• 한국환경과학회지
• /
• 제25권5호
• /
• pp.737-744
• /
• 2016

For electrolysis process using an insoluble electrode, electrochemical performance was greatly affected by the manufacturing method and procedure, such as the firing temperature, pre-treatment, type of precursor solution, coating method, electrode material, etc. Components of the electrode therein is one of the most important factors in electrochemical reaction. To achieve such characteristics, a appropriate ratio of the electrode material should be carefully chosen. The aim of this research was to apply experimental design method in the optimization of electrode component for the maximum generation of oxidants in electrochemical oxidation process. Mixture design, especially expanded simplex lattice design, in DOME (design of mixture experiments) with Design Expert - commercial software - was used to analyze the data. Analysis of variance (ANOVA) showed a high coefficient of determination ($R^2$) value of 0.9470, thus ensuring a satisfactory adjustment of the $3^{rd}$ order special cubic regression model with the experimental data. The application of response surface methodology (RSM) yielded the following regression equation, which is an empirical relationship between the TRO generation concentration and independent variables(mol ratio of 3 electrode components) in a real unit: TRO generation concentration $(mg/L)=TRO\;conc.=98.25{\times}[Ir]+49.71{\times}[Sn]+95.29{\times}[Sb]-16.91{\times}[Ir]{\times}[Sn]-29.47{\times}[Ir]{\times}[Sb]-22.65{\times}[Sn]{\times}[Sb]+703.19{\times}[Ir]{\times}[Sn]{\times}[Sb]$. The optimized formulation of the 3 component electrode for an high TRO (total residual oxidants) generation was acquired at mol ratio of Ir 0.406, Sn 0.210, Sb 0.384 (desirability d value, 1).

• 산업공학
• /
• 제18권4호
• /
• pp.402-411
• /
• 2005

Secondary batteries with high performance are essential in widespread use of modern portable devices such as cellular phones and laptop computers. High energy density, long cycle life, and safety are some of important requirements for secondary battery. To achieve such characteristics, a mixing proportion of electrolyte solution ingredients in the battery should be carefully chosen. In this paper, using statistical design of mixture experiments (DOME), we attempt to find an optimum condition of designing the secondary battery. DOME has a distinct feature in that the experimental region is represented by simplex, rather than hypercube, because the sum of blend proportions should be unity. Several designs based upon this point have been proposed for mixture experiments. Among them, an extreme vertices design is employed in this paper because there are a couple of blend constraints to be considered. In order to investigate how the mixing proportion interacts with other manufacturing factors, a fractional factorial design is also included across the extreme vertices design. As a result, we find that the blend proportion of solution ingredients has a significant effect on battery performances. By simultaneously optimizing two battery capacities, this paper proposes an optimum blend proportion according to process factor settings.

• 공업화학
• /
• 제32권5호
• /
• pp.574-580
• /
• 2021

최고 품질의 클렌징 제품 개발을 위해서 계면활성제 혼합물 조성의 최적화를 시도하였다. 사전실험을 통해 세정력, 기포형성력, 오염률에서 각각 우수한 특성을 나타내는 계면활성제 3종 sodium cocoyl alaninate (SCoA), cocamidopropyl betaine (CPB), decyl glucoside (DG)을 선정하였다. 계면활성제 혼합물의 심플렉스 중심 설계 배열에 따른 실험을 수행하고, 실험에서 얻어진 데이터를 가지고 회귀분석을 실시하였다. 통계적으로 유의미한 반응 표면 모델식을 구하고, 세 개의 반응변수의 동시 최적화 과정을 통해 계면활성제 혼합물의 최적 조성은 SCoA (0.22), CPB (0.78), DG (0.00)으로 구해졌다.

• 한국연소학회지
• /
• 제19권4호
• /
• pp.49-55
• /
• 2014

Design criterion for the size of micro Pt-catalytic combustor is investigated in terms of heat release rate. One-dimensional plug flow model is applied to determine the surface reaction constants using the experimental data at stoichiometric butane-air mixture. With these reaction constants, the mass fraction of butane and heat release rate predicted by the plug flow model are in good agreement with the experimental data at the combustor exit. The relationship between the size of micro catalytic combustor and mixture flowrate is introduced in the form of product of two terms-the effect of fuel conversion efficiency, and the effect of chemical reaction rate and mass transfer rate.

• Computers and Concrete
• /
• 제19권5호
• /
• pp.555-566
• /
• 2017

Recently some efforts have been performed to combine the advantages of light-weight and self-compacting concrete in one package called Light-Weight Self-Compacting Concrete (LWSCC). Accurate prediction of hardened properties from fresh state characteristics is vital in design of concrete structures. Considering the lack of references in mixture design of LWSCC, investigating the proper mixture components and their effects on mechanical properties of LWSCC can lead to a reliable basis for its application in construction industry. This study utilizes wide range of existing data of LWSCC mixtures to study the individual and combined effects of the components on the compressive strength. From sensitivity of compressive strength to the proportions and interaction of the components, two equations are proposed to estimate the LWSCC compressive strength. Predicted values of the equations are in good agreement with the experimental data. Application of lightweight aggregate to reduce the density of LWSCC may bring some mixing problems like segregation. Reaching a higher strength by lowered density is a challenging problem that is investigated as well. The results show that, the compressive strength can be improved by increasing the of mixture density of LWSCC, especially in the range of density under $2000Kg/m^3$.

