• Bulletin of the Korean Chemical Society
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• v.34 no.8
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• pp.2473-2479
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• 2013

The kinetics of the radical-polar molecule reaction $CH_3+HBr{\rightarrow}CH_4+Br$ has been studied at temperatures between 150 and 1000 K using classical dynamics procedures. Potential energy surfaces constructed using analytical forms of inter- and intramolecular interaction energies show a shallow well and barrier in the entrance channel, which affect the collision dynamics at low temperatures. Different collision models are used to distinguish the reaction occurring at low- and high-temperature regions. The reaction proceeds rapidly via a complex-mode mechanism below room temperature showing strong negative temperature dependence, where the effects of molecular attraction, H-atom tunneling and recrossing of collision complexes are found to be important. The temperature dependence of the rate constant between 400 and 1000 K is positive, the values increasing in accordance with the increase of the mean speed of collision. The rate constant varies from $7.6{\times}10^{-12}$ at 150 K to $3.7{\times}10^{-12}$ at 1000 K via a minimum value of $2.5{\times}10^{-12}\;cm^3\;molecule^{-1}\;s^{-1}$ at 400 K.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.36 no.3A
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• pp.278-286
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• 2011

Directional antennas have been used in Ad Hoc networks, significantly improving the spatial reuse of the networks. However, the extended transmission range causes collisions at the receivers of neighbors, which prevents full exploitation of the potential of the directional antenna. In this paper, we propose a new power control MAC protocol for a directional antenna. For this protocol, we propose a method to detect a set of interference nodes in the neighbors of a receiver. We then use a power control algorithm to calculate the minimum transmission power and send data. Simulation results demonstrate that this protocol increases the network performance and reduces energy consumption.

• Steel and Composite Structures
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• v.34 no.2
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• pp.227-239
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• 2020

The aim of this study is to obtain the nonlinear and post-buckling responses of relatively thick functionally graded plates with oblique elliptical cutouts using a new semi-analytical approach. To model the oblique elliptical hole in a FGM plate, six plate-elements are used and the connection between these elements is provided by the well-known Penalty method. Therefore, the semi-analytical technique used in this paper is known as the plate assembly technique. In order to take into account for functionality of the material in a perforated plate, the volume fraction of the material constituents follows a simple power law distribution. Since the FGM perforated plates are relatively thick in this research, the structural model is assumed to be the first order shear deformation theory and Von-Karman's assumptions are used to incorporate geometric nonlinearity. The equilibrium equations for FGM plates containing elliptical holes are obtained by the principle of minimum of total potential energy. The obtained nonlinear equilibrium equations are solved numerically using the quadratic extrapolation technique. Various sets of boundary conditions for FGM plates and different cutout sizes and orientations are assumed here and their effects on nonlinear response of plates under compressive loads are examined.

• Structural Engineering and Mechanics
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• v.10 no.4
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• pp.337-357
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• 2000

Analytical formulations and solutions for the first time, to the stability analysis of a simply supported composite and sandwich plates based on a higher order refined theory, developed by the first author and already reported in the literature are presented. The theoretical model presented herein incorporates laminate deformations which account for the effects of transverse shear deformation, transverse normal strain/stress and a nonlinear variation of inplane displacements with respect to the thickness coordinate - thus modelling the warping of transverse cross sections more accurately and eliminating the need for shear correction coefficients. The equations of equilibrium are obtained using the Principle of Minimum Potential Energy (PMPE). The comparison of the results using this higher order refined theory with the available elasticity solutions and the results computed independently using the first order and the other higher order theories developed by other investigators and available in the literature shows that this refined theory predicts the critical buckling load more accurately than all other theories considered in this paper. New results for sandwich laminates are also presented which may serve as a benchmark for future investigations.

• Geomechanics and Engineering
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• v.13 no.3
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• pp.385-410
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• 2017

This work presents a simple and refined nth-order shear deformation theory for mechanical and thermal buckling behaviors of functionally graded (FG) plates resting on elastic foundation. The proposed refined nth-order shear deformation theory has a new displacement field which includes undetermined integral terms and contains only four unknowns. Governing equations are obtained from the principle of minimum total potential energy. A Navier type analytical solution methodology is also presented for simply supported FG plates resting on elastic foundation which predicts accurate solution. The accuracy of the present model is checked by comparing the computed results with those obtained by classical plate theory (CPT), first-order shear deformation theory (FSDT) and higher-order shear deformation theory (HSDT). Moreover, results demonstrate that the proposed theory can achieve the same accuracy of the existing HSDTs which have more number of variables.

• Steel and Composite Structures
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• v.32 no.5
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• pp.657-670
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• 2019

This paper proposes a one-dimensional fiber beam element model taking account of materially non-linear behavior, benefiting the highly efficient elastic-plastic analysis of girders with shear-lag effects. Based on the displacement-based fiber beam-column element, two additional degrees of freedom (DOFs) are added into the proposed model to consider the shear-lag warping deformations of the slabs. The new finite element (FE) formulations of the tangent stiffness matrix and resisting force vector are deduced with the variational principle of the minimum potential energy. Then the proposed element is implemented in the OpenSees computational framework as a newly developed element, and the full Newton iteration method is adopted for an iterative solution. The typical materially non-linear behaviors, including the cracking and crushing of concrete, as well as the plasticity of the reinforcement and steel girder, are all considered in the model. The proposed model is applied to several test cases under elastic or plastic loading states and compared with the solutions of theoretical models, tests, and shell/solid refined FE models. The results of these comparisons indicate the accuracy and applicability of the proposed model for the analysis of both concrete box girders and steel-concrete composite girders, under either elastic or plastic states.

