• Journal of the Korean Wood Science and Technology
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• 제27권4호
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• pp.57-64
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• 1999

This research was carried out to investigate the effects of density, resin and particle types on the physical and mechanical properties of the composites made from various wood particles mixed with coating paper. The experiment was designed to apply with three particles (flake, chip, and fiber) and three resin types (urea, phenol and PMDI resin). The mixed ratio of coating paper to wood particle was fixed on 50 to 50% in each board making. And also it was designed to apply for four density levels (0.6, 0.7, 0.8 and 0.9 g/$cm^3$) and four mixed formulations of coating paper to wood particle (10:90, 20:80, 30:70, and 40:60 %) to analyze clearly the effects of PMDI resin. Coating paper-wood particle composites have acceptable bending strength (MOR, MOE) though the mixed ratio of coating paper was increased, but have low internal bond strength and poor dimensional stability (WA, TS, LE). Composites with high density had higher mechanical properties but showed lower physical properties than composites with low density. In conclusion, at least up to 20% mixed ratios, coating paper-wood particle composites have acceptable physical and mechanical properties, and PMDI resin has possibility for coating paper-wood particle composite manufacture.

• 한국환경과학회지
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• 제18권6호
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• pp.595-601
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• 2009

The effects of the cation-to-anion resin ratio and bed depth on ion exchange performance of mixed-bed were studied at ultralow solution concentration. Breakthrough curves were experimentally obtained for NaCI solution as functions of resin ratio and bed depth. The bed depth affects the pattern of the sodium breakthrough curve but not the chloride breakthrough curve in beds because of the selectivity difference. Resin selectivity determines the shape of breakthrough curves, Some sodium and chloride breakthrough curves crossed at a point as a function of resin ratio. The lower cation-to-anion resin ratio showed the higher effluent concentration or treated volume of the crossover point regardless of the total resin weight.

• 한국환경과학회지
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• 제16권8호
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• pp.907-912
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• 2007

Ion exchange resin was used to remove silica ion at ultralow concentration. The effects of temperature, type of ion exchange resin and single/mixed-resin systems on removal efficiency were estimated. As temperature increased, the slope of concentration profile became stiff, and the equilibrium concentration was higher. In the single resin system, the removal of silica was continued up to 400 min, but the silica concentration was recovered to initial concentration after 400 min due to the effect of dissolved $CO_2$. In the mixed-resin system it took about 600 min to reach equilibrium. Because of faster cation exchange reaction than anion exchange reaction, the effect of $CO_2$ could be removed. Based on the experimental results carried out in the mixed-resin system, the selectivity coefficients of silica ion for each ion exchange resin were calculated at some specific temperatures. The temperature dependency of the selectivity coefficient was expressed by the equation of Kraus-Raridon type.

• Journal of the Korean Wood Science and Technology
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• 제42권4호
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• pp.420-427
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• 2014

제재과정에서 발생되는 톱밥과 농업부산물인 왕겨의 활용방안을 찾고자 왕겨의 혼합비율에 따라 혼합보드를 제조하고 수지함침 및 탄화과정을 거쳐 혼합세라믹을 제조하여 왕겨의 혼합비율에 따라 물성을 조사하였다. 같은 수지함침율에서 왕겨혼합비율이 증가함에 따라 탄화 후 밀도 및 휨강도는 증가하였으나 중량감소율은 감소하였다. 또한 같은 탄화온도에서 밀도와 휨강도는 왕겨혼합비율이 40%일 때 가장 큰 것으로 나타났다.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2005년도 Proceedings of The 6th korea-china joint workshop on nuclear waste management
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• pp.165-175
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• 2005

Measurement of spent resin activity was initiated in 2004 in order to develop the C-14 removal technology for safe disposal. As part of this program, spent resins were sampled and measured in the in-station resin storage tank 2 at Wolsong Nuclear Power Plant Unit 1. At the time of sampling, the resins had been in storage tank from 3 to 23 years. Total 72 resin samples were sampled, which were collected from both man-hole (68 samples) and test-hole (4 samples) in the in-station resin storage tank 2. They were separated into liquid, activated carbon, zeolite, and spent resin. The spent resins were oxidized with sample oxidizer and analyzed for C-14. Ten of collected mixed resin samples were separated by density into cation and anion resins using a sugar solution. The C-14 concentration in anion exchange resin was approximately 2 times higher than in the mixed resin. The average concentration of C-14 in the cation/anion mixed exchange resin was $460\;GBq/m^3$ from test-hole and $53.1\;GBq/m^3$ from man-hole. We have found that concentration of C-14 in the spent resin is about from 0.4 to $1,321\;GBq/m^3$. So it could be a problem, when dispose of at a repository, since there is a disposal limit of $222\;GBq/m^3$. This means we should develop the C-14 removal technology.

