• Title/Summary/Keyword: mixed potential

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Effects of HLB value on oil-in-water emulsions: Droplet size, rheological behavior, zeta-potential, and creaming index

  • Hong, In Kwon;Kim, Su In;Lee, Seung Bum
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.123-131
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    • 2018
  • Using mixed nonionic surfactants Span/Tween, we investigated the effects of HLB value on the O/W emulsion stability and rheological behaviors. In this study, MS-01 (Span 60 & Tween 60) and MS-02 (Span 80 & Tween 80) was used as mixed nonionic surfactants. We considered required HLB value 10.85 and selected corresponding HLB value range 8-13. The droplet size distributions, droplet morphology, rheological properties, zeta-potential and creaming index of the emulsion samples were obtained to understand the mechanism and interaction of droplets in O/W emulsion. The results indicated that optimal HLB number for O/W emulsions was 10.8 and 10.7, while using MS-01 surfactant and MS-02 surfactant respectively. MS-01 (HLB = 10.8) sample and MS-02 (HLB = 10.7) sample showed smallest droplet size and highest zeta-potential value. Rheological properties are measured to understand rheological behaviors of emulsion samples. All emulsion samples showed no phase separation until 30 days storage time at $25^{\circ}C$.

A Study on the Refrigerant Characteristics of the HFC-l52a, and Azeotrope Mixed with $CF_3$I in Air Conditioners (에어컨용 냉매 HFC-152a와 HFC-152a에 $CF_3$I를 혼합한 공비혼합냉매 특성에 관한 연구)

  • 이종인;하옥남;홍경한;권일욱;박찬수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.4
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    • pp.332-340
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    • 2002
  • In these days, environmental concerns have been increased throughout the industry and community worldwide. To prevent the ozone depletion, ozone depletion potential of a refrigerant must be zero. Simultaneously, a refrigerant with low GWP (global warming potential) is very demanding to induce green house effect. Chlorine-free HFC-l34a is a refrigerant widely used for automotive air-conditioning system because its destruction potential is ecologically zero. Although HFC-l34a has no ozone depletion potential, its global warming potential is so high that it is not considered as a perfect alternative refrigerant that is acceptable for long-term use. In this paper, experimental measurement has been carried out to analyze the performance characteristics of automotive air-conditioning system using HFC-152a, which has low GWP and zero ODP. Also mixed refrigerant that is composed of HFC-152a and $CF_3$ was applied to investigate an alternative possibility for the automotive airconditioning system. As a result of this study, we could draw following conclusions; With respect to the variation of the rotational speed of compressor, outside air temperature and flow rate, the heat amount of evaporator and compressor and performance coefficient was varied.

Performance characteristics of a single-cylinder power tiller engine with biodiesel produced from mixed waste cooking oil

  • Choi, Hwon;Woo, Duk Gam;Kim, Tae Han
    • Korean Journal of Agricultural Science
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    • v.47 no.1
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    • pp.29-41
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    • 2020
  • Biodiesel is a clean energy resource that can replace diesel as fuel, which can be used without any structural changes to the engine. Vegetable oil accounts for 95 percent of the raw materials used to produce biodiesel. Thus, many problems can arise, such as rising prices of food resources and an imbalance between supply and demand. Most of the previous studies using waste cooking oil used waste cooking oil from a single material. However, the waste cooking oil that is actually collected is a mixture of various types of waste cooking oil. Therefore, in this study, biodiesel produced with mixed waste cooking oil was supplied to an agricultural single-cylinder diesel engine to assess its potential as an alternative fuel. Based on the results, the brake specific fuel consumption (BSFC) increased compared to diesel, and the axis power decreased to between 70 and 99% compared to the diesel. For emissions, NOx and CO2 were increased, but CO and HC were decreased by up to 1 to 7% and 16 to 48%, respectively, compared to diesel. The emission characteristics of the mixed waste cooking oil biodiesel used in this study were shown to be similar to those of conventional vegetable biodiesel, confirming its potential as a fuel for mixed waste cooking oil biodiesel.

One-Dimensional Model for Simulations of Atmospheric Mixed Layer : Application to Dukyang Bay Area (대기혼합층 모사를 위한 1차원 수치모형 : 득량만에서의 적용)

  • Kim, Yoo-Keun;Moon, Sung-Euii;Ahn, Joong-Bae
    • Journal of Environmental Science International
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    • v.6 no.5
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    • pp.425-435
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    • 1997
  • One-dimensional thermodynamic mixed layer model to stimulate variations of meteorological variables wish the planetary boundary layer has been developed In this study. This model consists of 2 prognostic equations, which can predict the variations of potential temperature and mixing ratio and several diagnostic equations. Physics within the surface and mixed layers has been considered seperately in the model. For the variations of the model, Its result has been analysed and compared with observated data over Ole Dukyang Bay for one day, July 23, 1992. The simulated height of mixed layer is comparable to the observation and the variations of temperature and mixing ratio in the mixed layer are also reasonably simulated. Those Imply that the model responds appropriately with given boundary conditions In sprite of Its simplilfied assumptions applied to the model and insufficient boundary and Initial conditions.

