• Title/Summary/Keyword: mixing state

검색결과 501건 처리시간 0.026초

Use of Wet Chemical Method to Prepare β Tri-Calcium Phosphates having Macro- and Nano-crystallites for Artificial Bone

  • Chang, Myung Chul
    • 한국세라믹학회지
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    • 제53권6호
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    • pp.670-675
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    • 2016
  • Calcium phosphate crystallites were prepared by wet chemical method for use in artificial bone. In order to obtain ${\beta}$-tricalcium phosphate (TCP), nano-crystalline calcium phosphate (CaP) was precipitated at $37^{\circ}C$ and at $pH5.0{\pm}0.1$ under stirring using highly active $Ca(OH)_2$ in DI water and an aqueous solution of $H_3PO_4$. The precipitated nano-crystalline CaP solution was kept at $90^{\circ}C$ for the growth of CaP crystallites. Through the growing process of CaP crystallites, we were able to obtain various sizes of rectangular CaP crystallites according to the crystal growing times. Dry nano-crystalline CaP powders at $37^{\circ}C$ were mixed with dry macro-crystalline CaP crystallites and the shaped mixture sample was fired at $1150^{\circ}C$ to make a ${\beta}-TCP$ block. Several tens of nm powders were uniformly coated on the surface, which was comprised of powders of several tens of ${\mu}m$, using a vibrator. The mixing ratio between the nanometer powders and the micrometer powders greatly affected the mechanical strength of the mixture block; the most appropriate ratio of these two materials was 50 wt% to 50 wt%. The sintered block showed improved mechanical strength, which was caused by the solid state interaction between the nano-crystalline ${\beta}-TCP$ and the macro-crystalline ${\beta}-TCP$.

NUMERICAL ANALYSIS OF THERMAL STRATIFICATION IN THE UPPER PLENUM OF THE MONJU FAST REACTOR

  • Choi, Seok-Ki;Lee, Tae-Ho;Kim, Yeong-Il;Hahn, Dohee
    • Nuclear Engineering and Technology
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    • 제45권2호
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    • pp.191-202
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    • 2013
  • A numerical analysis of thermal stratification in the upper plenum of the MONJU fast breeder reactor was performed. Calculations were performed for a 1/6 simplified model of the MONJU reactor using the commercial code, CFX-13. To better resolve the geometrically complex upper core structure of the MONJU reactor, the porous media approach was adopted for the simulation. First, a steady state solution was obtained and the transient solutions were then obtained for the turbine trip test conducted in December 1995. The time dependent inlet conditions for the mass flow rate and temperature were provided by JAEA. Good agreement with the experimental data was observed for steady state solution. The numerical solution of the transient analysis shows the formation of thermal stratification within the upper plenum of the reactor vessel during the turbine trip test. The temporal variations of temperature were predicted accurately by the present method in the initial rapid coastdown period (~300 seconds). However, transient numerical solutions show a faster thermal mixing than that observed in the experiment after the initial coastdown period. A nearly homogenization of the temperature field in the upper plenum is predicted after about 900 seconds, which is a much shorter-term thermal stratification than the experimental data indicates. This discrepancy may be due to the shortcoming of the turbulence models available in the CFX-13 code for a natural convection flow with thermal stratification.

CeO2의 첨가량 변화에 따른 세리아 안정화 지르코니아 세라믹스의 기계적 특성 관찰 (Mechanical Properties Observation of Ce-TZP Ceramics by Quantity Change of CeO2)

  • 강종봉
    • 한국세라믹학회지
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    • 제47권5호
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    • pp.439-444
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    • 2010
  • The usual ceramic process of mixing and milling in state of oxide of $ZrO_2$ and $CeO_2$ was adopted in wet process to manufacture Ce-TZP in this study. The maximum dispersion point of every slurry manufactured with mixture of $ZrO_2$ and $CeO_2$ was neat at pH10. The stable slurry in average particle size of 90 nm can be manufactured when it is dispersed with use of ammonia water and polycarboxylic acid ammonium. The sintered Ce-TZP ceramics manufactured with addition of $CeO_2$ less than 10 mol% was progressed to the fracture of specimen due to the monoclinic phase existence more than 30% at the room temperature. More than 99% of tetragonal phase was created for the sintered body with addition of $CeO_2$ beyond 18 mol%, but the mechanical property degrade on the entire specimen was brought due to the $CeO_2$ existing above 3%. Consequently, the optimal Ce-TZP combined in oxide state was identified in 16 mol% of $CeO_2$ contents.

