• Title/Summary/Keyword: mixed resin

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Effects of Density, Resin and Particle Types on Properties of Composites from Wood Particle Mixed with Coating Paper

  • Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.4
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    • pp.57-64
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    • 1999
  • This research was carried out to investigate the effects of density, resin and particle types on the physical and mechanical properties of the composites made from various wood particles mixed with coating paper. The experiment was designed to apply with three particles (flake, chip, and fiber) and three resin types (urea, phenol and PMDI resin). The mixed ratio of coating paper to wood particle was fixed on 50 to 50% in each board making. And also it was designed to apply for four density levels (0.6, 0.7, 0.8 and 0.9 g/$cm^3$) and four mixed formulations of coating paper to wood particle (10:90, 20:80, 30:70, and 40:60 %) to analyze clearly the effects of PMDI resin. Coating paper-wood particle composites have acceptable bending strength (MOR, MOE) though the mixed ratio of coating paper was increased, but have low internal bond strength and poor dimensional stability (WA, TS, LE). Composites with high density had higher mechanical properties but showed lower physical properties than composites with low density. In conclusion, at least up to 20% mixed ratios, coating paper-wood particle composites have acceptable physical and mechanical properties, and PMDI resin has possibility for coating paper-wood particle composite manufacture.

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The Effects of Resin Ratio and Bed Depth on the Performance of Mixed-bed Ion Exchange at Ultralow Solution

  • Yoon, Tae-Kyung;Lee, Gang-Choon;Noh, Byeong-Il
    • Journal of Environmental Science International
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    • v.18 no.6
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    • pp.595-601
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    • 2009
  • The effects of the cation-to-anion resin ratio and bed depth on ion exchange performance of mixed-bed were studied at ultralow solution concentration. Breakthrough curves were experimentally obtained for NaCI solution as functions of resin ratio and bed depth. The bed depth affects the pattern of the sodium breakthrough curve but not the chloride breakthrough curve in beds because of the selectivity difference. Resin selectivity determines the shape of breakthrough curves, Some sodium and chloride breakthrough curves crossed at a point as a function of resin ratio. The lower cation-to-anion resin ratio showed the higher effluent concentration or treated volume of the crossover point regardless of the total resin weight.

Equilibrium Property of Ion Exchange Resin for Silica Removal at Ultralow Concentration (초저이온농도에서 이온교환수지에 의한 실리카제거 평형특성)

  • Yoon, Tae-Kyung;Lee, Gang-Choon;Noh, Byeong-Il
    • Journal of Environmental Science International
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    • v.16 no.8
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    • pp.907-912
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    • 2007
  • Ion exchange resin was used to remove silica ion at ultralow concentration. The effects of temperature, type of ion exchange resin and single/mixed-resin systems on removal efficiency were estimated. As temperature increased, the slope of concentration profile became stiff, and the equilibrium concentration was higher. In the single resin system, the removal of silica was continued up to 400 min, but the silica concentration was recovered to initial concentration after 400 min due to the effect of dissolved $CO_2$. In the mixed-resin system it took about 600 min to reach equilibrium. Because of faster cation exchange reaction than anion exchange reaction, the effect of $CO_2$ could be removed. Based on the experimental results carried out in the mixed-resin system, the selectivity coefficients of silica ion for each ion exchange resin were calculated at some specific temperatures. The temperature dependency of the selectivity coefficient was expressed by the equation of Kraus-Raridon type.

Properties of Sawdust-Rice Husk Mixed Ceramic According to The Rice Husk Mixing Ratios (왕겨의 혼합비율에 따른 톱밥⋅왕겨 혼합세라믹의 성질)

  • Oh, Seung Won
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.420-427
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    • 2014
  • The physical and mechanical properties of sawdust-rice husk mixed ceramic were investigated with rice husk mixing ratios. The mixed ceramic board was produced with carbonization and resin impregnated sawdust-rice husk board at high temperature. At the same percentage of resin impregnation condition, density and bending strength of the mixed ceramic board increased with increasing the mixing rates of rice husk, whereas weight loss of the ceramic boards decreased. At the same temperature condition for the carbonization of resin impregnated sawdust-rice husk board, the density and bending strength were the highest with 40% of rice husk mixing ratio.

Measurement of Carbon-14 Activity in Spent Ion-exchange Resin of Wolsong Nuclear Power Plant

  • Kim Kyoung-Doek;Choi Young-Ku;Kang Ki-Du;Yang Ho-Yeon
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.165-175
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    • 2005
  • Measurement of spent resin activity was initiated in 2004 in order to develop the C-14 removal technology for safe disposal. As part of this program, spent resins were sampled and measured in the in-station resin storage tank 2 at Wolsong Nuclear Power Plant Unit 1. At the time of sampling, the resins had been in storage tank from 3 to 23 years. Total 72 resin samples were sampled, which were collected from both man-hole (68 samples) and test-hole (4 samples) in the in-station resin storage tank 2. They were separated into liquid, activated carbon, zeolite, and spent resin. The spent resins were oxidized with sample oxidizer and analyzed for C-14. Ten of collected mixed resin samples were separated by density into cation and anion resins using a sugar solution. The C-14 concentration in anion exchange resin was approximately 2 times higher than in the mixed resin. The average concentration of C-14 in the cation/anion mixed exchange resin was $460\;GBq/m^3$ from test-hole and $53.1\;GBq/m^3$ from man-hole. We have found that concentration of C-14 in the spent resin is about from 0.4 to $1,321\;GBq/m^3$. So it could be a problem, when dispose of at a repository, since there is a disposal limit of $222\;GBq/m^3$. This means we should develop the C-14 removal technology.

