• Applied Microscopy
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• v.25 no.3
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• pp.82-89
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• 1995

High resolution transmission electron microscopic observations on quaternary $Zn_{1-x}Mg_{x}S_y$ $S_{1-y}$(x=0.13, y=0.16) on (001) GaAs substrate grown up to $1.2{\mu}m$ with 20nm ZnSe buffer layer at $300^{\circ}C$ by RIBER MBE system which has a single growth chamber were investigated by HRTEM working at 300kV with point resolution of 0.18nm. The ZnSe buffer layer maintains the coherency with the GaAs substrate. The stacking faults had begun at ZnSe buffer/$Zn_{1-x}Mg_{x}S_{y}S_{1-y}$ interface, whose length and spacing became larger than 60nm and wider than 40nm, respectively. The inverse triangular stacking fault was bounded by stacking faults which were formed on {111} planes with different variants. There exists rare stacking faults inside the triangular defect. The epilayer surrounded by the straight stacking faults, which had formed in the same direction, became the columnar structure.

• Corrosion Science and Technology
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• v.7 no.3
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• pp.139-144
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• 2008

The results of microstructure observations of the $Al_2O_3$ scale formed on a Fe-Cr-Al steel during high temperature oxidation in the $SO_2$ atmosphere are presented. Morphology of the scale has been studied by SEM and TEM techniques. Phase and chemical compositions have been studied by EDX and XRD techniques. The alumina oxide is a primary component of the scale. TEM observations showed that the scale was multilayer. The entire surface of the scale is covered with "whiskers", which look like very thin platelets and have random orientation. The cross section of a sample shows, that the "whiskers" are approximately $2{\mu}m$ high, however the compact scale layer on which they reside is $0.2{\mu}m$ thick. The scale layer was composed mainly of small equiaxial grains and a residual amount of small columnar grains. EDX analysis of the scale surface showed that the any sulfides were found in the formed outer and thin inner scale layer. A phase analysis of the scale formed revealed that it is composed mainly of the $\theta-Al_2O_3$ phase and a residual amount of $\alpha-Al_2O_3$.

• Journal of Korea Foundry Society
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• v.14 no.6
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• pp.530-540
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• 1994

Aluminium-silicon alloy(JIS AC8A) matrix composites reinforced with SiC particles were fabricated by spray-cast forming process, and the microstructure of powders and preforms produced were studied by using an optical and scanning electron microscopy. SiC particles were co-sprayed by mixed phase injection method during the spray casting process. Most of the composite powders formed by this mixed phase injection method exhibit morphology of particle-embedded type, and some exhibits the morphology of particle attached type due to additional attachment of the SiC particles on the surface of the powders in flight. The preforms deposited were resulted in dispersed type microstructure. The pre-solidified droplets and the deposited preform of SiC-reinforced aluminium alloy exhibit finer equiaxed grain size than that of unreinforced aluminium alloy. Eutectic silicons of granular type are crystallized at the corner of the aluminum grains in the preforms deposited, and some SiC particles seem to act as nucleation sites for primary/eutectic silicon during solidification. Such primary/eutectic silicons seem to retard grain growth during the continued spray casting process. It is envisaged from the microstructural observations for the deposited preform that the resultant distribution of SiC injected particles in the Al-Si microsturcture is affected by the amount of liquid phase in the top part of the preform and by the solidification rate of the preform deposited.

• Journal of the Korean Society for Heat Treatment
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• v.11 no.2
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• pp.92-98
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• 1998

Degradation and recovery of damping capacity in a Cu-65%Mn alloy have been studied. When the alloy was isothermally aged at $400^{\circ}C$, the highest damping capacity was observed after aging for 4 hours. In case when the alloy aged at $400^{\circ}C$ for 4 hours was maintained at $100^{\circ}C$, the damping capacity gradually decreased with time. The microstructural observations showed that the formation of subdomains and ${\alpha}$-Mn precipitates are responsible for the degradation of damping capacity. When the degraded specimen was reheated at $250^{\circ}C$ for 30 minutes, the damping capacity was recovered considerably owing to the redistribution of impurity atoms, the extinction of subdomains and the release of damping sources from ${\alpha}$-Mn precipitates during the repeated transformation, fcc${\leftrightarrow}$fct.

• Korean Journal of Materials Research
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• v.24 no.9
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• pp.488-494
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• 2014

The effect of tungsten (W) addition on the hardenability of low-carbon boron steels was investigated using dilatometry, microstructural observations and secondary ion mass spectroscopy. The hardenability was discussed with respect to transformation behaviour aspects depending on the segregation and precipitation of boron at austenite grain boundaries. A critical cooling rate producing a hardness corresponding to 90 % martensite structure was measured from a hardness distribution plot, and was used as a criterion to estimate hardenability at faster cooling rates. In the low-carbon boron steel, the addition of 0.50 wt.% W was comparable to that of 0.20 wt.% molybdenum in terms of critical cooling rate, indicating hardenability at faster cooling rates. However, the addition of 0.50 wt.% W was not more effective than the addition of .0.20 wt.% molybdenum at slower cooling rates. The addition of 0.20 wt.% molybdenum completely suppressed the formation of eutectoid ferrite even at the slow cooling rate of $0.2^{\circ}C/s$, while the addition of 0.50 wt.% W did not, even at the cooling rate of $1.0^{\circ}C/s$. Therefore, it was found that the effect of alloying elements on the hardenability of low-carbon boron steels can be differently evaluated according to cooling rate.

