• Title/Summary/Keyword: moisture sorption

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Moisture Sorption and Desorption Isotherms of Various Leaf Tobaccos (잎담배의 흡습 및 탈습에 관한 연구)

  • 진학용;최승찬;이태호;유광근
    • Journal of the Korean Society of Tobacco Science
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    • v.3 no.1
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    • pp.30-40
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    • 1981
  • The moisture sorption and desorption isotherms of various tobaccos were obtained over a relative humidity range from 0 to 90% at $20^{\circ}C$ and $30^{\circ}C$. The hysteresis effect, constant and rate of moisture sorption and desorption, monomolecular-layer moisture content, and specific surface area were analyzed from the obtained data. The moisture sorption and desorption isotherms showed a different characteristics for different tobacco varieties. At a lower humidity range below 50% RH, Burley tobacco had higher moisture sorption and desorption figures than Hicks and Basma, while, at a higher humidity range above 50% RH, Hicks had higher values than the others. The hysteresis effect of tobacco were greater in an intermediate humidity range (40-70% RN), and Basma showed a greater effect than the others. The sorption and desorption constant (K) increased with temperature, but decreased with RH, and Burley tobacco had larger K values, while Hicks had smaller K values than others. The sorption and desorption rate of Burley tobacco were greater than the other tobaccos. The monomolecular-layer moisture was 27.8 and 51.4mg/g, and the specific surface was 101 and $186m^2/g$, for Basma and Burley, respectively.

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A Study on Internal Moisture Gradients of Wood (목재(木材) 건조중(乾燥中) 내부수분경사(內部水分傾斜)에 관(關)한 연구(硏究))

  • Kang, Ho-Yang
    • Journal of the Korean Wood Science and Technology
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    • v.19 no.2
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    • pp.30-39
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    • 1991
  • Internal moisture gradients of 3cm-thick radiata pine (Pinus radiata) sapwood and meranti(Shorea spp.) heartwood were determined by using slicing method during drying and were predicted by Hart's Sorption Simulation. The shapes of internal moisture gradients. moisture contents and drying rates, which were obtained by the slicing method. were compared with those predicted by Sorption Simulation. After the 2nd fitting attempts. the differences between the gravimetric drying rates and the drying rates predicted by Sorption Simulation were less than 0.021%/hr for radiata pine and 0.043%/hr for meranti. The shapes of the internal moisture gradients predicted by Sorption Simulation were in good agreement with those obtained by the slicing method. It could be concluded that Sorption Simulation be an excellent tool to predict internal moisture gradients of wood.

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Moisture Sorption Characteristics of Model Food Powders (모형 식품 분말의 흡습 특성)

  • Kim, Dong-Woo;Chang, Kyu-Seob;Kim, Suk-Shin;Lee, Un-Hyun
    • Korean Journal of Food Science and Technology
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    • v.28 no.6
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    • pp.1146-1150
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    • 1996
  • The purpose of this research was to provide fundamental data required for the process design of conveying, storage and processing of food powders. Potato starch, corn starch, wheat protein, soybean protein, and model food powders prepared by mixing potato starch and wheat protein were selected and their sorption characteristics such as equilibrium moisture content, monolayer moisture content, and sorption enthalpy were determined. Equilibrium moisture content and monolayer moisture content of high starch powders were higher than those of high protein powders, and the equilibrium moisture content decreased with temperature. The determination coefficients of the regression equations to predict the equilibrium moisture content of food powders were from 0.997 to 0.999. Sorption enthalpy experiments indicated that powder of high moisture content showed lower sorption than that of low· moisture content, and the high protein powder showed lower sorption than high starch powder.

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Molecular Diffusion of Water in Paper (IV) - Mathematical model and fiber-phase moisture diffusivities for unsteady-state moisture diffusion through paper substrates - (종이내 수분확산 (제4보) - 종이의 비정상상태 수분확산 모델과 섬유상 수분확산 계수 -)