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Iron hydrolysis and lithium uptake on mixed-bed ion exchange resin at alkaline pH

  • Olga Y. Palazhchenko;Jane P. Ferguson;William G. Cook
    • Nuclear Engineering and Technology
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    • v.55 no.10
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    • pp.3665-3676
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    • 2023
  • The use of ion exchange resins to remove ionic impurities from solution is prevalent in industrial process systems, including in the primary heat transport system (PHTS) purification circuit of nuclear power plants. Despite its extensive use in the nuclear industry, our general understanding of ion exchange cannot fully explain the complex chemistry in ion exchange beds, particularly when operated at or near their saturation limit. This work investigates the behaviour of mixed-bed ion exchange resin, saturated with species representative of corrosion products in a CANDU (Canadian Deuterium Uranium) reactor PHTS, particularly with respect to iron chemistry in the resin bed and the removal of lithium ions from solution. Experiments were performed under deaerated conditions, analogous to normal PHTS operation. The results show interesting iron chemistry, suggesting the hydrolysis of cation resin bound ferrous species and the subsequent formation of either a solid hydrolysis product or the soluble, anionic Fe(OH)3-.

Wettability Evaluation of Resin on the Glass Fabric (유리섬유직물에 대한 수지의 젖음성 평가)

  • Han, Seung-Wook;Choi, Nak-Sam;Lee, Min-Soo;Ahn, Hung-Kun
    • Composites Research
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    • v.24 no.2
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    • pp.30-37
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    • 2011
  • Analysis of wettability between epoxy resin and glass fabric was studied. The mixing ratios of epoxy resin and anhydride hardener were varied as 1:0.5, l:l and l:1.2. Catalyst content was fixed as 0.1wt% of the mixed resin. A curing analysis by differential scanning calorimeter(DSC) showed a possible impregnation of the mixed resin at the room temperature. An effective contact angle of the mixed epoxy resin drop onto the glass fabric being preset on a flat glass plate was measured as a function of time. The wet area of the epoxy resin drop was also measured. Behaviors of the contact angle, the droplet height, the neat wet area and the coefficient of wettability were used to evaluate the wettability of the epoxy resin onto the glass fabric. It was concluded that the equivalent ratio of 1: 1.2 was the most suitable for the wettability.

Microstructure of Cured Urea-Formaldehyde Resins Modified by Rubber Latex Emulsion after Hydrolytic Degradation

  • Nuryawan, Arif;Park, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.5
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    • pp.605-614
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    • 2014
  • This study investigated microstructural changes of cured urea-formaldehyde (UF) resins mixed with aqueous rubber latex emulsion after intentional acid etching. Transmission electron microscopy (TEM) was used in order to better understand a hydrolytic degradation process of cured UF resins responsible for the formaldehyde emission from wood-based composite panels. A liquid UF resin with a formaldehyde to urea (F/U) molar ratio 1.0 was mixed with a rubber latex emulsion at three different mixing mass ratios (UF resin to latex = 30:70, 50:50, and 70:30). The rate of curing of the liquid modified UF resins decreased with an increase of the rubber latex proportion as determined by differential scanning calorimetry (DSC) measurement. Ultrathin sections of modified and cured UF resin films were exposed to hydrochloric acid etching in order to mimic a certain hydrolytic degradation. TEM observation showed spherical particles and various cavities in the cured UF resins after the acid etching, indicating that the acid etching had hydrolytically degraded some part of the cured UF resin by acid hydrolysis, also showing spherical particles of cured UF resin dispersed in the latex matrix. These results suggested that spherical structures of cured UF resin might play an important role in hindering the hydrolysis degradation of cured UF resin.

The Effect on Mixed Ratio of Recycled Engineering plastic Resin on the Shrinkage in Molded Parts (엔지니어링 플라스틱 재료의 재활용 혼합비가 성형품 수축에 미치는 영향)

    • Resources Recycling
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    • v.13 no.3
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    • pp.43-49
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    • 2004
  • In this study. an experimental work was performed to mold tensile specimens by using the injection molding machine. Melt temperature, mold temperature and the mixed ratio of recycled resin were selected as processing parameters for studying the effect of those conditions on the shrinkage and weight of molded parts. As a result, the shrinkage was increased with the higher mold and melt temperature and it was more sensitive to the change of mold temperature. On the other hand, the weight of molded parts was decreased with the increment of mold and melt temperature.

Study of Heat of Reaction Between Plasma Polymer Coated Silica Fillers and Biphenyl Epoxy Resin (플라즈마 코팅된 실리카와 에폭시 수지간의 반응성 연구)

  • Kim N. I.;Kang H. M.;Yoon T. H.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.96-99
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    • 2004
  • Silica fillers were coated by plasma polymer coatings of 1,3-diaminopropane, allylamine, pyrrole, 1,2-epoxy-5-hexene, allyl mercaptan and allyl alcohol using RF plasma (13.56 MHz). The coated fillers were then mixed with biphenyl epoxy, phenol novolac (curing agent) and/or triphenylphosphine (catalyst), and subjected to DSC analyses in order to elucidate the chemical reaction between functional moieties in the plasma polymer coatings and the epoxy resin. Only the samples with 1,3-diaminopropane and allylamine plasma polymer coated silica fillers showed heat of reaction peaks when they were mixed with biphenyl epoxy resin only, while these samples as well as the samples with 1,3-diaminopropane, allylamine and pyrrole plasma polymer coated silica fillers exhibited heat of reaction peaks when mixed with both biphenyl epoxy and phenol novolac (curing agent).

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