• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.163-169
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• 2020

Synthesis of Fe-Co/meso-HZSM5 catalyst, intended to be applied in Fischer-Tropsch (FT) reaction was investigated. The study emphasized the effect of desilication agents, NaOH and KOH, on the catalyst materials properties. Impregnation composition of active metal (Fe and Co) was also examined. HZSM-5, converted from ammonium ZSM-5 through calcination, was treated with NaOH and KOH for desilication, followed by impregnation with 10% metal loading. Fe composition in the initial mixture was varied at 10-50% from total composition. After impregnation, reduction was applied by flowing hydrogen gas at 400 ℃ for 10 hours. The use of KOH solution induced greater mesoporous volumes; however, it had a detrimental effect on zeolite crystal structure. NaOH solutions, on the other hand, increased mesopore area as high as 100%, indicated from surface area increase from 266.28 m²/g of HZSM-5, to 526.03 m²/g of NaOH-desilicated HZSM-5. In addition, the application of NaOH solution increased pore volume from 0.14 cc/g to 0.486 cc/g. Further, more Fe-Co alloys and less oxide of iron (Fe₂O₃) as well cobalt (Co₃O₄) had been commonly observed in the produced catalysts. The largest Fe-Co alloys could be found in 50Fe-50Co/HZSM-5

• Journal of the Korean Ceramic Society
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• v.42 no.4
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• pp.232-236
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• 2005

The etching characteristics of a $LiNbO_{3}$ optical waveguide structure have been investigated using neutral loop discharge plasma with the mixture of $C_{3}F_{8}$ and Ar and the bias power parameters. The etching rate and profile angle of optical waveguide with etching parameters were evaluated by scanning electron microscopy. Also, the etching RMS roughness was evaluated by atomic force microscopy. From the results of optimum etching conditions are the $C_{3}F_{8}$ gas flow ratio of 0.2 and the bias power of 300 W.

• Journal of the Korean Electrochemical Society
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• v.8 no.1
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• pp.24-31
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• 2005

Ion shower doping with a main ion source of $P_2H_x$ using a source gas mixture of $PH_3/H_2$ was conducted on excimer-laser-annealed (ELA) poly-Si.The crystallinity of the as-implanted samples was measured using a UV-transmittance. The measured value using UV-transmittance was found to correlate well with the one measured using Raman Spectroscopy. The sheet resistance decreases as the acceleration voltage increases from 1kV to 15kV at the moderate doping conditions. It, however, increases as the acceleration voltage increases under the severe doping conditions. The reduction in carrier concentration due to electron trapping at uncured damage after activation annealing seems to be responsible for the rise in sheet resistance. Three different annealing methods were investigated in terms of dopant-activation and damage-recovery, such as furnace annealing, excimer laser annealing, and rapid thermal annealing, respectively.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.8
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• pp.510-515
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• 2016

Single-chamber solid oxide fuel cells (SC-SOFCs) consist of only one gas chamber, in which both the anode and the cathode are exposed to the same fuel-oxidant mixture. Thus, this configuration shows good thermal and mechanical resistance and allows rapid start-up and -down. In this study, the unit cell consisting of $La_{0.8}Sr_{0.2}MnO_3$ (cathode) / $Zr_{0.84}Y_{0.16}O_{2-x}$ (electrolyte) / $Ni-Zr_{0.84}Y_{0.16}O_{2-x}$ (anode) was fabricated and its electrochemical property was investigated as a function of temperature and the volume ratio of fuel and oxidant for SC-SOFCs. Impedance spectra were also investigated in order to figure out the electrical characteristics of the cell. As a result, the cell performance was governed by the polarization resistances of the electrodes. The cell exhibited an acceptable cell-performance of $86mW/cm^2$ at $800^{\circ}C$ and stable performance for 3 hs under 0.7 V.

• Korean Journal of Materials Research
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• v.28 no.5
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• pp.301-307
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• 2018

A boron-doped diamond(BDD) electrode is attractive for many electrochemical applications due to its distinctive properties: an extremely wide potential window in aqueous and non-aqueous electrolytes, a very low and stable background current and a high resistance to surface fouling. An Ar gas mixture of $H_2$, $CH_4$ and trimethylboron (TMB, 0.1 % $C_3H_9B$ in $H_2$) is used in a hot filament chemical vapor deposition(HFCVD) reactor. The effect of argon addition on quality, structure and electrochemical property is investigated by scanning electron microscope(SEM), X-ray diffraction(XRD) and cyclic voltammetry(CV). In this study, BDD electrodes are manufactured using different $Ar/CH_4$ ratios ($Ar/CH_4$ = 0, 1, 2 and 4). The results of this study show that the diamond grain size decreases with increasing $Ar/CH_4$ ratios. On the other hand, the samples with an $Ar/CH_4$ ratio above 5 fail to produce a BDD electrode. In addition, the BDD electrodes manufactured by introducing different $Ar/CH_4$ ratios result in the most inclined to (111) preferential growth when the $Ar/CH_4$ ratio is 2. It is also noted that the electrochemical properties of the BDD electrode improve with the process of adding argon.