  • 윤성훈;박종문;이병철
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.3
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    • pp.17-24
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    • 2002
  • An unsteady-state moisture diffusion through cellulosic fibers in paper was characterized from the moisture sorption experiment and the mathematical modeling. The sorption experiment was conducted by exposing thin dry paper specimens to a constant temperature-humidity environment. Oven dried blotting papers and filter papers were used as test samples and the gains of their weights were constantly monitored and recorded as a function of sorption time. For a mathematical approach, the moisture transport was assumed to be an one-dimensional diffusion in thickness direction through the geometrically symmetric structure of paper. The model was asymptotically simplified with a short-term approximation. It gave us a new insight into the moisture uptake phenomena as a function of square root of sorption time. The fiber-phase moisture diffusivities(FPMD) of paper samples were then determined by correlating the experimental data with the unsteady-state diffusion model obtained. Their values were found to be on the order of magnitude of $10^{-6}-10^{-7}cm^2$/min., which were equivalent to the hypothetical effective diffusion coefficients at the limit of zero porosity. The moisture sorption curve predicted from the model fairly agreed with that obtained from the experiment at some limited initial stages of the moisture uptake process. The FPMD value of paper significantly varied depending upon the current moisture content of paper. The mean FPMD was about 0.7-0.8 times as large as the short-term approximated FPMD.

Evaluation of Moisture Sorption Characteristics in Polymer Material (고분자 소재에서 흡습 특성의 평가)

  • Park, Hee-Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.11
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    • pp.1297-1303
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    • 2012
  • In this paper, the standard procedures for measuring the moisture sorption properties of thin polymeric materials such as polyethylene terephthalate (PET) by using the thermo-gravimetric method to characterize the moisture diffusion in the polymer are presented, and the sorption properties are quantified. The moisture diffusivity and solubility are characterized to investigate the effect of temperature and humidity on the moisture sorption properties according to the Arrhenius equation. The validation of the obtained sorption properties using thermogravimetry is discussed with the measured permeability based on Fickian diffusion. The nonlinear behavior of the concentration dependent moisture diffusion is investigated experimentally, and the nonlinearity is characterized numerically for the case of having an interface with an inorganic material such as a metal. The Fickian/Non-Fickian model based on the obtained moisture sorption properties is compared and discussed.

Comparison of Dynamic Sorption and Hygroexpansion of Wood by Different Cyclic Hygrothermal Changing Effects

  • Yang, Tiantian;Ma, Erni
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.2
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    • pp.191-203
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    • 2016
  • To investigate the dynamic sorptive and hygroexpansive behaviors of wood by different cyclic hygrothermal changing effects, poplar (populus euramericana Cv.) specimens, were exposed to dynamic sorption processes where relative humidity (RH) and temperature changed simultaneously in sinusoidal waves at 75-45% and $5-35^{\circ}C$ (condition A) and where RH changed sinusoidally at 75-45% but temperature was controlled at $20^{\circ}C$ (condition B), both for three cyclic periods of 1, 6, and 24 h. Moisture and dimensional changes measured during the cycling gave the following results: Moisture and transverse dimensional changes were generally sinusoidal. Moisture and dimensional amplitude increased with increasing cyclic period but all were lower for thicker specimens. The amplitude ratio of condition A to condition B ranged from 1.0 to 1.6 with the maximum value of 1.57 occurring at the shortest cyclic period, not as much as expected. T/R increased as cyclic period increased or specimen thickness decreased. T/R from condition B was weaker than that from condition A. Sorption and swelling hysteresis existed in both conditions. Sorption hysteresis was negatively related to cyclic period but in positive correlation with specimen thickness. Sorption hysteresis was found more obvious in condition B, while moisture sorption coefficient and humidity expansion coefficient showed the opposite results.

The Effect of Disintegrants on the Properties of Salicylamide Tablets (수종의 붕해제가 살리실아미드정제의 제제특성에 미치는 영향)

  • Hwang, Sung-Joo;Rhee, Gye-Ju;Jee, Ung-Kil;Kwak, Hyo-Sung;Kim, Chong-Kook
    • Journal of Pharmaceutical Investigation
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    • v.22 no.1
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    • pp.41-48
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    • 1992
  • Six common tablet disintegrants (corn starch, Avicel PH102, calcium carboxymethylcellulose, Primojel, Kollidon CL and Ac-Di-Sol) were used at the concentration of 0, 2, 4 and 6% (w/w) in salicylamide tablets made with wet granulation method. Certain physical parameters of the disintegrants (moisture sorption, hydration capacity and bulk density) were determined to evaluate their relative efficiency. The disintegration time and dissolution rate of the tablets were correlated well with the ranks of initial rate of moisture sorption for each disintegrant as follows; Ac-Di-Sol, Kollidon CL, primojel, calcium CMC, corn starch and Avicel PH102. The initial rate of moisture sorption was important for the disintegration capacity as well as hydration capacity. The effect of storage at different temperatures and relative humidity upon the tablets containing various disintegrants was evaluated in terms of tablet hardness and disintegration time. Storage at high temperature reduced the hardness substantially and retarded the disintegration of the all tablets studied. Especially, the hardness of tablets containing Kollidon CL was significantly reduced. Although the tablet hardness was decreased and the disintegration time was increased under a moderate humid condition, both of them were decreased under the severely high humid condition of 80 or 90% RH, which was due to the breakrupture of tablet matrix bonds by the excessive uptake of moisture. Therefore, the stability caused by moisture sorption should be considered, when disintegrants having high moisture sorption such as Kollidon CL, Ac-Di-Sol and Primojel were employed in the tablets containing water-labile or hygroscopic drugs.