• Nuclear Engineering and Technology
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• 제55권10호
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• pp.3665-3676
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• 2023

The use of ion exchange resins to remove ionic impurities from solution is prevalent in industrial process systems, including in the primary heat transport system (PHTS) purification circuit of nuclear power plants. Despite its extensive use in the nuclear industry, our general understanding of ion exchange cannot fully explain the complex chemistry in ion exchange beds, particularly when operated at or near their saturation limit. This work investigates the behaviour of mixed-bed ion exchange resin, saturated with species representative of corrosion products in a CANDU (Canadian Deuterium Uranium) reactor PHTS, particularly with respect to iron chemistry in the resin bed and the removal of lithium ions from solution. Experiments were performed under deaerated conditions, analogous to normal PHTS operation. The results show interesting iron chemistry, suggesting the hydrolysis of cation resin bound ferrous species and the subsequent formation of either a solid hydrolysis product or the soluble, anionic Fe(OH)₃^-.

• Composites Research
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• 제24권2호
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• pp.30-37
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• 2011

에폭시 수지와 유리섬유직물 간의 젖음성을 분석하였다. 에폭시 수지와 산무수물 경화제의 혼합비는 당량비 1:0.5, 1:1, 1:1.2로 하였고, 촉매는 혼합된 수지의 0.lwt%로 첨가하였다. DSC 경화거동분석 결과 이 혼합 수지는 상온에서 함침이 가능하였다. 혼합 수지에 대해 유리평판에 놓여진 유리섬유직물 위에 수지 한 액적(방울)을 투하 후 시간에 따른 접촉각 변화를 측정하였다, 또한, 일정량의 에폭시 수지 액적을 투하시켜 시간에 따른 젖음면적 변화를 측정하였다, 접촉각, 액적높이, 순수 젖음면적, 젖음계수를 측정함으로써 유리섬유직물에 대한 에폭시 수지의 젖음성을 비교 평가하였다. 그 결과 당량비 1:1.2에서 유리섬유직물에 대한 젖음성이 가장 우수하였다.

• Journal of the Korean Wood Science and Technology
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• 제42권5호
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• pp.605-614
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• 2014

This study investigated microstructural changes of cured urea-formaldehyde (UF) resins mixed with aqueous rubber latex emulsion after intentional acid etching. Transmission electron microscopy (TEM) was used in order to better understand a hydrolytic degradation process of cured UF resins responsible for the formaldehyde emission from wood-based composite panels. A liquid UF resin with a formaldehyde to urea (F/U) molar ratio 1.0 was mixed with a rubber latex emulsion at three different mixing mass ratios (UF resin to latex = 30:70, 50:50, and 70:30). The rate of curing of the liquid modified UF resins decreased with an increase of the rubber latex proportion as determined by differential scanning calorimetry (DSC) measurement. Ultrathin sections of modified and cured UF resin films were exposed to hydrochloric acid etching in order to mimic a certain hydrolytic degradation. TEM observation showed spherical particles and various cavities in the cured UF resins after the acid etching, indicating that the acid etching had hydrolytically degraded some part of the cured UF resin by acid hydrolysis, also showing spherical particles of cured UF resin dispersed in the latex matrix. These results suggested that spherical structures of cured UF resin might play an important role in hindering the hydrolysis degradation of cured UF resin.

• 자원리싸이클링
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• 제13권3호
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• pp.43-49
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• 2004

플라스틱 재료는 재생이 가능한 열가소성 플라스틱과 재생이 거의 불가능한 열경화성 플라스틱으로 분류 할 수 있고, 본 연구에서는 재생이 가능한 열가소성 플라스틱 중 산업 및 생활 전반에 널리 사용되고 있는 PP. PA6, PC 및 PBT 재료의 재생 방안에 대한 기초 연구로서 재생 재료의 혼합비가 증가함에 따라 치수 정밀도에 미치는 영향을 고찰하였다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2004년도 추계학술발표대회 논문집
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• pp.96-99
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• 2004

Silica fillers were coated by plasma polymer coatings of 1,3-diaminopropane, allylamine, pyrrole, 1,2-epoxy-5-hexene, allyl mercaptan and allyl alcohol using RF plasma (13.56 MHz). The coated fillers were then mixed with biphenyl epoxy, phenol novolac (curing agent) and/or triphenylphosphine (catalyst), and subjected to DSC analyses in order to elucidate the chemical reaction between functional moieties in the plasma polymer coatings and the epoxy resin. Only the samples with 1,3-diaminopropane and allylamine plasma polymer coated silica fillers showed heat of reaction peaks when they were mixed with biphenyl epoxy resin only, while these samples as well as the samples with 1,3-diaminopropane, allylamine and pyrrole plasma polymer coated silica fillers exhibited heat of reaction peaks when mixed with both biphenyl epoxy and phenol novolac (curing agent).