• Title/Summary/Keyword: mixing rules

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Prediction of partial molar volumes of solutes in supercritical CO2 using the Peng-Robinson equation of state with various mixing rules and Kirkwood-Buff solution theory (3차 상태방정식과 여러 혼합법칙 및 Kirkwood-Buff용액이론을 이용한 초임계유체내에서의 용질의 무한희석 부분몰부피의 계산)

  • Jeon, Young-Pyo;Park, Jong-Seon;Kwon, Yong-Jung
    • Journal of Industrial Technology
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    • v.19
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    • pp.253-260
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    • 1999
  • Two thermodynamic models were used to predict the partial molar volumes of solutes in supercritical carbon dioxide at infinite dilution: (1) the Peng-Robinson equation of state with various mixing rules including those based on $EOS/G^E$ (2) the Kirkwood Buff fluctuation integral with the hard sphere expansion (HSE) method. The Kirkwood-Buff fluctuation integral method, in which an equation of state for pure component and molecular parameters are required, produced better results especially near the critical point than the Peng-Robinson equation of state with the several mixing rules based an $EOS/G^E$. When the $EOS/G^E$ mixing rules were used, poorer results were obtained compared with the classical mixing rule and Kirkwood-Buff model.

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Vapor-Liquid Equilibria in Aqueous Polymer Solutions using a PRSV Equation of State (PRSV 상태방정식을 이용한 고분자 수용액 계의 기액 평형)

  • Leem, Young-Min;Kim, Mi-Kyung;Kim, Ki-Chang
    • Journal of Industrial Technology
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    • v.22 no.A
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    • pp.241-248
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    • 2002
  • In this work, we calculated the vapor-liquid equilibrium of aqueous polymer solutions by using PRSV equation of state combined with $G^{ex}$ mixing rules(HVO, MHVL, MHV2, LCVM). From the comparison of calculated results with experimental data obtained from literature, we found that calculation results by using MHV1 mixing rule have showed small range of error than HVO, MHV2 and LCVM mixing rules. Calculation results by using the combination of MHV1 mixing rule and UNIFAC-FV model have showed the best result for selected aqueous polymer solutions.

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Effects of Mixing Characteristics at Fracture Intersections on Network-Scale Solute Transport

  • 박영진;이강근
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.69-73
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    • 2000
  • We systematically analyze the influence of fracture junction, solute transfer characteristics on transport patterns in discrete, two-dimensional fracture network models. Regular lattices and random fracture networks with power-law length distributions are considered in conjunction with particle tracking methods. Solute transfer probabilities at fracture junctions are determined from analytical considerations and from simple complete mixing and streamline routing models. For regular fracture networks, mixing conditions at fracture junctions are always dominated by either complete mixing or streamline routing end member cases. Moreover bulk transport properties such as the spreading and the dilution of solute are highly sensitive to the mixing rule. However in power-law length networks there is no significant difference in bulk transport properties, as calculated by assuming either of the two extreme mixing rules. This apparent discrepancy between the effects of mixing properties at fracture junctions in regular and random fracture networks is explained by the statistics of the coordination number and of the flow conditions at fracture intersections. We suggest that the influence of mixing rules on bulk solute transport could be important in systematic orthogonal fracture networks but insignificant in random networks.

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Evaluation of Microwave Dielectric Properties of MgO-TiO2 System by Dielectric Mixing Rules

