Lingual nerve injury was significantly higher in the patient versus the control groups in age. The lingual nerve injury was on the right side in 46 and on the left side in 36 patients. There was no significant difference for the injury side. The distoangular and horizontal ratios were the highest in our lingual nerve injury group. The distoangular impaction rate in our lingual nerve injury group was significantly higher than the rate for the control groups. Conclusion: Distoangular impaction of the mandibular third molar in female patients in their 30s, 40s, and 50s may be a higher risk factor of severe lingual nerve injury in the removal of mandibular third molars.

Effects of pH, molar ratios and pre-treatment on phosphorus recovery through struvite crystallization from effluent of anaerobically digested swine wastewater

  • Kim, Daegi;Min, Kyung Jin;Lee, Kwanyong;Yu, Min Sung;Park, Ki Young
    • Environmental Engineering Research
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    • v.22 no.1
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    • pp.12-18
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    • 2017
  • Struvite precipitation has been proven to be an effective method in removing and recovering ammonia nitrogen (N) and phosphate phosphorus (P) from wastewater. In this study, effects of pH, molar ratios and pre-treatment of effluent of anaerobically digested swine wastewater were investigated to improve struvite crystallization. The magnesium : ammonium : phosphate ratio of 1.2 : 1.0 : 1.0 was found to be optimal, yet the molar ratio in the wastewater was 1 : 74.9 : 1.8. From the analysis, the optimum pH was between 8.0 and 9.0 for maximal phosphate P release and from 8.0 to 10.0 for maximal ammonia N and phosphate P removal from real wastewater. Analysis from Visual MINTEQ predicted the pH range of 7-11 for ammonia N and phosphate P removal and recovery as struvite. For pre-treatment, microwave pre-treatment was ineffective for phosphate P release but ultrasound pre-treatment showed up to 77.4% phosphate P release at 1,000 kJ/L of energy dose. Precipitates analysis showed that phosphorus and magnesium in the collected precipitate had almost same values as theoretical values, but the ammonia content was less than the theoretical value.