• Transactions of Materials Processing
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• v.22 no.5
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• pp.269-274
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• 2013

Experiments and numerical simulations of the incremental upsetting test were carried out to investigate void closure behavior and mechanical characteristic of a 1.5wt%C ultra-high carbon steel. The experimental results showed that the voids become quickly smaller as the reduction ratio increases. The simulation results confirmed this behavior and indicated that the voids were completely closed at a reduction ratio of about 40~45% during incremental upsetting. After the completion of the incremental upsetting tests, the process of diffusion bonding was employed to heal the closed voids in the deformed specimens. To check the appropriate temperature for diffusion bonding, deformed specimens were kept at 800, 900, 1000 and $1100^{\circ}C$ for an hour. In order to investigate the effect of holding time for diffusion bonding at $1100^{\circ}C$, specimens were kept at 10, 20, 30, 40, 50 and 60minutes in the furnace. A distinction between closed and healed voids was clearly established using microstructural observations. In addition, subsequent tensile tests demonstrated that complete healing of a closed void was achieved for diffusion bonding temperatures in the range $900{\sim}1100^{\circ}C$ with a holding time larger than 1 hour.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2003.05a
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• pp.65-69
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• 2003

The effects of microstructural features on the fracture behaviors, including impact, high-cycle fatigue, fatigue and crack propagation, of thixoformed 357-T5 (Al-7%Si-0.6%Mg) alloy were examined. The resistance to impact and high-cycle fatigueof thixoformed 357-T5 tended to improve greatly with increasing solid volume fraction. An almost three-fold increase in impact energy value was, for example, observed with increasing solid volume fraction from 59 to 70%. The improvement in both impact and fatigue properties of thixoformed 357-75 with increasing solid volume fraction in the present study appeared to be related to the magnitude of stress concentration at the interface between primary and eutectic phase, by which the fracture process was largely influenced. Based on the fractographic and micrographic observations, the mechanism associated with the beneficial effect of high solid volume fraction in thixoformed 357-T5 alloy was discussed.

• Korean Journal of Materials Research
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• v.25 no.9
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• pp.497-502
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• 2015

The hardenability of boron steel specimens with different molybdenum and chromium contents was investigated using dilatometry and microstructural observations, and then was quantitatively measured at a critical cooling rate corresponding to 90 % martensite hardness obtained from a hardness distribution plotted as a function of cooling rate. Based on the results, the effect of an austenitizing temperature on the hardenability and tensile properties was discussed in terms of segregation and precipitation behavior of boron atoms at austenite grain boundaries. The molybdenum addition completely suppressed the formation of pro-eutectoid ferrite even at the slowest cooling rate of $0.2^{\circ}C/s$, while the chromium addition did at the cooling rates above $3^{\circ}C/s$. On the other hand, the hardenability of the molybdenum-added boron steel specimens decreased with an increasing austenitizing temperature. This is associated with the preferred precipitation of boron atoms since a considerable number of boron atoms could be concentrated along austenite grain boundaries by a non-equilibrium segregation mechanism. The secondary ion mass spectroscopy results showed that boron atoms were mostly segregated at austenite grain boundaries without noticeable precipitation at higher austenitization temperatures, while they formed as precipitates at lower austenitization temperatures, particularly in the molybdenum-added boron steel specimens.

• Journal of Powder Materials
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• v.13 no.3 s.56
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• pp.199-204
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• 2006

We manufactured the metal hydrides of $(Ti_{0.88}Mg_{0.12})H_2$ using a very easy and cheap way that Ti-12%Mg blending powder was mechanically milled with liquid milling media such as isopropyl alcohol ($C_3H_8O$, containing oxygen) and hexane ($C_6H_{14}$, no oxygen) as hydrogen source. The $(Ti_{0.88}Mg_{0.12})H_2$ synthesized in isopropyl alcohol contained the high oxygen of 11.2%, while one in hexane had the low oxygen content of 0.7%. Such a difference of oxygen content affected the dehydriding behavior, phase transformation, and microstructural evolution at high temperature, which was investigated through X-ray diffraction and DSC measurements, and electron microscope observations.

• Journal of Powder Materials
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• v.5 no.4
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• pp.334-339
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• 1998

In purpose of introducing the inverse magnetostrictive properties into the structural ceramics, $Al_2O_3$ based nanocomposites dispersed with nano-sized Ni-Co particles were studied. The composites were fabricated by the hydrogen reduction and hot-pressing of $Al_2O_3$ and NiO-CoO mixed powders. The mixtures were prepared by using Ni- and Co-nitrate $(Ni(NO_3)_2\;{\cdot}\;6H_2O\;and\;Co(NO_3)_2\;{\cdot}\6H_2O)$ as source materials for the Ni-Co particles. Microstructural observations revealed that nano-sized Ni-Co particles were dispersed homogeneously at $Al_2O_3$ grain boundaries. High strength above 1 GPa was obtained for the $Al_2O_3/10$ wt% Ni-Co nanocomposite fabricated by a controlled powder preparation process. The inverse magnetostrictive response to applied stress was obtained due to the presence of dispersed Ni-Co particles, which indicates a possibility to incorporate new functions into the structural ceramics without loosing the mechanical properties.