• Title/Summary/Keyword: mineral material

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Thermogravimetric Analysis of Black Mass Components from Li-ion Battery (폐이차전지 블랙 매스(Black Mass) 구성 성분의 열중량 특성 분석)

  • Kwanho Kim;Kwangsuk You;Minkyu Kim;Hoon Lee
    • Resources Recycling
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    • v.32 no.6
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    • pp.25-33
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    • 2023
  • With the growth of the battery industry, a rapid increase in the production and usage of lithium-ion batteries is expected, and in line with this, much interest and effort is being paid to recycle waste batteries, including production scrap. Although much effort has been made to recycle cathode material, much attention has begun to recycle anode material to secure the supply chain of critical minerals and improve recycling rates. The proximate analysis that measures the content of coal can be used to analyze graphite in anode material, but it cannot accurately analyze due to the interaction between the components of the black mass. Therefore, in this study, thermogravimetric analysis of each component of black mass was measured as the temperature increased up to 950℃ in an oxygen atmosphere. As a result, in the case of cathode material, no change in mass was measured other than a mass reduction of about 5% due to oxidation of the binder and conductive material. In the case of anode material, except for a mass reduction of about 2% due to the binder, all mass reduction were due to the graphite(fixed carbon). In addition, metal conductors (Al, Cu) were oxidized and their mass increased as the temperature increased. Thermal analysis results of mixed samples of cathode/anode show similar results to the predictive values that can be calculated through each cathode and anode analysis results.

Development of Material Separation Process for Recycling Waste Coffee Capsules (폐 커피 캡슐의 재활용을 위한 재질분리 공정 개발)

  • Baek, Sang-Ho;Han, Yosep;Kim, Seongmin;Davaadorj, Tsogchuluun;Jeon, Ho-Seok
    • Resources Recycling
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    • v.30 no.3
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    • pp.70-81
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    • 2021
  • This study evaluated the recyclability of waste plastics in used coffee capsules disposed of as municipal waste. For recycling, a new material separation process was developed to remove the coffee grounds through primary crushing, washing, sieving, and secondary crushing, followed by corona discharge electrostatic separation. Furthermore, for the under 10 mm size fraction samples, the aluminum removal and the plastic recovery were 95.4% and 98.3%, respectively, under optimal conditions. In addition, for the 15 mm fraction samples, the aluminum removal and the plastic recovery were 91.3% and 97.2%, respectively. To evaluate the recyclability of the separated waste plastics, the samples were pelleted, and their material properties were analyzed. No hazardous substances were detected, and the results were similar to those for homo-PP. Therefore, it was confirmed tha t sufficient functiona lity existed a s recycled PP. However, owing to the da rk color of the pellets, limited applications to black or dark products are expected.

Development of RTD Model of the Mixer-Settler-Type Extractor Using the Stimulus-Response Method (자극-반응법(反應法)을 이용(利用)한 혼합침강형(混合沈降型) 추출장치(抽出裝置)의 RTD 모델 개발(開發))

  • Lee, Jin-Young;Kim, Joon-Soo;Lee, Hoo-In;Sohn, Jeong-Soo
    • Resources Recycling
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    • v.16 no.5
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    • pp.65-70
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    • 2007
  • This study presents the findings of the experiments that were conducted on single- and multi-stage solvent extractors using the stimulus-response method, with the am of identifying flow characteristics of the material inside the mixer-settler-type extractor. The results of this study show that the response characteristics of a single-stage mixer is the same as that of a completely stirred tank reactor (CSTR), and that the lag time of a mixer-settler-type extractor increases with the number of its extraction stages. The experimental data for the single- and multiple-stage extractors were analyzed using K-RTD, a response analysis program, to obtain a retention time distribution (RTD) model of one-stage and four-stage extractors. The correlation coefficient between the calculated values and the experimental data was 0.963 for the one-stage extractor and 0.995 for the four-stage extractor, showing quite a good correlation.

