• Title/Summary/Keyword: mixed crystal

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A study of crystal growth and phase transition in $K_2Zn_{1-X}Co_XCl_4$ mixed crystal ($K_2Zn_{1-X}Co_XCl_4$ 결정 성장 및 상전이에 관한 연구)

  • 김성규;안호영;정세영
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.2
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    • pp.278-285
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    • 1998
  • It was known that the C-IC transition in the mixed crystal $(A_{1-x}A^'_x)_2ZnCl_4$ is smeared out with increasing x, which is attributed to the pinning effect of the doped A' ions. In this study, we introduce a new mixed crystal system $K_2Zn_{1-X}Co_XCl_4$, where doped Co ions do not destroy the orientation of the polarization in C phase and preserve the long range ordering of IC phase. We grew a series of mixed crystals $K_2Zn_{1-X}Co_XCl_4$ for x=0, 0.001, 0.005, 0.01, 0.05, 0.1, 0.3, 0.5, 0.7, 1 by the Czochralski method and investigated the real composition of the mixed crystals, structure and the change of the C-IC phase transition with increasing x by the thermal analysis.

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A Quantitative Visualization of Mixed Convection in Parallel Plates Using PIV (PIV를 이용한 평행평판 내의 혼합대류의 정량적 가시화)

  • 박일용;배대석
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.3
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    • pp.509-515
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    • 2004
  • The PIV(Particle Image Velocimetry) with liquid crystal tracers is used for visualizing and analysis of the mixed convection in the parallel plates with the upper part cooled and the lower part heated. It is found that the flow pattern of mixed convection in the parallel plates can be classified into three patterns which was affected by Reynolds number. Also, the periodic nature is confirmed, and visualized in experiment.

6H-SiC epitaxial growth and crystal structure analysis (6H-SiC 에피층 성장과 결정구조 해석)

  • Kook-Sang Park;Ky-Am Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.2
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    • pp.197-206
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    • 1997
  • A SiC epilayer on the 6H-SiC crystal substrate was grown by chemical vapor deposition (CVD). The crystal structure of the SiC epilayer was investigated by using the X-ray diffraction patterns and the Roman scattering spectroscopy. The SiC epilayer on the 6H-SiC substrate was grown to be homoepilayer by CVD. In order to distinguish a certain SiC polytype mixed in the SiC crystal grown by the modified Lely method, we have calculated the X-ray diffraction intensities and Brags angles of the typical SiC crystal powders. By comparing the measured X-ray diffraction pattern with the calculated ones, it was identified that the SiC crystal grown by the modified Lely method was the 6H-SiC crystal mixed some 15R-SiC.

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Membrane from Liquid Crystal Composite of Cellulose Acetate and Poly (4-vinyl pyridine) (셀룰로오스 아세테이트와 폴리비닐 피리딘 액정중합체의 박막에 관한 연구)

  • Hong, Young-Keun;Cho, Bong-Heuy
    • Textile Coloration and Finishing
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    • v.3 no.2
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    • pp.43-48
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    • 1991
  • Cellulose acetate (CA) and poly-4-vinyl pyridine (PVP) in various weight proportions were mixed in a mixed solvent of trifluoroacetic acid: methylene chloride/6:4 (v:v). CA was miscible with PVP in that solvent system. CA/PVP/solvent show liquid crystal in a certain range of concentration and the nature of that liquid crystal was cholesteric. Films of the liquid crystal composite cast from the liquid crystal solutions of CA/PVP were tested in a viewpoint of biomembrane. Results show that considering permselectivity CA/PVP membrane is better than that of CA and CA/PVP membrane is closer to cell membrane.

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A preparation of dysprosium monotitanate powder by mixed-oxide ceramics processing employing polymer carrier (Polymer carrier 효과에 의하여 단순화된 새로운 세라믹분말 제조방법)

  • 이상진
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.2
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    • pp.350-355
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    • 1998
  • Dysprosium monotitanate $(Dy_2TiO_5)$ powder was synthesized by a simple mixed-oxide ceramics process using ethylene glycol (EG). Ethylene glycol, as the organic carrier for the metal cations, was used for polymerization mechanism. The successful used of a non-chelating polymer for the mixed-oxide ceramic process indicated that cation chelation is not the only route for creating stable ceramic precursors. Characterization of the powders by various thermal analysis, microscopy, and diffraction methods has been carried out.