STUDY ON THE IN-CYLINDER FLOW CHARACTERISTICS OF AN SI ENGINE USING PIV

  • LEE S.-Y.;JEONG K.-S.;JEON C.-H.;CHANG Y.-J.
    • International Journal of Automotive Technology
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    • 제6권5호
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    • pp.453-460
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    • 2005
  • The tumble or swirl flow is used to promote mixing of air and fuel in the cylinder and to enlarge turbulent intensity in the end of the compression stroke. Since the in-cylinder flow is a kind of transient state with rapid flow variation, which is non-steady state flow, the tumble or swirl flow has not been analyzed sufficiently whether they are applicable to combustion theoretically. In the investigation of intake turbulent characteristics using PIV method, typical flow characteristics were figured out by SCV configurations. An engine installed SCV had higher vorticity and turbulent strength by fluctuation and turbulent kinetic energy than a baseline engine, especially near the cylinder wall and lower part of the cylinder. Above all, the engine with SCV 8 was superior to the others in aspect of vorticity and turbulent strength. For energy dissipation, a baseline engine had much higher energy loss than the engine installed SCV because flow impinged on the cylinder wall. Consequently, as swirl flow was added to existing tumble flow, it was found that fluctuation increased and flow energy was conserved effectively through the experiment.

Utilization of PTE and LDPE Plastic Waste and Building Material Waste as Bricks

  • Intan, Syarifah Keumala;Santosa, Sandra
    • 한국재료학회지
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    • 제29권10호
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    • pp.603-608
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    • 2019
  • Plastic waste is becoming a problem in various countries because of the difficulty of natural decomposition. One type is PET plastic(Polyethylene Terephthalate), which is often used as a bottle for soft drink packaging, and LDPE(Low Density Polyethylene), which is also widely used as a food or beverage packaging material. The use of these two types of plastic continuously, without good recycling, will have a negative impact on the environment. Building material waste is also becoming a serious environmental problem. This study aims to provide a solution to the problem of the above plastic waste and building material waste by making them into a mixture to be used as bricks. Research is carried out by mixing both materials, namely plastic heated at a temperature of $180-220^{\circ}C$ and building material waste that had been crushed and sized to 30-40 mesh with homogeneous stirring. The ratios of PET and LDPE plastic to building material waste are 9 : 1, 8 : 2, 7 : 3, 6 : 4 and 5 : 5. After heating and printing, density, water absorption and compressive strength tests are carried out. Addition of PET and LDPE plastic can increase compressive strength, and reduce water absorption, porosity and density. A maximum compressive strength of 10.5 MPa is obtained at the ratio of 6 : 4.

Estimation of Input Material Accounting Uncertainty With Double-Stage Homogenization in Pyroprocessing

  • Lee, Chaehun;Kim, Bong Young;Won, Byung-Hee;Seo, Hee;Park, Se-Hwan
    • 방사성폐기물학회지
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    • 제20권1호
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    • pp.23-32
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    • 2022
  • Pyroprocessing is a promising technology for managing spent nuclear fuel. The nuclear material accounting of feed material is a challenging issue in safeguarding pyroprocessing facilities. The input material in pyroprocessing is in a solid-state, unlike the solution state in an input accountability tank used in conventional wet-type reprocessing. To reduce the uncertainty of the input material accounting, a double-stage homogenization process is proposed in considering the process throughput, remote controllability, and remote maintenance of an engineering-scale pyroprocessing facility. This study tests two types of mixing equipment in the proposed double-stage homogenization process using surrogate materials. The expected heterogeneity and accounting uncertainty of Pu are calculated based on the surrogate test results. The heterogeneity of Pu was 0.584% obtained from Pressurized Water Reactor (PWR) spent fuel of 59 WGd/tU when the relative standard deviation of the mass ratio, tested from the surrogate powder, is 1%. The uncertainty of the Pu accounting can be lower than 1% when the uncertainty of the spent fuel mass charged into the first mixers is 2%, and the uncertainty of the first sampling mass is 5%.