The effects of current density and nickel content on copper electrowinning by energy saving system (에너지절약형 동(Cu)전해채취 및 전류밀도의 영향)

  • Lee, Hoo-In;Lee, Jae-Chun;Park, Jin-Tae;Kim, Min-Seuk;Sohn, Jeong-Soo;Koyama, Kazuya
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.386-387
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    • 2006
  • This study is about the recycling technology of scrap a PCB(printed circuit board) produced in home appliances or automobile industry. And we develop the recycling technology of cooper (Cu)which is contained to leaching solution. In stead of electrolytic collecting in existing sulphuric atmosphere, we apply process using the ammonia solution which is used in economizing energy. So m the process of electrolyzing scrap a PCB through the leaching and separation, we examine the effect of the nickel contained to the solution and the cooper degree of purity which is changed according to current density.

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Metal Nano Powders as a New Getter Material (새로운 게터소재로서의 금속 나노 분말)

  • Kim, Won-Baek;Park, Je-Shin;Suh, Chang-Youl;Chang, Han-Kwon;Lee, Jae-Chun;Park, Mi-Young
    • Journal of Powder Materials
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    • v.14 no.1 s.60
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    • pp.56-62
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    • 2007
  • Getter property of nano-sized metallic powders was evaluated as a possible candidate for the future getter material. For the purpose, Ti powders of about 50 nm were prepared by electrical wire explosion. Commercial Ti powders of about 22 micrometer were tested as well for comparison. The room-temperature hydrogen-sorption speed of nano-sized Ti powders was $1.34\;L/sec{\cdot}cm^{2}$ which was more than 4 times higher than that of micron-sized ones. The value is comparable to or even higher than those of commercial products. Its sorption speed increases with activation temperature up to $500^{\circ}C$ above which it deteriorates due to low-temperature sintering effect of nano-sized particles.

Development of the Magnetic Abrasive Using Worthless Mineral (폐광물을 이용한 자기 연마재 개발)

  • Kim, Hee-Nam;Kim, Dong-Wook
    • Journal of the Speleological Society of Korea
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    • no.70
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    • pp.45-50
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    • 2006
  • The magnetic polishing is the useful method to finish using magnetic power of magnet. This method is one of precision polishing techniques and has an aim of the clean technology using for the pure of gas and inside of the clean pipe for transportation. The magnetic abrasive polishing method is not so common for machine that it is not spreaded widely. There are rarely researcher in this field because of non-effectiveness of magnetic abrasive. Therefore, in this paper deals with development of the magnetic abrasive using worthless mineral. In this development, abrasive grain WA and GC used to resin bond fabricated low temperature. And magnetic material was fabricated from the worthless mineral which were closed into 200 mesh grit type. The XRD analysis result show that only WA and GC abrasive and worthless mineral crystal peaks detected which explains resin bond was not any more chemical reaction. From SEM analysis it is found that WA and GC abrasive and worthless mineral were strong bonding with each other by bond.

Procedures Involving the IMA Commission on New Minerals and Mineral Names, and Guidelines on Mineral Nomenclature

  • Nickel, E.H.;Mandarino, J.A.
    • Journal of the Mineralogical Society of Korea
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    • v.2 no.1
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    • pp.47-55
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    • 1989
  • The Commission on New Minerals and Mineral Names (hereafter abbreviated as CNMMN) of the International Mineralogical Association was established in 1959 for the purpose of controlling mineral nomenclature, All proposals for introducing new minerals, changing mineralogical nomenclature, and discrediting or redefining existing minerals and mineral names should be submitted to the CNMMN for approval before publication. If approval is withheld, the proposal should not be published. This report incorporates material from previous reports on mineral nomenclature and procedures of the CNMMN (Fleischer, 1970; Donnay and Fleischer, 1970; Embrey and Hey, 1970; Hey and Gottardi, 1980; and Mandarino et al., 1984), and represents an attempt to consolidate this information and to present a there are differences between this report and the earlier ones, this versionis to be regarded as the correct one.