• Computers and Concrete
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• v.24 no.3
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• pp.185-192
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• 2019

In this paper, the buckling of micro sandwich hollow circular plate is investigated with the consideration of the porous core and piezoelectric layer reinforced by functionally graded (FG)carbon nano-tube. For modeling the displacement field of sandwich hollow circular plate, the high-order shear deformation theory (HSDT) of plate and modified couple stress theory (MCST) are used. The governing differential equations of the system can be derived using the principle of minimum potential energy and Maxwell's equation that for solving these equations, the Ritz method is employed. The results of this research indicate the influence of various parameters such as porous coefficients, small length scale parameter, distribution of carbon nano-tube in piezoelectric layers and temperature on critical buckling load. The purpose of this research is to show the effect of physical parameters on the critical buckling load of micro sandwich plate and then optimize these parameters to design structures with the best efficiency. The results of this research can be used for optimization of micro-structures and manufacturing different structure in aircraft and aerospace.

• Advances in aircraft and spacecraft science
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• v.6 no.5
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• pp.409-426
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• 2019

The aim of the present work is to study the nonlinear behavior of the laminated composite plates under transverse sinusoidal loading using a new inverse trigonometric shear deformation theory, where geometric nonlinearity in the Von-Karman sense is taken into account. In the present theory, in-plane displacements use an inverse trigonometric shape function to account the effect of transverse shear deformation. The theory satisfies the traction free boundary conditions and violates the need of shear correction factor. The governing equations of equilibrium and boundary conditions associated with present theory are obtained by using the principle of minimum potential energy. These governing equations are solved by eight nodded serendipity element having five degree of freedom per node. A square laminated composite plate is considered for the geometrically linear and nonlinear formulation. The numerical results are obtained for central deflections, in-plane stresses and transverse shear stresses. Finite element Codes are developed using MATLAB. The present results are compared with previously published results. It is concluded that the geometrically linear and nonlinear response of laminated composite plates predicted by using the present inverse trigonometric shape function is in excellent agreement with previously published results.

• Computers and Concrete
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• v.23 no.5
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• pp.361-376
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• 2019

In this research, bending analysis of a micro sandwich skew plate with isotropic core and piezoelectric composite face sheets reinforced by carbon nanotube on the elastic foundations are studied. The classical plate theory (CPT) are used to model micro sandwich skew plate and to apply size dependent effects based on modified strain gradient theory. Eshelby-Mori-Tanaka approach is considered for the effective mechanical properties of the nanocomposite face sheets. The governing equations of equilibrium are derived using minimum principle of total potential energy and then solved by extended Kantorovich method (EKM). The effects of width to thickness ratio and length to width of the sandwich plate, core-to-face sheet thickness ratio, the material length scale parameters, volume fraction of CNT, the angle of skew plate, different boundary conditions and types of cores on the deflection of micro sandwich skew plate are investigated. One of the most important results is the reduction of the deflection by increasing the angle of the micro sandwich skew plate and decreasing the deflection by decreasing the thickness of the structural core. The results of this research can be used in modern construction in the form of reinforced slabs or stiffened plates and also used in construction of bridges, the wing of airplane.

• Asian-Australasian Journal of Animal Sciences
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• v.15 no.9
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• pp.1307-1311
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• 2002

Twelve dietary combinations were prepared using 70 parts of fermented wheat straw (FWS) as the sole roughage supplemented with 30 parts of either the low protein concentrate mixture (Conc.-I), high protein concentrate mixture (conc.-II), maize grains (M), solvent extracted mustard cake (DMC), deoiled rice bran (DRB), uromol bran mixture (UBM), deep stacked poultry litter (DSPL), dried poultry droppings (DPD), M-DMC mixture (50:50), M-UBM mixture (50:50), M-DPD mixture (50:50) or M-UBM-DPD mixture (50:25:25) and evaluated by in-sacco technique. The above dietary combinations were also evaluated by changing the roughage to concentrate ratio to 60:40. The digestion kinetics for DM and CP revealed that FWS:DPD had the highest, whereas, the FWS:M-DMC had the lowest rapidly soluble fraction. The potentially degradable fraction was found to be maximum in FWS:M and minimum in FWS:DPD dietary combinations. The higher degradation rate of FWS:DRB and FWS:UBM combinations was responsible for their significantly (p<0.05) higher effective degradability as compared to other combinations. The highest undegradable fraction noted in FWS:M-UBM-DPD followed by FWS:DMC was responsible for high rumen fill values. The FWS:DRB, FWS:UBM and FWS:DPD combinations had higher potential for DM intake. The dietary combination with higher concentrate level (60:40) was responsible for higher potentially degradable fraction, which was degraded at a faster rate resulting in significantly higher effective degradability as compared to the corresponding dietary combination with low concentrate level (70:30). The low undegradable fraction in the high concentrate diet was responsible for low rumen fill values, which predicted of high potential for DM intake. Out of 24 dietary combinations, FWS with either of UBM, DRB, DMC, Maize, M-DMC or DPD in 70:30 ratio supplemented with minerals and vitamin A in comparison to conventional feeding practice (roughage and concentrate mixture) could be exploited as complete feed for different categories of ruminants.