Surface properties of Nb oxide thin films prepared by rf sputtering

  • 박주연;강용철
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.306.2-306.2
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    • 2016
  • Niobium oxide thin films were synthesized by reactive rf magnetron sputtering. The target was metallic niobium with 2 inch in diameter and the substrate was n-type Si wafer. To control the surface properties of the films, Nb oxide thin films were obtained at various mixing ratios of argon and oxygen gases. Nb oxide thin films were analyzed with alpha step, scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The result of alpha step showed that the thickness of Nb oxide thin films were decreased with increasing the oxygen gas ratios. SEM images showed that the granular morphology was formed at 0% of oxygen gas ratio and then disappeared at 20 and 75% of oxygen gas ratio. The amorphous Nb oxide was observed by XRD at all films. The oxidation state of Nb and O were studied with high resolution Ni 2p and O 1s XPS spectra. And the change in the chemical environment of Nb oxide thin films was investigated by XPS with Ar+ sputtering.

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해양 구조물의 철근부식 예측기법 개발에 관한 연구 (A Study on the Development of Corrosion Prediction System of Reinforcing Bars in Sea-shore Structure)

  • 박승범;김도겸
    • 콘크리트학회논문집
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    • 제11권6호
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    • pp.89-100
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    • 1999
  • Service life of concrete structures that are exposed to the environmental attack is largely influenced by the corrosion of reinforcing bare due to the chloride contamination. Chloride ions penetrate continuously into concrete from the environment, and chloride diffusion velocity is governed by a mechanical steady stage. In this study, a method is developed to predict corrosion initiation of reinforcing bars in the sea-shore structures, based on governing equations that take into account the diffusing of chloride ions and a mechanical steady state. As a result of this study, Corrosion Prediction System (CPS) is developed, and it can be used to determine an optimal time for repair and rehabilitation actions need to be taken. Futhermore, CPS assists the concrete mixing structures by predicting of chloride concentrations in concrete mixture, exposed to salt concentrations and service environment.

높이차가 존재하는 두 분류의 2상유동에 관한 연구 (Study on Two-Phase Flow generated by Two Jets with Height Difference)

  • 박상규;양희천;이용호
    • Journal of Advanced Marine Engineering and Technology
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    • 제24권1호
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    • pp.88-93
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    • 2000
  • In this study, the mixing process of two-phase flow generated by two jets with height difference is analyzed. The primary jet is jetted on the condition of the state mixed pulverized solid particles with air. The height difference between the main jet and the secondary jet is changed into three kinds(0, 32.5, 47.5mm). The velocity vector field, concentration field and turbulent properties of solid particles are measured by using 3-Dimensional Particles Dynamics Analyzer. As the height difference of two jets through the two nozzles increases, the solid particle recirculation zone and the dense zone in the combustion chamber become large. The solid particle concentration at the center of the combustion chamber gets dense because the particle velocity remains slow due to the existence of the solid particle recirculation zone. The particle concentration in the combustion chamber can also be influenced by the hight difference of two jets.

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혼합모드(I+II)에서 피로 하중에 의한 균열진전 거동 (Crack Growth Behavior by Fatigue Load under Mixed Mode(I+II))

  • 공병채;최성대
    • 한국생산제조학회지
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    • 제21권2호
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    • pp.276-282
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    • 2012
  • This study looked for Mode status of each for fatigue crack growth behavior about the repeat load of mode I and the static load of mode II. The experiment was performed in the state of the repetition frequency of the sine wave 10Hz, the stress ratio 0.1, maximum load 300kg.f, a static load 0, 100, 200, 300kg.f, As the experimental results, in mode of static load, while the load value increases, the crack growth rate is slower as the energy of a crack mixing grows. Mode I and the power mode II get an influence each other in the direction of crack propagation path, but as they eventually get closer to the breaking point of the crack growth, it is dominated by the mode I.