• Title/Summary/Keyword: mmPb

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Evaluation of Piezoelectric Properties in Pb(Zr,Ti)$O_3$-PVDF 0-3Type Composites for Thick Film Speaker Application (후막스피커 응용을 위한 Pb(Zr,Ti)$O_3$-PVDF 0-3형 복합체의 압전 특성 평가)

  • Son, Yong-Ho;Kim, Sung-Jin;Jeong, Joon-Seok;Ryu, Sung-Lim;Kweon, Soon-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.40-41
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    • 2006
  • In this work, we developed the 0-3 type piezoelectric composite to incorporate the advantages of both ceramic and polymer. The PVDF-PZT composites were fabricated with various mixing ratio by 3-roll mi11 mixer. The composite solutions were coated on ITO bottom-electrode deposited on PET (polyethylene terephthalate) polymer film by the conventional screen-printing method. After depositing the top-electrode of silver-paste, 4kV/mm of DC field was applied at $120^{\circ}C$ for 30min to poling the 0-3 composite film. The value of $d_{33}$ was increased as the PZT weight percent was increases. But the $g_{33}$ value showed the maximum at 65 wt% of PZT powder.

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Background reduction by Cu/Pb shielding and efficiency study of NaI(TI) detector

  • Ramadhan, Revink A.;Abdullah, Khairi MS.
    • Nuclear Engineering and Technology
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    • v.50 no.3
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    • pp.462-469
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    • 2018
  • The background spectrum of a $3^{{\prime}{\prime}}{\times}3^{{\prime}{\prime}}$ NaI(Tl) well-type scintillation SILENA detector was measured without shielding, in 6 cm thick lead shielding, and with 2 mm thick electrolytic copper covering the detector inside the lead shielding. The relative remaining background of the lead shield lined with copper was found to be ideal for low-level environmental radioactive spectroscopy. The background total count rate in the (20-2160 KeV) was reduced 28.7 times by the lead and 29 times by the Cu + Pb shielding. The effective reduction of background (1.04) by the copper mainly appeared in the energy range from X-ray up to 500 KeV, while for the total energy range the ratio is 1.01 relative to the lead only. In addition, a strong relation between the full-energy peak absolute efficiency and the detector well height was found using gamma-ray isotropic radiation point sources placed inside the detector well. The full-energy peak efficiency at a midpoint of the well (at 2.5 cm) is three times greater than that on the detector surface. The energy calibrations and the resolution of any single energy line are independent of the locations of the gamma source inside or outside of the well.

A study on the uniformity of the electrodeposits in Pb-Sn-Cu ternary alloy plating (Pb-Sn-Cu삼원 합금 전착층의 균일성 연구)

  • NamGoong, E.;Gwon, Sik-Cheol
    • Journal of Surface Science and Engineering
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    • v.18 no.3
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    • pp.105-115
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    • 1985
  • Lead-tin-copper ternary alloy electrodeposition is conducted onto the inner bore surface of plain bearings as an overlay in order to investigate the effect of slot width, current density and fluoboric acid concentration on the uniformity of overlay. The thickness of overlay is analyzed by means of current distribution resulting from the overvoltage of plating bath and the apparent distance between cathode and anode. The result demonstrate that the uniformity of overlay is remarkably dependent of the slot size and current density, but has little bearing on the fluoboric acid concentration over 100g/L. This present study indicates that uniform overlay is obtainable within the tolerable thickness of ${\pm}2{\mu}m$ by using the slot width of 22mm. The surface morphology examination also shows the important role of concentration polarization of the micro-uniformity of overlay. The micro-uniformity has improved at the low concentration polarization which resulted from operating at the low current density and high fluoboric acid concentration. The surface morphology of deposits exhibits the vivid pyramid crystalline in the plating condition of low concentration polarizatio and all deposits have columnar structure parallel to the applied electric field regardless of the electroplating condition used.

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The Influence of (Pd+Ag) Additions on the Glass Forming Ability of Zr-Al-Cu-Ni based Alloys (Zr-Al-Cu-Ni계 합금의 비정질형성능에 미치는 Pd과 Ag 복합첨가의 영향)

  • Kim, Mi-Hye;Lee, Byung-Woo;Kim, Sung-Gyu;Bae, Cha-Hurn;Jeong, Hae-Yong
    • Journal of Korea Foundry Society
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    • v.24 no.1
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    • pp.40-44
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    • 2004
  • The influence of Pd and Ag additions on the thermal stability, the glass forming ability (GFA) and mechanical property of $Zr_{55}Al_{10}Cu_{20}Ni_{10}Pb_{(5-x)}Ag_x$ (x = $0{\sim}5at%$) alloys obtained by melt spun and injection casting method have been investigated by using of X-ray diffraction, thermal analysis (DTA, DSC) and micro-Vickers hardness(Hv) testing. The thermal properties of melt-spun $Zr_{55}Al_{10}Cu_{20}Ni_{10}Pb_{(5-x)}Ag_x$ (x = $0{\sim}5at%$) alloys exhibit a supercooled liquid region(${\Delta}T_x$) exceeding 91 K before crystallization. The largest ${\Delta}T_x$ reaches as large as 126 K for the $Zr_{55}Al_{10}Cu_{20}Ni_{10}Pb_5$ alloy. The reduced glass transition temperature, $T_{rg}$ increased with increasing Ag content. The largest $T_{rg}$ is obtained for the $Zr_{55}Al_{10}Cu_{10}Ni_{10}Ag_5$ alloy. The $Zr_{55}Al_{10}Cu_{10}Ni_{10}Ag_5$ bulk amorphous alloy rod with 3 mm in diameter was fabricated by injection casting. Hv increased with increasing Ag content and the largest value was obtained for the $Zr_{55}Al_{10}Cu_{10}Ni_{10}Ag_5$ bulk amorphous alloy.

