• Journal of Welding and Joining
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• 제19권5호
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• pp.481-485
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• 2001

Laser cladding processing allows rapid transfer of heat to the material being processed with minimum conduction into base metal. The effect of $CO_2$ laser cladding with high viscosity mixed powders was investigated. High viscosity mixed powder consists of bronze powder and flux that is used at a high temperature condition. The mixed powder has a high viscosity that it can be easily pasted over a curved or slope substrate. The device for mixed powder was designed and manufactured. It consists of the high viscosity mixed powder feeding system, the preheating system and the shielding gas system which prevents the clad layer from being oxidized. The results of experiment indicated that the feed rate of high viscosity mixed powder was important for later cladding with mixed powder feeding. The high viscosity mixed powder and substrate must be preheated to prevent porosity from breaking at the clad layer. The experimental result shows that the high viscosity mixed can be applied for laser cladding process.

• Journal of Microbiology
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• 제40권1호
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• pp.51-54
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• 2002

Heavy metal adsorptions of four streptomycetes were compared with each other, Among the test strains, Streptomyces viridochromogenes showed the most efficient metal binding activity, which was carried out by cell wall as well as freeze-dried mycelium. An order of adsorption potential (zinc > copper > lead > cadmium) was observed in single metal reactions, whereas this adsorption order was disturbed in mixed-metal reactions. The metal adsorption reactions were very fast, pH dependent and culture age-independen, suggestive of a physico-chemical reaction between cell wall components and heavy metal ions. The metal tolerant stains presented the weakest adsorbing activity, indicating that the metal biosorption was not the basis of the metal tolerance.

• 한국지반환경공학회 논문집
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• 제13권12호
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• pp.59-66
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• 2012

본 연구에서는 철도정비창 부지 내에 폐기물 및 중금속오염 구간에서 채취한 토양을 대상으로 하였다. 그리고 효율적인 정화공정 설계를 위하여 고농도 오염구간, 저농도 오염구간, 폐주물사 함유 시료를 대상으로 입도분포 및 입도 분포 오염농도 분석을 실시하였다. 하지만 폐콘크리트, 폐목재 등의 건설폐기물, 폐주물사, 소각재 등이 부지 전반에 걸쳐 매립되어 있어 일반토양 오염과 다른 양상을 보이고 있었다. 따라서 일반적인 중금속정화기술로는 오염원이 감소하지 않아 혼합된 폐기물 중에 자성을 띠는 성분을 자력선별을 적용하여 실험한 결과 중금속 오염도는 감소하는 것으로 나타났다.

• 디자인학연구
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• 제13권4호
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• pp.43-56
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• 2000

본 논문은 현대금속공예에서 다양하게 사용되는 특수한 기법중의 하나인 형질변환의 다양한 사례를 연구하는 것을 주요골자로 하고 있다. 이러한 형질변환은 타장르에서도 활발히 연구되고 있는 부분이기는 하나, 금속공예에 있어서 실제적으로 적용되고 다양한 양태로 실험되고 있는 사례는 타장르에서 찾을 수 없는 부분이기도 하다. 이러한 형질변환에 대하여 그 가치를 따져보자면 금속공예가 현대화되기 이전부터 조금씩 다루어온 것이긴 하지만, 현대에 이르러 물질 자체의 이면적인 의미와 상징성 은유성 등을 다루기 시작하는 등 그 의미에 있어서의 차연화가 이루어지는 해체주의가 대두되면서 더욱 정당성이 부여되어 실험의 깊이와 폭이 한층 더 깊어졌다. 형질변환을 위한 특수한 기법에는 목목금기법, 강상조직기법, 융합기법, 전해주조기법, 특수한 형질변환 혼합매체의 사용 등이 있으며, 이러한 연구는 합금법과 함께 더욱 진전이 이루어지고 있다. 나아가서, 금속공예의 표현의 가능성을 더욱 광범위하게 하고 있다.

• 한국주조공학회지
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• 제17권4호
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• pp.402-410
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• 1997

Developing a salt core for squeeze casting process, two different salt cores(pure salt core and mixed salt core) were fabricated and investigated. Pure salt core was composed of 100% NaCl and mixed salt core was made by mixtures of NaCl with MgO(1%), $Na_2B_4O_7$(2%), and talc(1%) as a binder or a strengthening agent. Salt cores were compacted to various theoretical density, heat treated, and then squeeze-cast with molten Al alloy(AC8A). The compression strength of salt cores were measured and the squeeze-cast products were examined for shape retention, infiltration of molten metal into the cores, and microstructures. The shape of salt core compacted at above 75% of the theoretical density was maintained stably. The higher theoretical density of salt cores gave higher compression strength, and the compression strength of mixed salt core was higher than that of pure salt core. Namely at 90% theoretical density, the compression strength of mixed salt core was $6.3 kg/mm^2$, compared to $4.6 kgmm^2$ for pure salt core. At a squeeze casting pressure of $1000 kg/cm^2$, molten Al alloy was infiltrated into pure salt core of under 85% of the theoretical density. At squeeze casting pressure of $1000 kg/cm^2$, only mixed salt core above 90% of the theoretical density were valid, but the shape of the core was altered in the case of pure salt core at 90% of theoretical density. A key factor for developing a salt core for squeeze casting process was estimated as the ultimate compressive strength of salt core.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.339-339
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• 2010