• 보존과학연구
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• s.14
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• pp.94-108
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• 1993

The cultural properties of cloth are of animal orgin (silk), or of vegetable orgin(cotton, hemp, ramie). As clothes are of an orginic material, they were subjected to damage by chemical, phisigical or biological factors, viz, moulds insects, lights, humidity and temperature changes, etc. And these factors promote that clothes generally result from various types of deterioration. In 1992, We were performed the conservation treatments for total 9 pieces of cloth, such as 3 pieces of General PAK SHIN-RYONG(Important Folklore Material No.110) 3 pieces of Madam Jung(Important Folklore Material No.115) and 1 piece of King Se-jo(Important Folklore Material No.219). The procedure of the conservation treatment for clothes describe the following below. 1) The washing and dry-cleaning to remove the contaminated substances from cloth was used 0.2% stearyl potassium soap solution and the mixture solution compound of n-Hexane, C6H14. and n-Decane, C10H22. And after the washing and dry-cleaning, the dry of clothes was carried out in a warm condition. These steps were repeated in 2 times over for each cloth. 2) The repair of clothes was attached the similar textiles to stronger fabric linings by needlework.3) The reprodution was made for cloth of King Se-jo to equalize the type, color, quality and skill of materials. 4) After these above procedures, all clothes fumigated to prevent the biodeterioration by using the mixed gas of methyl bromide and ethylene oxide as insecticide and fungicide. 5) Finally for the purpose to keep in a safety long-term condition, the treated clothes sealed with Biaxially Oriented Polyvinylacohol Film(BO-PVA film) and Helium, purity 99.999%, filled up in sealed BO-PVA film bag.

• Nuclear Engineering and Technology
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• v.23 no.4
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• pp.438-443
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• 1991

The operational characteristics of the duoplasmatron ion source are investigated in order to obtain the maximum achievable extraction current of the $He^+$ ion beam with the small divergence. Under the variations of the gas pressure, the arc current, the magnet current and the extraction voltage of the ion source, the change of the extracted $He^+$ ion beam current is observed. An oxide filament, the mixture of BaO and SrO coated on Ni meshes, is used as the hot cathode, and its average lifetime is about 100 hours. The extraction current is linearly proportional to the arc current. As the magnet current of the ion source is increased, the extraction current increases, but the beam divergence becomes larger. The maximum extraction current is obtained at the source pressure of 0.084 Torr. The extraction current is proportional to the extraction voltage raised to the power of 3/2 as estimated from theory. At the extraction voltage of 5.72 kV, the maximum extraction current of 50 $\mu$A is obtained under the optimized extraction condition.

• Clean Technology
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• v.13 no.1 s.36
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• pp.72-78
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• 2007

As a basic research fur the separation of effective components included in pyrolysis gas oil, the crystallization on each system of naphthalene with 2-methylnaphthalene, indene and 1-methylnaphthalene as impurity has been carried out in column and cold-finger type crystallizer, respectively. In crystallization operation, the purity of naphthalene has been a tendency of increase with decreasing of cooling rate and in the presence of impurity with lower melting point. In comparison of crystallizer types, naphthalene purity in column type crystallizer was a higher value than that in cold-finger type due to effective sweating operation after crystallization.

• Nuclear Engineering and Technology
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• v.23 no.2
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• pp.183-199
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• 1991

Transient response of temperature distributions in a Pressurized Water Reactor (PWR) pressurizer vessel wall for the Inadvertent Auxiliary Spray transient has been analyzed with conservatism accounted for the resulting thermal stresses in the regions of the vessel wall which are wetted by the spray water droplets. In order to determine the forced convective heat transfer coefficient at the inner boundary surface of vessel wall where the droplets impinge on and flow down, the transient temperatures of spray droplets when they reach the inner surface of the vessel wall after travelling from the spray nozzle through the pressurizer interior space occupied with the saturated steam-noncondensable hydrogen gas mixture have been predicted. The transient temperature distributions in the vessel wall have been obtained by using the finite element method, and the typical results have been provided. It has been shown that the results of thermal analysis are consistent with representation of the input transient and have plausible physical meaning.

• Korean Journal of Veterinary Research
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• v.25 no.2
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• pp.133-144
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• 1985

The changes of acid-base status in vitro of the venous blood for 24 hours in ten Korean native goat were investigated. The acid-base parameters were measured within ten minutes after collection of the blood, and every hour during the first six hours and finally after twenty four hours of storage. Blood samples were stored at two different temperatures ($0-4^{\circ}C$ and $21-24^{\circ}C$). Twelve goats were induced acute acid-base disturbances by intravenous infusion of either hydrochloric acid or sodium bicarbonate and inhalated with $CO_2$ gas mixture (20% $CO_2$, 80% $O_2$) or hyperventilation were performed by means of respirator. The results were as follows; 1. Blood samples could be stored during the first two hours in ice water ($0-4^{\circ}C$) and one hour at room temperature without significant changes in pH. The magnitudes of changes were similar to those of cow, and lower than those of men and dogs. 2. The mean values of acid-base parameters in normal goat were arterial pH, 7.40; $P_{CO_2}$, 35.4mmHg; $HCO_3{^-}$, 21.8mEq/L. 3. Both the base excess and the bicarbonate showed high correlation (r=0.99) during the metabolic disturbance and were represented as $B.E.=1.38\;HCO^-{_3}-29.7$. 4. The slope of blood buffer curve obtained from the in vivo experiment was 16.3mEq/L/pH. 5. The magnitudes of changes in hydrogen ion concentration per unit change of $P_{CO_2}$ were 0.8nM/mmHg in hypercapnia and 1.0nM/mmHg in hypocapnia. 6. The ranges of acid-base parameters in normal goat urine were pH, 6.0-8.1; $P_{CO_2}$, 42-61mmHg; $HCO_3{^-}$, 2-110mEq/L. The concentration of potassium was higher (60-200mEq/L), and that of sodium was lower (8-70mEq/L) than those of human urine.