• 제목/요약/키워드: mixture gas

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Properties and Mock-up Test of Lightweight Foamed Concrete Based on Blast Furnace Slag by Crack Reducing Admixture (팽창성 균열저감제를 이용한 고로슬래그 미분말 기반 경량기포 콘크리트의 특성 및 목업실험)

  • Han, Sang-Yoon;Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.6
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    • pp.507-515
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    • 2017
  • This study is to develop a high quality lightweight foamed concrete that can be applied in the field using EXFG by cracking reducing agent combined with FGD and ALS. First, to increase the volume of foam, the flow and density of the mixture was increased and decreased, respectively. At this time, the effect of substitution ratio of EXFG on fluidity was negligible. The fraction of foam was the highest at EXFG 1%, and the settlement was found to be prevented by the expansion reaction at EXFG 1%. At this time, the ratio of foam was 65%. In the compressive strength, the strengths were similar or decreased when the substitution ratio of EXFG was more than 1%. The apparent density satisfied the KS 0.5 type at the bubble contents was 65%. In case of EXFG substitution, dry shrinkage was decreased by about 10%. As the substitution ratio of EXFG increased, the thermal conductivity increased proportionally.

Tin Germanium Sulfide Nanoparticles for Enhanced Performance Lithium Secondary Batteries (고성능 리튬 이차 전지를 위한 황화 주석 저마늄 (SnxGe1-xS) 나노입자 연구)

  • Cha, E.H.;Kim, Y.W.;Lim, S.A.;Lim, J.W.
    • Journal of the Korean Electrochemical Society
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    • v.18 no.1
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    • pp.31-37
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    • 2015
  • Composition-controlled ternary components chalcogenides germanium tin sulfide ($Sn_xGe_{1-x}S$) nanoparticles were synthesized by a novel gas-phase laser photolysis reaction of tetramethyl germanium, tetramethyl tin, and hydrogen sulfide mixture. Subsequent thermal annealing of as-grown amorphous nanoparticles produced the crystalline orthorhombic phase nanoparticles. All these composition-tuned nanoparticles showed excellent cycling performance of the lithium ion battery. The germanium sulfide nanoparticles exhibit a maximum capacity of 1200 mAh/g after 70 cycles. As the tin composition (x) increases, the capacity maintains better at the higher discharge/charge rate. This novel synthesis method of tin germanium sulfide nanoparticles is expected to contribute to expand their applications in high-performance energy conversion systems.

Statistical Analysis of Experimental Results on Emission Characteristics of Biodiesel Blended Fuel (바이오디젤 혼합연료의 배기특성 실험결과에 대한 통계학적 해석)

  • Yeom, Jeong Kuk;Yoon, Jeong Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.12
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    • pp.1199-1206
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    • 2015
  • In this study, the exhaust gas of a diesel engine operating on biodiesel(BD) fuel(a mixture of diesel and soybean oil) was investigated for different fuel mixing ratios in the range of BD3 to BD100. The experiments were conducted using injection pressures of 400, 600, 800, 1000, and 1200 bar. The Pearson correlation coefficient and Spearman rank-order correlation coefficient were used to quantify the NOx and Soot emissions based on the fuel mixing ratio and injection pressure. Consequently, the Pearson correlation coefficient obtained for NOx and Soot emissions according to the mixing ratio and injection pressure was -0.811 and the corresponding Spearman rank-order correlation coefficient was -0.884, which indicated that the correlation of the NOx and Soot emissions was linear. Thus, the NOx and Soot have a trade-off relationship. Moreover, at each injection pressure, the Pearson correlation coefficient was a negative number, which indicated an inversely proportional relationship between NOx and Soot.

Evaluation of proficiency and improvement of accuracy on the analysis of brominated flame retardants (PBDEs) in ABS polymer (ABS수지 중 polybrominated diphenyl ether(PBDE)류 분석 숙련도 평가 및 정확도 향상)

  • Ryu, Jehoon;Kim, Dalho
    • Analytical Science and Technology
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    • v.28 no.6
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    • pp.446-452
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    • 2015
  • In order to evaluate and improve the ability of Korean testing laboratories to measure Polybrominated diphenyl ethers in acrylonitrile-butadiene-styrene (ABS), a proficiency test was organised by Korea Research Institute of Standards and Science (KRISS) based on ISO/IEC 17043. The proficiency test material used was 10 g of a granular ABS fortified with a mixture of congeners of PBDE (BDE-154, 183, 206, 209). Homogeneity and stability were investigated to assess the adequacy of the test material. The certified value established by KRISS based on the national reference was used for assigned value of each PBDE. The test materials were distributed to the 16 participating laboratories. The participating laboratories were requested to analyse the samples employing the methods used in their routine analysis. Each laboratory was given it’s own code to secure the anonymity. Participants results were evaluated with z-scores according to ISO/IEC 17043. The standard deviation for proficiency assessment was set by standard deviation of the participants results except for outlier. The results, the laboratory's performance and improvement of accuracy were discussed.

