• Title/Summary/Keyword: mixing mill

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Mechanical Alloying Effect in Immiscible Cu30Mo70 Powders (비고용 Cu30Mo70계 혼합분말의 기계적 합금화 효과)

  • 이충효;이성희;이상진;권영순
    • Journal of Powder Materials
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    • v.10 no.1
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    • pp.46-50
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    • 2003
  • Lee et al. reported that a mixture of Cu and Ta, the combination of which is characterized by a positive heat of mixing, $\{Delta}H_{mix}$ of +2 kJ/㏖, can be amorphized by mechanical alloying(MA). It is our aim to investigate to what extent the MA is capable of producing a non-equilibrium phase with increasing the heat of mixing. The system chosen is the binary $Cu_{30}Mo_{70}$ with $\{Delta}H_{mix}$=+19 kJ/㏖. The mechanical alloying was carried out using a Fritsch P-5 planetary mill under Ar gas atmosphere. The vial and balls are made of Cu containing 1.8-2.0 wt.%Be to avoid contaminations arising mainly from Fe when steel balls and vial are used. The MA powders were characterized by the X-ray diffraction, EXAFS and thermal analysis. We conclude that two phase mixture of nanocrystalline fcc-Cu and bcc-Mo with grain size of 10 nm is formed by the ball-milling for a 3:7 mixture of pure Cu and Mo, the evidence for which has been deduced from the thermodynamic and structural analysis based on the DSC, X-ray diffraction and EXAFS spectra.

A Study on the Strength and Fracture Toughness of High Strength Hardened Cement Paste (고강도 시멘트 경화체의 강도 및 파괴인성에 관한 연구)

  • 김정환
    • Magazine of the Korea Concrete Institute
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    • v.6 no.6
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    • pp.151-158
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    • 1994
  • In this work, in order to inrprove the flexural strength of hardened portlarid cerncrit paste, mix ing water was reduced to water ccrnent ratio of 0.1 aid water soluble polymer such as hydroxy propyl methyl cellulose was adclelri to the paste to obtain a better dispersion. The paste was kneaded by the twin roll mill for cornpact and homogeneous mixing. The high strength mechanism of the hardened cement paste may be due to the removal of macropores larger than 100${\mu}m$, the reduction of capillary pores acting as the passage of crack propagation, the increase of Young's moculus with iticrease of unhytlratcci cenxxnt ard the incicasc of fracture toughnevs with the crack toughening mechanism (grain bridging, polymer fibril bridging and fritional inter-locking).

Amorphous Ultrafine Particle Preparation for Improvement of Bioabailability of Insolube Drugs: Effect of Co-Grinding of UDCA with SLS (난용성 의약품의 생체이용률 증진을 위한 무정형 초미립자의 조제 : UDCA와 SLS의 혼합분쇄 효과)

  • 정한영;곽성신;김현일;최우식
    • YAKHAK HOEJI
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    • v.46 no.2
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    • pp.102-107
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    • 2002
  • The particle size of medicinal materials is an important physical property which affects the pharmaceutical behaviors such as dissolution, chemical stability, compressibility and bioavailability of solid dosage forms. The size reduction of raw pharmaceutical powder is needed to formulize insoluble drugs or slightly soluble drugs and to improve the pharmaceutical properties such as the solubility, the pharmaceutical mixing and the dispersion. The objective of the present study is to evaluate the grinding characteristics of ursodeoxycholic acid(UDCA) as a model of insoluble drugs. The effects of the grinding time and the amount of additive on particle size distribution of ground UDCA were investigated. Grinding of insoluble drug, UDCA and a series of dry co-grinding experiments of UDCA with sodium lauryl sulfate(SLS) as an additive were carried out using a planetary ball mill. It was measured that the median diameter and the particle size distribution of ground products with grinding UDCA and additive SLS by Mastersizer. As a result of co-grinding of UDCA and SLS, the particle size of co-grinding products was decreased more than single grinding one. However, it was observed that co-grinding products were reaggregated to larger particles after 120 min.

The research about properties of modified low heat slag cement (개질 처리된 저발열 슬래그시멘트 특성에 관한 연구)

  • Kim, Hong-Joo;Kim, Won-Ki;Kim, Hoon-Sang;Lee, Won-Jun;Shin, Jin-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.677-680
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    • 2008
  • The surface of particles was energetically modified by inter-grinding OPC and BFS in vibration mill for improvement of the early strength and low-heat evolution of concretes. BFS was pre-grinding in ball-mill to 2535(BS2) and 3245 $cm^2/g$(BS3), in blaine surface area. The inter-grinding time in vibration mill was changed from 10 minutes to 30 minutes. And Mixing ration of BFS to OPC was changed in 60, 70, 80%. After inter-grinding, the change of specific surface area, particle size distribution, hydration heat of cement and compressive strength of mortar were measured. As the result of comparison test with LHC, it was found that the mixture and inter-grinding time satisfying the value of over 100% of compressive strength for 7 days and under 170J/g of heat of hydration for 72 hours. and it was confirmed that the possibility of low heat slag cement utilizing blast furnace slag(BS2, BS3) with the low fineness in high volumes.