• 한국의류산업학회지
• /
• 제13권1호
• /
• pp.7-16
• /
• 2011

Maximalism is the code which has a power to interpret a fashion phenomenon expressed complexly and variously in the multicultural society. In the 21st century, maximalism which reappeared is not the expression by a method only. It is presenting the experimental design for the new pursuit through the mixture such as expansion, splendor, variety, decoration, distortion of configuration or transformation, and composition. Therefore, this study aims at analyzing expression of fashion design by four types(expansion, decoration, mixture, non-structure) materializing a feature of maximalism expressed in the domestic and foreign collection works from 2005 to 2010. The research results are as follows. 1. Expansion: It was showed artificial, formative, unique, and odd teatures through the expansion of the upper half of the body, the lower half of the body, and both of them. 2. Decoration: It was showed the actual decoration considering functionality and practicality and the decoration emphasizing and unique character and featuring domination and emphasis. 3. Mixture: It was showed through the mixture of the contrary textiles or the different sex image. 4. Non-structure: It showed the non-structure of the avant-garde trend and non-structure through decoration, detail, adjustment direction of a dress.

• 산업경영시스템학회지
• /
• 제33권1호
• /
• pp.1-9
• /
• 2010

Quality design methodologies have received constituent attention from a number of researchers and practitioners for more than twenty years. Specially, the quality design for drug products must be carefully considered because of the hazards involved in the pharmaceutical industry. Conventional pharmaceutical formulation design problems with mixture experiments have been typically studied under the assumption of an unconstrained experimental region with a single quality characteristic. However, real-world pharmaceutical industrial situations have many physical limitations. We are often faced with multiple quality characteristics with constrained experimental regions. ln order to address these issues, the main objective of this paper is to propose a robust desirability function (RDF) model using a desirability function (DF) and mean square error (MSE) to simultaneously consider a number of multiple quality characteristics. This paper then present L-pseudocomponents and U-pseudocomponents to handle physical constraints. Finally, a numerical example shows that the proposed RDF can efficiently be applied to a pharmaceutical process design.

• 한국구조물진단유지관리공학회 논문집
• /
• 제24권3호
• /
• pp.26-38
• /
• 2020

자기 충전형 콘크리트의 배합물 설계는 전형적인 다기준의사결정의 과정이다. 본 연구에서는 실험설계법과 반응표면법을 이용하여 SCC 배합물 전산 설계가 가능하도록 재료성능 및 비용모델을 생성하고, 요구조건을 반영한 여러 성능 사이의 상대적 중요도를 산정하여 가중 다목적 설계문제로 정식화하여 수치최적해를 계산함으로써 비용효율을 고려한 SCC최적설계를 수행하였다. 실험비용과 시간을 고려하여 SCC의 수많은 요구성능 중 압축강도, 철근충전성, 재료분리저항성, 비용정보 등을 다목적 최적화의 목적함수로 설정하였다. 재료경제성을 최적재료설계프로세스에 합리적으로 반영함으로써 경제적 콘크리트배합설계를 수행할 수 있었으며, 본 연구 결과 실험점 계획에서부터 최적해 산출에 이르는 과정을 객관적인 프로세스로 구성함으로써 콘크리트 범용 최적재료설계기술 및 전산화를 기대할 수 있다.

• 한국도로학회논문집
• /
• 제13권1호
• /
• pp.41-48
• /
• 2011

환경보호에 부응하고 고에너지효율성을 갖춘 중온아스팔트혼합물이 가열아스팔트혼합물의 대안으로 부각되고 있다. 본 연구의 목적은 아스파민을 혼합하여 제조한 중온아스팔트혼합물을 실험적으로 평가하고, 역학적-경험적 포장설계법인 MEPDG를 이용하여 설계한 결과를 일반아스팔트혼합물 설계와 비교하는 것이다. 실험재료는 최대공칭치수 12.5mm인 골재와 PG64-28바인더가 사용되었으며, 기존 혼합물, 0.3%와 0.5%의 아스파민을 혼합한 중온아스팔트혼합물에 대한 회복탄성계수실험이 실시되었다. 실험결과를 MEPDG 설계의 입력변수로 하여 분석한 결과, 아스파민을 사용한 중온아스팔트혼합물의 소성변형량이 일반혼합물에 비해 훨씬 적어 소성변형에 대한 저항성이 향상됨을 알 수 있었다.

• 응용통계연구
• /
• 제28권1호
• /
• pp.93-102
• /
• 2015

D-최적 등을 위시한 최적실험은 비선형모형인 경우 추정을 하여야할 모수에 의존하는 문제점이 존재한다. 따라서 기본적으로 문헌에서는 모수추정을 위해서는 순차실험을 제안한다. 본 연구에서는 2단계 실험설계를 모수추정의 사례를 포함한 다양한 환경 하에서의 사용방법을 알아보았다. 본 연구에서 제안한 내용은 단계의 수나 구체적인 실험기준의 숫자에 상관없이 적용되는 범용적인 기준이다. 본 연구는 2단계 실험에서 3개 이상의 실험목적을 가지고 있는 경우 하이브리드(hybrid)방법을 제안하였다. 모든 실험은 근사실험설계의 형태로 논의되었다.