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Moisture Sorption Characteristics of Lactobacillus brevis-fermented Sea Tangle Saccharina japonica, Mekabu Fucoidan, and These Mixture Powders (발효 다시마(Saccharina japonica) 분말, 미역귀 후코이단 분말 및 이들 혼합분말의 수분 흡습 특성)

  • Lee, Changheon;Sim, Jin Ha;Kim, Jin Hyeon;Yu, Daeung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.54 no.1
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    • pp.107-110
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    • 2021
  • The goal of this study was to investigate moisture sorption characteristics of Lactobacillus brevis-fermented sea tangle Saccharina japonica, Mekabu fucoidan, and these mixture powders. Moisture sorption isotherms of powders were determined at 37℃ using the static gravimetric technique in a water activity (aw) range of 0.11-0.93. Equilibrium moisture content (Xeq) values of the fermented sea tangle powder were almost 3 times when aw<0.7 and increased upto almost 4 times when aw<0.9 higher than mekabu fucoidan powder. In these reason, to improve strong hygroscopic nature of the fermented sea tangle powder, fermented sea tangle and mekabu fucoidan powders were dissolved as ratios of 7:3, 5:5, and 3:7 (w/w) in a distilled water and then freeze dried. Xeq values of mixture powders were around average value of sum of both powders at all aw ranges. All moisture sorption isotherms of powders exhibited typical J-shaped type III. Xeq of mixture powders increased with increasing aw and decreased as increasing proportion of mekabu fucoidan powder. The Peleg model was found to accurately describe moisture sorption isotherms of powders. The results can be used to understand hygroscopic nature of powders, improve shelf life, and retain quality across postharvest processing.

Equilibrium Moisture Contents of Major Korean Coniferous Species (주요 국산 침엽수종의 평형함수율)

  • Lee, Won-Hee;Park, Byung-Soo;Byeon, Hee-Seop;Kang, Ho-Yang;Chong, Sung-Ho
    • Journal of the Korea Furniture Society
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    • v.19 no.1
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    • pp.75-82
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    • 2008
  • A series of the studies on the applied physical properties of main domestic species have been conducted last three years. Equilibrium moisture content(EMC) of Pinus koraiensis, Larix kaemferi, Pinus koraiensis were investigated. The experiments for sorption property were conducted with 20- and 80-mesh wood powder and resulted in their EMC's at various sorption conditions. Amount of moisture sorption and sorption speed of Larix kaemferi were shown the most large values and very fast among three Korean main coniferous wood.

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Moisture Sorption and Desorption Characteristics of Tobacco Types. (담배종류별 흡습 및 방습 특성)

  • 김용옥;정한주;공판임;장기철
    • Journal of the Korean Society of Tobacco Science
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    • v.26 no.1
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    • pp.43-49
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    • 2004
  • This study was carried out to investigate moisture sorption and desorption characteristics followed by tobacco type. Experiments were performed at various temperature(5, 15, 25, 40 $^{\circ}C$) and relative humidity range (11~84 %) controlled by saturated salt solution. Regression equation was obtained to predict equilibrium moisture according to various relative humidity, temperature and tobacco types. The obtained regression equation showed high $R^2$(above 0.95) and predicted accurate equilibrium moisture. Equilibrium moisture contents declines in the following order when a relative humidity is 50 % or above: expanded stem, flue-cured, expanded tobacco, reconstituted tobacco, USA flue-cured, orient, burley. To maintain 13 % moisture of each tobacco type in the range of 5~40 $^{\circ}C$ it is recommendable to control relative humidity 49~56 % for expanded stem, 50~57 % for flue-cured, 54~61 % for USA flue-cured, 56~60 % for reconstituted tobacco, 57~62 % for expanded tobacco, 58~64 % for orient and 58~65 % for burley, respectively. It means that the relative humidity of each tobacco type should be differently controlled to maintain the same moisture under the same temperature. In the range of 5~25 $^{\circ}C$, the lower temperature showed the higher equilibrium moisture content.