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Synthesis of Kaolinitic Clay Mineral from Amorphous Alumino-Silicate by Hydrothermal Process (비정질 Alumino-Silicate로부터 수열반응에 의한 Kaolinite질 인공점토의 합성에 관한 연구)

  • 김남일;박계혁;정창주
    • Journal of the Korean Ceramic Society
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    • v.31 no.9
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    • pp.1076-1086
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    • 1994
  • This study covers synthetic effect of the various hydrothermal treatments on formation of artificially made kaolinite mineral. The hydrothermal treatment includes the temperature treatment with time duration, addition of seeds, particle size of the starting material used, pH variation and the different types of organic acids. A colloidal silica and alumina sol which are commercially available are used for this study. A colloidal silica and alumina sol are mixed by the atomic ratio of Al/Si = 1, based on the theoretical kaolinite composition and calcined at $600^{\circ}C$ for 8 hours duration. It was found that the kaolinitic clay mineral was well developed; thereby, the different patterns of crystalline mineral are appeared. Spherical type as a crystal form was distinctively formed at the temperature of 20$0^{\circ}C$ to 25$0^{\circ}C$ with short duration time, while platy type as a crystal was highly yielded at 300~35$0^{\circ}C$. Moreover, by adding more than 20 wt% of seed as the natural kaolinitic clay to the starting material is widely distributed and developed when 2 ${\mu}{\textrm}{m}$ or less particle size of the starting material is used; also, when they are heat-treated at the temperature of 25$0^{\circ}C$ with 5 hours duration. With respect of the effect of pH variation on formation of the synthetic kaolinite minerals, the crystalline minerals are highly yielded at less than pH 2 and gradually diminished at more than pH9. Regarding to the effect of different acids on development of the kaolinite mineral, the organic acids with high chelating capacity produces good formation of crystalline minerals; whereas, amine radical-(NH2) is not an effective agent to generate the crystalline minerals.

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Development of Vermiculite Board to Secure the Fire Resistance Performance of Light-Frame Wood Structural Wall (경골목구조 벽체의 내화성능확보를 위한 질석보드 개발)

  • Yoo, Seok Hyung;Cheong, Chang Heon
    • Fire Science and Engineering
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    • v.32 no.1
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    • pp.40-45
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    • 2018
  • It is considered that vermiculite as an inorganic material is highly effective when it is used as a building finishing material because it is eco-friendly. Vermiculite has excellent properties such as fire resistance, heat insulation, sound absorption as well as prevention of condensation, deodorization and aesthetics. In this study, we developed a finishing board with vermiculite as its main material and mixed with mineral loose wool (VB-L) or mineral powder (VB-P), and conducted fireproof test and insulation test. In addition, fire resistance tests were carried out by applying the two developed vermiculite boards as finishing materials for the standard wall details of light frame wood structures (KS F 1611-1). As a result of the fire resistance test, the VB-L specimen showed better fire resistance than the VB-P specimen. Both vermiculite boards showed sufficient fire resistance performance of 2 hours for a thickness of 30 mm.

Synthesis of Si-CNT-C Composites and Their Application to Lithium Ion Battery (실리콘-탄소나노튜브-탄소 복합체 제조 및 리튬이온전지 응용)

  • Kim, Chan Mi;Kim, Sun Kyung;Chang, Hankwon;Kil, Dae sup;Jang, Hee Dong
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.42-48
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    • 2018
  • Silicon has attracted extensive attention due to its high theoretical capacity, low discharge potential and non-toxicity as anode material for lithium ion batteries. In this study, Si-CNT-C composites were fabricated for use as a high-efficiency anode material in a lithium ion battery. Aerosol self-assembly and post-heat treatment processes were employed to fabricate the composites. The morphology of the Si-CNT-C composites was spherical and an average particle size was $2.72{\mu}m$. The size of the composite increased as concentration of Si and CNT increased in the precursor solution. In the Si-CNT-C composites, CNT and C carbonized from glucose were attached to the surface of Si particles. Electrochemical measurement showed that the cycle performance of Si-CNT-C composites was better than that of silicon particles.