Electrical Properties of Laser CVD Silicon Nitride Film (Laser CVD SiN막의 전기적 특성)

  • Kim, Yong-Woo;Kim, Sang-Wook;Park, Jong-Wook;Kim, Chun-Sub;Sung, Yung-Kwon
    • Proceedings of the KIEE Conference
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    • 1990.11a
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    • pp.85-87
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    • 1990
  • Silicon nitride film was deposited on a silicon wafer using a laser CVD(LCVD) technique, which is based on direct photolysis of $SiH_4/NH_3$ gas mixture by ArF laser beam(${\lambda}=193\;nm$). The refractive index of deposited SiN film is 1.9 at the temperature of $300^{\circ}C$, pressure of 5 torr. The breakdown field strength of LCVD SiN film was 10MV/cm. In IR spectrum, the absorption peak of Si-H, N-H, and Si-N is detected and it is shown that hydrogen is included in SiN film. From analysis of absorption band. it is calculated that density of Si-H, N-H bond is higher than $5{\times}10^{22}cm^{-3}$. LCVD MIS capacitor and PECVD MIS capacitor have injection-type hysteresis but it is known that hysteresis loss of LCVD MIS capacitor is smaller than that of PECVD MIS capacitor. It means that Interface state density of LCVD capacitor is smaller than that of PECVD capacitor. In addition, the flatband voltage($V_{FB}$) of LCVD is smaller than that of PECVD capacitor. And it means that fixed charged density($Q_{FIX}$) of LCVD capacitor is smaller than that of PECVD MIS capacitor.

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A study of Compositional range of Ti-Si-N films for the ULSI diffusion barrier layer (ULSI 확산억제막으로 적합한 Ti-Si-N의 조성 범위에 관한 연구)

  • 박상기;강봉주;양희정;이원희;이은구;김희재;이재갑
    • Journal of the Korean Vacuum Society
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    • v.10 no.3
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    • pp.321-327
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    • 2001
  • Ti-Si-N films obtained by using RF reactive sputtering of targets with various Ti/Si ratios in a $N_2(Ar+N_2)$ gas mixture have been investigated in terms of films resistivity and diffusion barrier performance. The chemical bonding state of Si in the Ti-Si-N film which contained a higher Si content was in the form of amorphous $Si_3N_4$, producing increased film resistivity with increased $N_2$flow rate. Lowering the Si content in the deposited Ti-Si-N film favored the formation of crystalline TiN even at low $N_2$flow rates, and leads to low film resistivity. In addition increasing the N content led to Ti-Si-N films having a higher density and compressive stress, suggesting that the N content in the films appear to be one of the most important factors affecting the diffusion barrier characteristics. Consequently, we proposed the optimum composition in the range of 29~49 at.% of Ti, 6~20 at.% of Si, and 45~55 at.% of N for the Ti-Si-N films having both low resistivity and excellent diffusion barrier performance.

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Quantitative analysis of the effect of fraction of inspired oxygen on peripheral oxygen saturation in healthy volunteers

  • Kang, Bong Jin;Kim, Myojung;Bang, Ji-Yeon;Lee, Eun-Kyung;Choi, Byung-Moon;Noh, Gyu-Jeong
    • Journal of Dental Anesthesia and Pain Medicine
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    • v.20 no.2
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    • pp.73-81
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    • 2020
  • Background: The international organization for standardization (ISO) 80601-2-61 dictates that the accuracy of a pulse oximeter should be assessed by a controlled desaturation study. We aimed to characterize the relationship between the fraction of inspired oxygen (FiO2) and peripheral oxygen saturation (SpO2) using a turnover model by retrospectively analyzing the data obtained from previous controlled desaturation studies. Materials and Methods: Each volunteer was placed in a semi-Fowler's position and connected to a breathing circuit to administer the hypoxic gas mixture containing medical air, oxygen, nitrogen, and carbon dioxide. Volunteers were exposed to various levels of induced hypoxia over 70-100% arterial oxygen saturation (SaO2). The study period consisted of two rounds of hypoxia and the volunteers were maintained in room air between each round. FiO2 and SpO2 were recorded continuously during the study period. A population pharmacodynamic analysis was performed with the NONMEM VII level 4 (ICON Development Solutions, Ellicott City, MD, USA). Results: In total, 2899 SpO2 data points obtained from 20 volunteers were used to determine the pharmacodynamic characteristics. The pharmacodynamic parameters were as follows: kout = 0.942 1/min, Imax = 0.802, IC50 = 85.3%, γ = 27.3. Conclusion: The changes in SpO2 due to decreases in FiO2 well explained by the turnover model with inhibitory function as a sigmoidal model.