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Improvement of Cooling Technology through Atmosphere Gas Management

  • Renard, Michel;Dosogne, Edgar;Crutzen, Jean-Pierre;Raick, Jean-Marc;Ma, Jia Ji;Lv, Jun;Ma, Bing Zhi
    • Corrosion Science and Technology
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    • v.8 no.6
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    • pp.217-222
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    • 2009
  • The production of advanced high strength steels requires the improvement of cooling technology. The use of high cooling rates allows relatively low levels of expensive alloying additions to ensure sufficient hardenability. In classical annealing and hot-dip galvanizing lines a mixing station is used to provide atmosphere gas containing 3-5% hydrogen and 97-95% nitrogen in the various sections of the furnace, including the rapid cooling section. Heat exchange enhancement in this cooling section can be insured by the increased hydrogen concentration. Drever International developed a patented improvement of cooling technology based on the following features: pure hydrogen gas is injected only in the rapid cooling section whereas the different sections of the furnace are supplied with pure nitrogen gas; the control of flows through atmosphere gas management allows to get high hydrogen concentration in cooling section and low hydrogen content in the other furnace zones. This cooling technology development insures higher cooling rates without additional expensive hydrogen gas consumption and without the use of complex sealing equipments between zones. In addition reduction in electrical energy consumption is obtained. This atmosphere control development can be combined with geometrical design improvements in order to get optimised cooling technology providing high cooling rates as well as reduced strip vibration amplitudes. Extensive validation of theoretical research has been conducted on industrial lines. New lines as well as existing lines, with limited modifications, can be equipped with this new development. Up to now this technology has successfully been implemented on 6 existing and 7 new lines in Europe and Asia.

Changes of Physicochemical Properties of Paper Mill Sludge and Sewage Sludge Mixed with Various Ratios of a Bulking Agent During Composting (공극개선재의 혼합비율에 따른 제지·하수슬러지의 퇴비화과정중 이화학성 변화)

  • Yu, Young-Suk;Chang, Ki-Woon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.2
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    • pp.45-57
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    • 1998
  • The object of this experiment was to determine the optimum mixing ratio of paper mill sludge and sewage sludge with woodchips as a bulking agent. The bulking agent was mixed with the mixture of paper mill sludge and sewage sludge(2:1 by dried weight) at the rates of 0(W-0), 20(W-20), 33(W-33), and 50(W-50)% on volume basis, and then the mixtures were composted by forced aerated static pile. The changes of physicochemical properties of the mixtures were measured during the composting in order to evaluate the maturity of composts. The temperatures of W-30 and W-50 treatments increased rapidly as soon as the composting started, and reached $60^{\circ}C$ in the fifth day of composting. Reduction of hot water soluble C/N ratio of W-33 and W-50 treatments showed faster than that of W-0 and W-20 treatments at early stage of the composting. The contents of hot water soluble $NO_3{^-}-N$ showed little change in the early stage of the composting in all treatments, but increased rapidly after 20 days of the composting, and the contents of W-0 among all treatments were lower than the others. The G.I. values of W-50 treatment were over 80 before 20 days after starting the composting, those of W-0 treatment were over 80 after 30 days. As a result of evaluation of compost, W-33 and W-50 treatments were found very reasonable at the mixing ratio of a bulking agent. But it is very difficult to aerate compost pile for W-50 treatment than W-33 treatment due to intensified fluctuation of temperature. Considering cost, availability of a bulking agent, and productivity of compost, W-33 treatments more efficient than W-50 treatment.