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Mass Loss Rates and Nutrient Dynamics of Oak and Mixed-Hardwood Leaf Litters in a Gyebangsan (Mt,) Forest Ecosystem

  • Kim, Choonsig
    • The Korean Journal of Ecology
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    • v.26 no.6
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    • pp.335-340
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    • 2003
  • Patterns of mass loss and nutrient release from decomposing oak (Quercus mongolica) and mixed litters (Q. mongolica, Betula schmidtii, Acer pseudo-sieboldianum, Kalopanx pictus and Tilia amurensis) in a natural hardwood forest in Gyebangsan (Mt.) were examined using litterbags placed on the forest floor for 869 days. Mass loss rates from decomposing litter were consistently higher in mixed litter (59%) than in oak litter types (52%) during the study period. Nutrient concentrations such as nitrogen (N), phosphorus (P), potassium (K), and magnesium (Mg) from decomposing litter were also higher in mixed litter than in oak litter types. Nutrient concentrations (N, P, Ca, and Mg) increased compared with initial concentration of litter, while K concentrations dropped rapidly at the first 5 months and then stabilized. The results suggest that mas loss and nutrient release obtained from decomposing litter of single species in mixed hardwood forest ecosystem should be applied with caution because of the potential differences of mass loss and nutrient release between single litter and mixed litter types.

A MIXED INTEGRAL EQUATION IN THE QUASI-STATIC DISPLACEMENT PROBLEM

  • Badr, Abdallah A.
    • Journal of applied mathematics & informatics
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    • v.7 no.2
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    • pp.575-583
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    • 2000
  • In this work, we solve the Fredholm-Volterra integral equation(FVIE) when the kernel takes a potential function form under given conditions. we represent this kernel in the Weber-sonin integral form.

Evaluation on Steel Bar Corrosion Embedded in Antiwashout Underwater Concrete

  • Moon Han-Young;Shin Kook-Jae
    • Journal of the Korea Concrete Institute
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    • v.17 no.2 s.86
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    • pp.303-309
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    • 2005
  • This study aims the evaluation of the corrosion of steel bar embedded in antiwashout underwater concrete, which has rather been neglected to date. To that goal, accelerated steel bar corrosion tests have been performed on three series of steel bar-reinforced antiwashout underwater concrete specimens manufactured with different admixtures. The three series of antiwashout underwater concrete were: concrete constituted exclusively with ordinary portland cement (OPC), concrete composed of ordinary portland cement mixed with fly-ash in $20\%$ ratio (FA20), and concrete with ground granulated blast furnace slag mixed in $50\%$ ratio (BFS50). The environment of manufacture was in artificial seawater. Measurement results using half-cell potential surveyor showed that, among all the specimens, steel bar in OPC was the first one that exceeded the threshold value proposed by ASTM C 876 with a potential value below -350mv after 14 cycles. And, the corresponding corrosion current density and concentration of water soluble chloride were measured as $30{\mu}A/mm^2$ and $0.258\%$. On the other hand, for the other specimens that are FA20 and BFS50, potential values below -350mV were observed later at 18 and 20 cycles, respectively. Results confirmed the hypothesis that mineral admixtures may be more effective on delay the development of steel bar corrosion in antiwashout underwater concrete.

부탄 이용 미생물에 의한 MTBE(Methyl tert-Butyl Ether) 분해 특성

  • 장순용;백승식;이시진
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.136-139
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    • 2001
  • In this study, we have examined potential degradation of MTBE (methy1 tert-butyl ether) by pure culture ENV425 and mixed culture isolated from gasoline contaminated soil using n-butane as the sources of carbon and energy. The results described in this study suggest that MTBE is degraded cometabolically by ENV425 and mixed culture grown n-butane, and the disappearance of TBA after complete degradation of MTBE suggest the further degradation of TBA. Butane and MTBE degradation was completely inhibited by acetylene, which indicated that both substrates were degraded by butane-utilizing bacteria. MTBE was degraded ENV425 and mixed culture grown n-butane, and TBA (tert-butyl alcohol) was produced as product of MTBE oxidation. TBA production was accounted 54.7% and 58.6% for MTBE oxidation by ENV425 and mixed culture, respectively. The observed maximal transformation yield (T$_{y}$) were 44.7 and 34.0 (nmol MTRE degraded/$\mu$mol n-butane Utilized) by ENV425 and mixed culture, respectively.y.

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A Study on the Stabilization of Asphalt Emulsion with Phase Inversion Emulsification Method (반전유화법에 의한 유화아스팔트의 안정성 연구)

  • Heo, Woo-Sung;Lee, Eun-Kyoung;Choi, Sei-Young
    • Elastomers and Composites
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    • v.44 no.2
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    • pp.143-149
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    • 2009
  • In this study, asphalt emulsion was manufactured by phase inversion emulsification method with nonionic surfactants(Span 80, Span 60, Tween 80, and Tween 60), anionic surfactant(SLS) and cationic surfactant(Imidazole) in different feeding ratio to make up for the week points of asphalt. Its stabilization was carefully investigated with respect to droplet size, viscosity, zeta potential, and water-proofing property. When the surfactants mixed with nonionic and anionic surfactant were used into the asphalt, a stabilization of the asphalt emulsion was good. As the amount of the mixed surfactant was increased, the droplet size of asphalt emulsion were decreased, while the viscosity and zeta potential were increased. When the surfactants mixed with nonionic and anionic surfactant were used into the asphalt, a stabilization of asphalt emulsion was good.