The metallic nanoparticles (Pt, Au, Ag. Cu, etc.) supported on ceria-titania mixed oxide exhibit a high catalytic activity for the water gas shift reaction ($H_2O\;+\;CO\;{\leftrightarrow}\;H_2\;+\;CO_2$) and the CO oxidation ($O_2\;+\;2CO\;{\leftrightarrow}\;2CO_2$). It has been speculated that the high catalytic activity is related to the easy exchange of the oxidation states of ceria ($Ce^{3+}$ and $Ce^{4+}$) on titania, but very little is known about the ceria titanium interaction, the growth mode of metal on ceria titania complex, and the reaction mechanism. In this work, the growth of $CeO_x$ and Au/$CeO_x$ on rutile $TiO_2$(110) have been investigated by Scanning Tunneling Microscopy (STM), Photoelectron Spectroscopy (PES), and DFT calculation. In the $CeO_x/TiO_2$(110) systems, the titania substrate imposes on the ceria nanoparticles non-typical coordination modes, favoring a $Ce^{3+}$ oxidation state and enhancing their chemical activity. The deposition of metal on a $CeO_x/TiO_2$(110) substrate generates much smaller nanoparticles with an extremely high activity. We proposed a mechanism that there is a strong coupling of the chemical properties of the admetal and the mixed-metal oxide: The adsorption and dissociation of water probably take place on the oxide, CO adsorbs on the admetal nanoparticles, and all subsequent reaction steps occur at the oxide-admetal interface.

• Bulletin of the Korean Chemical Society
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• 제21권7호
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• pp.685-689
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• 2000

The complexation reaction between Pb2+,TI and Cd2+ions and macrocyclic ligands, 18-crown-6 ( 18C6) and dibenzo- 18-crown-6 (DB 18C6), was studied in dimethylsulfoxide (DMSO)-nitromethane (NM) and dimethyl-formamide (DMF)-nitromethane binary system s by square wave polarography (SWP) technique. The stoichiometry and stability of the complexes were determined by monitoring the shifts in half-waves or peak potentials of the polarographic waves of metal ions against the Iigand concentration. In most cases, the stability constants of complexes increase with increasing amounts of the nitromethane in mixed binary solvents used in this study. The complexes formed between 18C6 and DB18C6 and these metal cations in all cases had a stoichiometry of 1 : 1. The results obtained show that there is an inverse relationship between the formation constant of complexes and the donor number of solvents based on a Gatmann donocity scale and the stability constants show a high sensitivity to the composition of the mixed solvent systems. A linear behavior was observed for variation of log Kf of I8C6 complexes vs the composition of the mixed solvent systems in NM/DMSO and NM/DMF,but a non-linear behavior was observed in the case of DB 18C6 complexes in these binary systems. In most of the systems investigated, the Pb2+ cation forms a more stable complex with the 18C6 than other two cations and the order of selectivity of this Iigand for cations is: Pb2+ > TI+,Cd2+.

• 환경위생공학
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• 제14권4호
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• pp.150-157
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• 1999

According to the fact that Macbansuk and clay are very porous, we produced combined adsorbent and we investigated the removing capacity of adsorbent to toxic heavy metal (Pb, Cu) in the single and mixed solution.Then the experimental parametars were pH, reaction time and amount of adsorbent. And we studied possibility of adsorbent by applying to the Freundlich isotherm. As raising the pH of single and mixed solution in range 2~5, the maximum adsorption capability was investigated in range 3~4. When Cu and Pb were applied to Freundlich isotherm, l/n were 0.291 and 0.513 respectively. In the case of mixed solution with both, l/n value was 0.614. In this study, we concluded that the combined adsorbent treated toxic heavy metal is possible under 100 ppm of its concentration.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
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• pp.253-259
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• 2005

Mine is quickly decline, Nowadays, many of abandoned and closed mines. AMD is abandoned surface water by accumulated yellowboy and caused environmental pollution by amount of heavy metals. The aim of this study waste lime was mixed with the sediment to produce an aggregate far the purpose of neutralizing the acidity and stabilization the heavy metal in the aggregate structure .to pozzolan effect. The result of Waste lime and sediment mixed(5%, 10%, 20%)ration by curing days(3, 7, 38days), After 28 curing days as 5% mixed waste lime leaching solution concentration of all heavy metals is satisfied with regulation limit. Also, the result of fractionate heavy metals to stabilization as 28 curing days very decrease exchangeable and reducible type, and then increase carbonate type. With the above results, waste lime the most effective for the sediment treatment and useful for the recycling waste resource.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2006년도 추계학술대회 논문집 전기물성,응용부문
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• pp.81-82
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• 2006

Chemical mechanical polishing (CMP) technology has been widely used for global planarization of multi-level interconnection for ULSI applications. However, the cost of ownership and cost of consumables are relatively high because of expensive slurry. In this paper, so as to investigate the influence of mixed abrasive slurry (MAS), such as $ZrO_2$, $CeO_2$, and $MnO_2$ for Ti-CMP application.