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Development of the Optimal Composting Condition for the High Quality of Pig manure compost (고품질의 돈분 퇴비를 위한 합리적인 퇴비화 조건 개발)

  • Chang, Ki-Woon;Yu, Young-Seok;Min, Kyoung-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.4
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    • pp.112-117
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    • 2002
  • This study was conducted to induce the optimal composting conditions of pig manure mixed with sawdust and dried paper-mill sludge in the composting for production of high quality compost. Pig manure contains high water content and How C/N ratio because of comparatively high nitrogen content than sawdust and dried paper-mill sludge. Therefore the addition of dried paper-mill sludge and sawdust to the raw materials helps controlling the C/N and the water content of compost pile. The composting system used in the experiment was agitated static bed system. The physical properties of the mixed raw materials was not good at the working conditions in the early stage of composting. The temperature of compost heap reaches at $60^{\circ}C$within 5 day after starting composting in P-2 treatment mixed with pig manure and sawdust(56.6 : 43.4). Then the water content of P-2 was 58%. The pH in all treatments were slowly decreased as the composting was proceeded. Although the changes of T-C and T-N were not extended because of the short composting experiment period. Reduction rates of T-C in treatments were 5-12% without special difference. By considering the efficiency of composting in each of five treatments with pig manure the optimal water contents was about 57% level. Mixing a sawdust as a bulking agent was more positive than dried paper-mill sludge from a viewpoint of compost quality.

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Effects of PCC Loading at Thick Stock on the Paper Properties (고농도 지료에서의 PCC 충전이 종이 물성에 미치는 영향)

  • Won, Jong-Myoung;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.4
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    • pp.62-68
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    • 2012
  • This study was carried out to evaluate the effect of PCC loading at thick stock on the physical properties of paper. The effect of starch addition(2, 4 and 6%) and mixing time(5, 10 and 20 min.) on the filler retention and paper properties were investigated. Optimum dosage of cationic starch as a fixing agent was 4%, and mixing time did not showed any significant effect on the filler retention. PCC loading at thick stock was more effective to improve bulk and opacity than PCC loading at thin stock, although their improvement was not so significant. It was also found that the strength properties could be improved by the loading at thick stock. PCC loading method at thick stock could be considered as one of potential approaches for further improving of paper properties, although further research works are required in order to apply the PCC loading at thick stock in the paper mill.

Evaluation of Gelation Characteristics with The Variation of Additive Contents in The Alumina Slurry for Gel Casting Process (겔 캐스팅 공정을 위한 알루미나 슬러리에서의 첨가제 함량 변화에 따른 겔화특성 평가)

  • Chung, J.K.;Oh, C.Y.;Ha, T.K.
    • Transactions of Materials Processing
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    • v.31 no.5
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    • pp.290-295
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    • 2022
  • Recently, the use of high-tech ceramic parts in functional electronic parts, automobile parts and semiconductor equipment parts is increasing. These ceramics materials are required to have high reproducibility, reliability, large size and complex shapes. The researchers initiated the work to develop a new shaping method called gel casting, which allows high performance ceramic materials with a complex shape to be produced. The manufacturing process parameters of gel casting include uniform mixing of the initiator, bubble removal, and slip injection. In this study, we analyzed the dispersion and gelation characteristics according to the change in the additive content of the alumina slurry in the gel casting process. The alumina slurry for gel casting was prepared by mixing a solvent, a monomer and a dispersant through a ball mill. Alumina powder and a gelation initiator were added to the mixed solution, and ball milling was performed for 24 hours. A viscosity of 6,435 cps and a stable zeta potential value were obtained under the conditions of alumina powder content of 55 vol% and dispersant 2.0 wt%. After curing for 12 hours by adding aps 0.1wt%, TEMED 0.2wt%, and Monomer 3, 5wt%, it was possible to separate from the molding cup, confirming that the gelation was completed.

Changes of Physico-chemical Properties of paper Mill Sludge amended with Pig Manure in Composting Process (제지슬러지와 돈분을 이용한 퇴비화 과정중 이화학적 특성 변화)

  • Min, Kyoung-Hoon;Chang, Ki-Woon;Yu, Young-suk
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.4
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    • pp.86-92
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    • 2000
  • This study was conducted to determine the optimal mixing ratio of the paper mill sludge(PMS) and pig manure(PM). Since the former contains lots of total carbon and low nitrogen, it was used as carbon source. Also, dried paper mill sludge(DPMS) was added to the mixture to control the water content. The treatments was composed of four as follows, PMS-100(PM 0%+PMS 80%+DPMS 20%), PMS-85(15+65+20), PMS-70(30+50+20), and PMS-55(45+35+20). The mixtures were composted under aerobic condition in $1.25m^3$ static piles. The piles were aerated for 15 minutes per day and turned over the mixture once a week at the early stage of composting. To estimate the maturity of composts, the changes of physico-chemical properties such as temperature, pH, C/N ratio and color were monitored every week. The 25-30 and 55-60% as optimal condition of C/N ratio and moisture content were respectively recommended for effective composting by the evaluation of the changes of phsico-chemical properties for materials taken from compost files during the composting period. When the 30 and 45% of PM were mixed with PMS, the maturity time at least demanded to the stable state were shortened and the qualify of the final product was improved in a view of nutritional components.

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