  • Kim, Eung-Soo;Seo, Seock-No
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.163-168
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    • 2010
  • Effects of compositions on the microwave dielectric properties of the MgO-$TiO_2$ system were investigated as a function of the molar ratio of MgO to $TiO_2$ ($0.9{\leq}MgO/TiO_2\;(x){\leq}1.2$). With the compositional changes, secondary phases of $MgTi_2O_5$ and $Mg_2TiO_4$ were also detected along with $MgTiO_3$. Microwave dielectric properties of the specimens were dependent on the types of phases developed in the sintered specimens. A single phase of $MgTiO_3$ showed a dielectric constant (K) of 18.2, a quality factor (Qf) of 198,000 GHz, and a temperature coefficient of resonant frequency (TCF) of $-51\;ppm/^{\circ}C$. However, the dielectric properties of the specimens with a secondary phase of $MgTi_2O_5$ (K=19.9, Qf=48,000 GHz) and/or $Mg_2TiO_4$ (K=15.6, Qf=56,000 GHz) were worsened. Dependence of the microwave dielectric properties on the secondary phase of the MgO-$TiO_2$ system was also discussed in terms of dielectric mixing rules.

Development of an Automatic Nutrient-Solution Supply System Using Fuzzy Control (퍼지제어를 이용한 양액 자동공급 시스템 개발)

  • 황호준;류관희;조성인;이규철;김기영
    • Journal of Biosystems Engineering
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    • v.23 no.4
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    • pp.365-372
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    • 1998
  • This study was carried out to develop a nutrient-solution mixing-and-supplying system, which used a low-cost metering device instead of expensive metering pumps and a fuzzy logic controller. A low cost and precise overflow-type metering device was developed and evaluated by testing the flow discharge for the automatic nutrient-solution mixing-and-supplying system for snail-scale hydroponic sewers. The fuzzy logic controllers, which could predict and meet the desired values of EC and supply rate of nutrient solution were developed and verified by simulation and experiment. this fuzzy logic controller, whose algorithm consists of four crisp inputs, two crisp outputs and nine rules, was developed to predict the desired value of EC and supply rate of nutrient solution and two crisp inputs, one crisp output and nine rules used to control EC to the desired values. The nutrient-solution mixing-and-supplying system showed satisfactory EC control performance with the maximum overshooting of 0.035 mS/cm and the maximum settling time of 15 minutes in case of increasing 0.7 mS/cm. also, the accuracy of the overflow-type metering device in terms of the full-scale error was 2.29% when using solenoid valve only and 0.2% when using solenoid valve and flow control valve together.

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A Study on the Scale-Up of Fluidized Bed Combustors for Low-Calorific Value Wastes (저발열량 폐기물 소각용 유동층 소각로의 Scale-Up에 관한 연구)

  • Park, S.H.;Kim, J.E.;Park, B.S.
    • Journal of the Korean Society of Combustion
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    • v.1 no.1
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    • pp.1-10
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    • 1996
  • An effective scale-up methodology of fluidized bed incinerators for low calorific value industrial wastes such as paper sludge and sewage sludge has been developed based on the similarity rules. Conventional scale-up theories are briefly reviewed and a new simple theory defining the diffusion Fourier number is established taking account of the lateral mixing of fuels in the fluidized bed. From the design and the operating conditions of the pilot FBC plant at Inchon, important design data for the full-scale incinerators are calculated and discussed.

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Refractive Index and Excess Volume for Diisopropylamine + Isomeric Butanol Mixtures in terms of Nakata and Sakurai model

  • Kumari, Kavitha;Maken, Sanjeev
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.644-651
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    • 2021
  • Alkyl amines are widely used in various industries. Nowadays these are also used in CO2 capture technology because amines react with CO2 and remove it from the flue gas. To make the amines more compatible towards this technology, physico chemical properties may be altered by mixing with other solvents. In the present report, we measured the refractive properties of pure diisopropylamine (DIPA) (1) + isomeric butanol (2) at 298.15 K to 308.15 K. The 𝚫n values were positive for DIPA + n-butanol or sec-butanol or isobutanol or tert-butanol mixtures. The measured data was correlated with Redlich-Kister equation. The excess molar volume data were predicted from refractive index data using Nakata and Sakurai model. The experimental data were also predicted by various correlations, and the prediction capability of these correlations was reported through standard deviation. Further, the deviation in refractive index (𝚫n) data was interpreted by the consideration of specific molecular interactions between DIPA and isomeric butanol.