Quantification of Pediatric Cervical Spine Growth at the Cranio-Vertebral Junction

  • Lee, Ho Jin;Kim, Jong Tae;Shin, Myoung Hoon;Choi, Doo Yong;Hong, Jae Taek
    • Journal of Korean Neurosurgical Society
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    • v.57 no.4
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    • pp.276-282
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    • 2015
  • Objective : The purpose of this study was to investigate morphological change at the craniovertebral junction (CVJ) region using computed tomography. Methods : A total of 238 patients were included in this study, and mean age was $47.8{\pm}21.3months$. Spinal canal diameter, Power's ratio, McRae line, antero-posterior C1 ring height, atlantoaxial joint space, C2 growth, epidural space from the dens (M-PB-C2) and longitudinal distance (basion to C2 lower margin, B-C2) were measured. The mean value of each parameter was assessed for individual age groups. The cohorts were then divided into three larger age groups : infancy (I) (${\leq}2years$), very early (VE) childhood (2-5 years) and early (E) childhood ($5{\geq}years$). Results : Spinal canal diameter increased with age; however, this value did not increase with statistical significance after VE age. A significant age-related difference was found for all C2 body and odontoid parameters (p<0.05). Mean McRae line was 8.5, 8, and 7.5 mm in the I, VE, and E groups, respectively. The M-PB-C2 line showed up-and-down dynamic change during early pediatric periods. Conclusion : Expansion of the spinal canal was restricted to the very early childhood period (less than 5 years) in the CVJ region; however, the C2 body and odontoid process increased continuously with age. The above results induced a dynamic change in the M-PB-C2 line. Although C2 longitudinal growth continued with age, the McRae line showed relatively little change.

Distribution of Heavy Metals in the Soils of Hanam City. (경기도 하남시 토양의 중금속 함량 분포 조사)

  • Kim, Kye-Hoon;Kim, Kwon-Rae
    • Korean Journal of Environmental Agriculture
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    • v.19 no.4
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    • pp.345-350
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    • 2000
  • The objectives of this study were to find out distribution of heavy metal contents in the soils of Hanam city and to provide base-line data towards development of an eco-city Hanam. One hundred surface soil (0-20 cm) samples were collected from rice paddy field, cultivated upland, forest, riverside and other areas. The samples were air-dried, sieved to pass through 2 mm sieves, followed by analyses for As, Cd, Cu, Pb and Zn by the standard method set by the ministry of environment. All the average heavy metal contents were close to background level and were much lower than concern level of the Soil Environment Conservation Act of Korea. However, some individual heavy metal contents were higher than the action level. Since natural environment including soil environment of Hanam city is being destroyed rapidly and the number of the sampling points allocated to Hanam city based on the soil contamination monitoring network of the ministry of environment is only 6, an in-depth soil survey for contamination of Hanam city is highly recommended.

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Low Temperature Sintering of PNN-PZT Ceramics and Its Electrical Properties (PNN-PZT 세라믹스의 저온 소결 및 전기적 특성 평가)

  • Lee, Myung-Woo;Kim, Sung-Jin;Yoon, Man-Soon;Ryu, Sung-Lim;Kweon, Soon-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.12
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    • pp.1077-1082
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    • 2008
  • To fabricate a multi-layered piezoelectrics/electrodes structure, the piezoelectrics should be sintered at the temperature lower than $950^{\circ}C$ to use the silver electrode, which is cheaper than the electrodes containing noble metals such as Pd and Pt. Therefore, in this study, we modified the composition of $Pb(Zr,Ti)O_3$-based material as $(Pb_{0.98}Cd_{0.02})(Ni_{1/3}Nb_{2/3})_{0.25}Zr_{0.35}Ti_{0.4}O_3$ to lower the sintering temperature and to improve the piezoelectric properties. Small amount of $MnCO_3$, $SiO_2$, and $Pb_3O_4$ were also added to lower the sintering temperature of the ceramic. The prepared raw powders were mixed by using a ball mill for 24 hours. And then the mixed powders were calcinated for 2 hours at $800^{\circ}C$. The calcinated powders were again crushed with the ball mill for 72 hours. The final powders were pressed for making the shape of ${\emptyset}15\;mm$ disk. The disk-type samples were sintered at temperature range of $850{\sim}950^{\circ}C$. The crystal phases of the sintered specimens were perovskite structure without secondary phases. All of the measured electrical properties such as electromechanical coupling coefficients ($k_p$), mechanical quality factors ($Q_m$), and piezoelectric charge constants ($d_{33}$) were decreased with decreasing the sintering temperatures. The electrical properties measured at the sample sintered at $950^{\circ}C$ were 54% of $k_p$, 503 of $Q_m$, and 390 pC/N of $d_{33}$, respectively. These properties were considered to be fairly good for the application of multi-layered piezoelectric generators or actuators.