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SI(superconductor-insulator) Transitions in Bi-superconducting Mixed Crystal Thin Films

  • Park, No-Bong;Yang, Sung-Ho;Park, Yong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.486-489
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    • 2002
  • Temperature(T) dependence of the sheet resistance( $R_{$\square$}$) has been investigated on the c-axis oriented thin films of the (Bi2212/Bi2201) mixed crystal with different molar fractions. The $R_{$\square$}$-T superconducting characteristic deteriorated with reduction of the Bi2212 fraction, and almost disappears at 48 mol% where a superconductor-to-insulator transition took place, with the resistance on the normal state, RN, reaching 4.l㏀ at 80 K. This $R_{N}$ value is close to the universal quantum number, h/(2e)$^2$≡6.5㏀ predicted by the Kosterlitz-Thouless(KT) transition theory. The $R_{$\square$}$-T characteristics of the 48 mol% thin film can be elucidated as a competitive process of KT transition brought about by charge or vortex in the two-dimensional layer structure.e.

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Sl Transitions in BSCCO Mixed Crystal Thin Films

  • Ahn, Joon-Ho;Yi, Keon-Young;Park, Yong-Pil
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.2
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    • pp.20-23
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    • 2002
  • Temperature (T) dependence of the sheet resistance (R$\_$$\square$/) has been investigated an the c-axis oriented thin films of the (Bi2212/Bi2201) mixed crystal with different molar fractions. The R$\_$$\square$/-T superconducting characteristic deteriorated with reduction of the Bi2212 fraction, and almost disappears at 48 mol% where a superconductor-to-insulator transition too k place, with the resistance on the normal state, R$\_$N/, reaching 4.1 kΩka at 80 K. This R$\_$$\square$/ value is close to the universal quantum number, h/(2e)$_2$≡ 6.5 kΩ predicted by the Kosterlitz-Thouless (KT) transition theory. The R$\_$$\square$/-T characteristics of the 48 mol% thin film can be elucidated as a competitive process of KT transition brought about by charge or vortex in the two-dimensional layer structure.

Start-up dynamics in a CMSMPR crystallizer (CMSMPR 결정화기의 시동 특성 연구)

  • 신영준;이철수
    • 제어로봇시스템학회:학술대회논문집
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    • 1986.10a
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    • pp.200-204
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    • 1986
  • Particle size distribution in a Continuous Mixed Suspension Mixed Crystal Removal (CMSMPR) crystallizer has been analyzed using the Population Balance (PB) model. This method presents difficulties when the growth rate of crystal depends on the crystal size. Recent studies indicate that in many cases the growth rate is dependent on size when the crystal sizes are small. In this study, a Residence Time Distribution(RTD) model was proposed to take the size dependence into account together with an appropriate numerical scheme. When compared with the approximate results based on PB model, RTD model results showed improvements also a nucleation effect which is normally unimportant for steady state analysis. Start-up data for NaCl-Water-Ethanol system was compared with computed values.

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An Experimental Investigation of Unsteady Mixed Convection in a Horizontal Channel with Cavity Using Thermo-Sensitive Liquid Crystals

  • Bae, Dae-Seok;Cai, Long-Ji;Kim, Eun-Pil
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.7
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    • pp.987-993
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    • 2009
  • An experimental study is performed to investigate unsteady mixed convection in a horizontal channel with a heat source. Particle image velocimetry (PIV) with thermo-sensitive liquid crystal (TLC) tracers is used for visualization and analysis. This method allows simultaneous measurement of velocity and temperature fields at a given instant of time. Quantitative data of the temperature and velocity are obtained by applying the color-image processing to a visualized image, and neural network is applied to the color-to-temperature calibration. It is found that the periodic flow of mixed convection in a cavity appears at very low Reynolds numbers (Re<0.4), and the period decreases with increasing Reynolds numbers and increases with increasing aspect ratio.