Effects of Fracture Intersection Characteristics on Transport in Three-Dimensional Fracture Networks

  • Park, Young-Jin;Lee, Kang-Kun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.27-30
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    • 2001
  • Flow and transport at fracture intersections, and their effects on network scale transport, are investigated in three-dimensional random fracture networks. Fracture intersection mixing rules complete mixing and streamline routing are defined in terms of fluxes normal to the intersection line between two fractures. By analyzing flow statistics and particle transfer probabilities distributed along fracture intersections, it is shown that for various network structures with power law size distributions of fractures, the choice of intersection mixing rule makes comparatively little difference in the overall simulated solute migration patterns. The occurrence and effects of local flows around an intersection (local flow cells) are emphasized. Transport simulations at fracture intersections indicate that local flow circulations can arise from variability within the hydraulic head distribution along intersections, and from the internal no flow condition along fracture boundaries. These local flow cells act as an effective mechanism to enhance the nondiffusive breakthrough tailing often observed in discrete fracture networks. It is shown that such non-Fickian (anomalous) solute transport can be accounted for by considering only advective transport, in the framework of a continuous time random walk model. To clarify the effect of forest environmental changes (forest type difference and clearcut) on water storage capacity in soil and stream flow, watershed had been investigated.

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Total Ordering by Fuzzy Inference

  • Hyung, Lee-Kwang;Lee, Do-Heon;Lee, Keon-Myung
    • Journal of the Korean Institute of Intelligent Systems
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    • v.5 no.1
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    • pp.21-24
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    • 1995
  • Fuzzy inference method is introduced to order totally a partiallyordered system. When there there are more than one order indices and fuzzy order rules, the proposed method provides one order index by mixing them.

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A study on the rules and the principles of the six-drugs mixing forming the prescription of Yukmijihwanghuan(六味地黃丸) (육미지황환(六味地黃丸)의 제방원칙(制方原則) 및 배합원리(配合原理)에 관(關)한 연구(硏究))

  • Kim, Yoon-Hyeon;Yoon, Chang-Yeol
    • Journal of Korean Medical classics
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    • v.23 no.6
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    • pp.1-14
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    • 2010
  • The conclusions after studying the rules and the principles of the six-drugs mixing forming the prescription of Yukmijihwanghuan(六味地黃丸) are as follows: 1. Yukmijihwanghuan cares for the three viscera; the liver, the spleen and the kidney and the three entrails; the urinary bladder, the gall bladder, and the stomach and it strengthens them as well. The drug can be used mainly for the cure of the Three Yang Channels of Foot and the Three Yin Channels of Foot. 2. The three drugs of Yukmijihwanghuan; Rehmanniae Radix, Dioscoreae Rhizoma, Corni Fructus altogether has the tonifying effect and the other three; Alismatis Rhizoma, Moutan Cortex, Poria has the purging effect. The first three kinds of drugs tonifies and the last three kinds of drugs purges. While these two groups of drugs are pitted against each other, they also balance each other harmoniously increasing the curative effect(remedial[curative] value). 3. Yukmijihwanghuan cools off the lung which is under metal category, helps the spleen, an earth category to be strong. It also adds the Water Qi to the kidney so that it stabilizes the Fire Qi. 4. Yukmijihwanghuan helps the kidney strongly, helps the urine to be excreted well, cools down the Fire Qi and makes dry things wet. 5. Rehmanniae Radix, the principal drug of Yukmijihwanghuan and Corni Fructus, the minister drug of the medicine have a taste of thick and are materially heavy. The two drugs do the descending action that it tonifies Yin Qi and adds Essence of Life. The other ingredients of Yukmijihwanghuan; Moutan Cortex, Poria, Alismatis Rhizoma have effects on lowering the Fire Qi. If Fire Qi descends, then Water Qi ascends. Yukmijihwanghuan has an efficacy of lowering Fire Qi and increasing Water Qi.