Study on Backfire for a Two-Stroke Hydrogen Fueled Free-Piston Engine with Loop Scavenging (루프소기방식을 갖는 2행정 프리피스톤 수소기관의 역화에 관한 연구)

  • Cho, Kwan-Yeon;Byun, Chang-Hee;Back, Dae-Ha;Lee, Jong-Tae
    • Journal of Hydrogen and New Energy
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    • v.21 no.6
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    • pp.487-492
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    • 2010
  • For developing a two-stroke free-piston hydrogen engine with high efficiency and low emission, determination of the scavenging type is one of the most important factor. In this research, backfire characteristics for loop scavenging were analyzed with the number of piston crevice volume and piston expansion speed. Rapid Compression Expansion Machine, RCEM was used for combustion research of the free piston $H_2$ engine in the experiment. As the results, it was shown that although backfire occurring in a loop scavenging type can be partially controled by a complete exhaust of burned gas, possibility of backfire basically exist due to the structure which piston crevice volumes contact with fresh mixture in a scavenging port. However, a loop scavenging may be considered as combustion chamber of a free piston $H_2$ engine from the point of view that backfire does not occur nearby lean equivalence ratio obtained high thermal efficiency. It was also analyzed that an advances of backfire occurrence timing with increase of the fuel-air equivalence ratio were due to promotion of flame propagation into piston crevice volumes by decrease of the quenching distance.

Flame Structure and Light Emission Characteristics in Coaxial Laminar Partially Premixed $CH_{4}/Air$ Flames;Effect of Central Fuel Injection (이중동축 메탄/공기 층류 부분 예혼합화염에서의 화염구조와 자발광 배출 특성;안쪽관 연료주입의 영향)

  • Oh, Jeong-Seog;Jeong, Yong-Ki;Jeon, Chung-Hwan;Chang, Young-June
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1116-1121
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    • 2004
  • In this study, the effect of central fuel injection on a coaxial laminar $CH_{4}/air$ flame was experimented at the defined premixing condition(${\Phi}=1.90$, ${\sigma}=50/75/100%$, x/D=10). The partial premixing parameter are the equivalence ratio that total fuel is fixed at 200cc/min, the fuel split degree which means the percentage of fuel entering the outer tube to the total amount, and the mixing distance indicating the nonreactant mixture's homogeneity between inner tube top and burner exit. The object is to investigate the flame structure and chemiluminescence characteristics of laminar partial premixed flame as changing mixing parameters. The radical signal was acquired from ICCD camera and PMT. Each intensity was compared with Abel inverted value for measuring the effect of background light on the peak signal location and the intensity at central preheat zone. The results show that the peak location of each radical was broaden as the fuel split degree increasing because the mixing quality was enhanced. and $OH^{\ast}$ is a good indicator for flame front between reaction and preheat zone. At last $CH_{2}^{\ast}$ has the same tendency with $CH^{\ast}$ but a thinner reaction zone than $CH^{\ast}$ due to a rapid decay on the burned gas side.

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Study on Analysis of Flow Field in Ejector Suction Pipe (이젝터 흡입관의 유동장 분석에 관한 연구)

  • Kim, Noh-Hyeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.10
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    • pp.989-999
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    • 2012
  • An ejector is a fluid transportation device that operates based on the principle that a high-pressure fluid is spouted through a driving pipe and the pressure of a low-pressure fluid is increased through exchange of momentum with a low-pressure gas. Steam-steam ejectors have been widely used for suction, mixture, and dehydration. They can be easily used in places where fluid moves and expenses are reasonable. In addition, such ejectors are a semi-permanent fluid device that requires little maintenance. In this study, we present an optimized design by analyzing what cannot be obtained through experiments in order to improve the device performance, analyze general contents of a flow by acquiring exact test data on specific and interpretative areas using more advanced experimental techniques, and identify the flow characteristics of a branch pipe by examining the validity of experiments using computer hydrodynamics simulations.