Evaluation of Fatigue Resistance of Selected Warm-mix Asphalt Concrete (준고온 아스팔트 콘크리트 피로저항성 평가)

  • Kim, Sungun;Lee, Sung-Jin;Kim, Kwang W.
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.3
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    • pp.29-38
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    • 2020
  • Since some warm-mix asphalt (WMA) concretes were known to show poorer rut resistance than the hot-mix asphalt (HMA) concretes, many studies were performed in efforts of improving its performance at high temperature. The reason is assumed to be due to the moisture remaining in aggregates dried at lower temperature. Therefore, not only the rut resistance, the crack resistance of WMA concrete was also in question. In this study, fatigue life of WMA concrete was evaluated in comparison with HMA using 3-point bending (3PB) beam test. The asphalt mixtures were prepared based on Korean mix-design guide using a 13 mm dense-graded aggregate and 6 binders; two HMA binders and four WMA binders. By 3PB fatigue test, normal (unmodified) and polymer-modified WMA concretes were evaluated in comparison with normal and polymer-modified HMA concretes at a low temperature (-5℃). The results showed that most of WMA concretes showed longer fatigue lives than HMA concretes, even though the same PG binders were used for HMA and WMA. This result indicates that the WMA concretes have stronger resistance against fatigue cracking than HMA at the low temperature, and this result is in contrast to the high-temperature performance test.

Dielectric and Piezoelectric Properties in Multilayer Ceramic Actuator (적층형 세라믹 액츄에이터의 유전 및 압전특성)

  • Choi, Hyeong-Bong;Jeong, Soon-Jong;Ha, Mun-Su;Koh, Jung-Hyuk;Lee, Dae-Su;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.615-618
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    • 2004
  • The piezoelectricity and polarization of multilayer ceramic actuators, being designed to stack ceramic layer and electrode layer alternately, were investigated under a consideration of geometry, the thickness ratio of the ceramic layer to electrode layer The actuators were fabricated by tape-casting of $0.42PbTiO_3-0.38PbZrO_3-0.2Pb(Mn_{1/3}Nb_{2/3})O_3$ followed by laminating, burn-out and co-firing process. The actuators of $5\times5mm^2$ in area were formed in a way that $60{\sim}200{\mu}m$ thick ceramics were stacked 10 times alternately with $5{\mu}m$ thick electrode. Increase in polarization and electric field-displacement with increasing thickness ratio of the ceramic/electrode layer and thickness/cross section ratio were attributed to the change of $non-180^{\circ}/180^{\circ}$ domain ratio which was affected by the interlayer internal stress and Poisson ratio of ceramic layer. The piezoelectricity and actuation behaviors were found to be dependent upon the volume ratio (or thickness ratio) of ceramic layer relative to ceramic layer. Concerning with the existence of internal stress, the field-induced polarization and deformation were described in the multilayer actuator.

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A Study on the Behavior of Charged Particles of $(1-x)(SrPb)(CaMg)TiO_3-Bi_2O_3{\cdot}3TiO_2$ Ceramics ($(1-x)(SrPb)(CaMg)TiO_3-xBi_2O_3{\cdot}3TiO_2$ 세라믹의 하전입자 거동에 관한 연구)

  • Kim, Chung-Hyeok;Choi, Woon-Shik;Jung, Il-Hyung;Chung, Kue-Hye;Lee, Joon-Ung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.11a
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    • pp.34-37
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    • 1992
  • In this paper, the $(SrPb)(CaMg)TiO_3$-xBi_2O_3{\cdot}3TiO_2$ ceramics with paraelectric properties were fabricated by the mixed oxide method. In order to investigate the behavior of charged particles, the characteristics of electrical conduction and thermally stimulated current were measured respectively. As a result on characteristics of the electrical conduction, the leakage current was increased as measuring temperature was increased. At room temperature, the conduction current was divided into the three steps as a function of DC electric field. The first step was Ohmic region due to ionic conduction, below 15[kV/cm]. The second step was showed a saturation which seems to be related to a depolarizing field occuring in field-enforced ferroelectric phase, between 15[kV/cm] and 40[kV/cm]. The third step was attributed to Child's law related to spare charge which injected from electrode, above 40[kV/cm]. Thermally stimulated currents(TSC) spectra with various biasing fields exhibited three distinguished peaks that were denoted as ${\alpha}$, ${\alpha}'$ and ${\beta}$ peak, each of which appeared at nearby -30, 20 and 95[$^{\circ}C$] respectively. It is confirmed that the a peak was due to trap electron trapped in the grainboundary, and ${\alpha}'$ peak that was observed above only 1.5[kV/mm] was attributed to field-enforced ferroelectric polarization. The origin of ${\beta}$ peak was identified as ion migration which caused the degradation.

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