• Title/Summary/Keyword: microstate

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EDISON 앱 개발 및 교육을 위한 Polymer Collapse 중 Polymer의 Entropy 및 Free Energy 계산

  • Park, Yun-Jae;Jang, Rak-U
    • Proceeding of EDISON Challenge
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    • 2017.03a
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    • pp.75-81
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    • 2017
  • Polymer collapse transition에 대한 연구가 많이 진행되어왔다. 허나 각각의 microstate에 대한 entropy나 free energy에 대한 계산을 하지는 못하였다. 최근 local nonequilibrium thermodynamics와 관련한 논문이 발표되었는데 이는 비평형 상태에서의 각각의 microstate에 대한 확률 분포를 결정하는 물리량을 발견 및 특성을 규명하여 이 중 특별한 상태가 지니는 "information" 이라는 양이 내부에너지와 엔트로피와의 상관관계가 있음을 보였다. 또한, 이러한 information theory를 이용한 Shannon entropy를 사용하여 entropy를 정의하고 free energy와 같은 물리량을 계산하였다. 따라서 이를 이용하여 information theory를 이용한 Shannon entropy와 이로 정의된 free energy를 이용하여 polymer collapse중 entropy 및 free energy를 계산하였다.

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A Study of Pre-service Chemistry Teacher's Understanding on Entropy

  • Seo, Young-Jin;Hong, Hun-Gi
    • Journal of The Korean Association For Science Education
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    • v.32 no.3
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    • pp.415-427
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    • 2012
  • In this study, we conducted preliminary survey, diagnostic test and in-depth interview in order to study Korean pre-service chemistry teachers' understanding on entropy and investigate how Korean pre-service chemistry teachers deal with the natural phenomenon which is related to entropy conceptions. Firstly, as a result of the preliminary survey, it was found that pre-service chemistry teachers strongly recognized entropy as the degree of disorder. Secondly, the diagnostic test showed pre-service chemistry teachers were mostly confused about whether the entropy of the universe increases during a spontaneous change, and they had a tendency to interpret the natural phenomenon related to entropy change as the change of disorder. Finally, during in-depth interview, after we explained entropy change in all diagnostic test questions with the concept of microstate, pre-service chemistry teachers revealed a better understanding about entropy. Through this research, pre-service chemistry teachers had an opportunity to reflect on their deficiencies of entropy conceptions, which will ultimately help students to approach the concept of entropy more correctly.

Studies of the Definition and Explanation of Entropy in the GeneralChemistry Textbook (일반화학 교재에 나타난 엔트로피 정의와 설명의 고찰)

  • Seo, Young-Jin;Chae, Hee K.
    • Journal of the Korean Chemical Society
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    • v.53 no.1
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    • pp.62-72
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    • 2009
  • In this study, entropy definition and explanation in twelve general chemistry textbooks published in USA including what Korean universities select are analyzed. Analysis consists of two parts. One is diachronic analysis which focuses on the change between editions of same authors and the other is contents analysis composed of three sections‐ disorder in entropy definition and explanation, microstates number in entropy definition and explanation, possibility of alternative conception in learning statistical entropy and thermal entropy. As a result, the definition that entropy is the measure of disorder is denied and explanation using microstates number is introduced. Also, caution for the possibility of alternative conception that there are two different entropies is found. Reflecting the change in entropy explanation on new chemistry curriculum and reeducating teachers are meaningful on improvement of Korean chemistry education.

Entropy and its Relation with the Property of Molecule, Phase and Component (엔트로피와 분자 특성, 상 및 성분의 관계)

  • Jaeeon Chang
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.116-122
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    • 2023
  • We study the relationship of entropy with the properties of molecules and also with the macroscopic specifications of the system, i.e., component and phase. Understanding different viewpoints of classical mechanics and quantum mechanics for the indistinguishability of molecules belonging to the same component, we discuss a few thermodynamic systems in which the properties of molecules are to be consistent with the component as a macroscopic term of classifying the molecules. With a clear definition of thermodynamic microstate, the drawback of the Boltzmann statistics caused by the distinguishability of molecules is avoided, and the Gibbs paradox of entropy consequently disappears. Corresponding to the characteristics of fluid and solid phases, we investigated the effects of the indistinguishability and the symmetry number of molecules and the number of microstates realized in time on the partition function and the entropy. In particular, we show that crystalline solid can be regarded as a system which does not satisfy the ergodic hypothesis.

Geography of Microstate Migration Caused by Environmental Problems: The Case of Tuvalu (환경문제로 인한 미소국가 이주의 지리학: 투발루의 사례)

  • Shen, Shawn
    • Journal of the Korean Geographical Society
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    • v.51 no.2
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    • pp.185-200
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    • 2016
  • The discipline of Geography is broadly concerned with the interconnections between people and the environment. Particularly, this unique human-environment relationship often can be typically reflected from, and well illustrated by, the dynamics of microstates' island environment. While Tuvaluans living on vulnerable, low-lying atolls in the Pacific are not primarily responsible for contributing to climate change, yet they are experiencing its dreadful effects. Population pressure, caused by the differences in population size, distribution, and composition, has been constantly affected by resource unavailability and environmental instability on the islands. It also represents one of our challenges in understanding the complex influence of population dynamics on the living environment. What can be learned from Tuvalu in the context of population geography and environmental geography as well as its relationship with other Pacific island microstates? What are Tuvaluans' migration responses to their atolls' environmental crisis as well as the carrying capacity scenarios related to overpopulation? What are the current living experiences and settlement situations of Tuvaluan internal and external migrants both at home and abroad? This research examines the contemporary migration literature in the context of Tuvalu's population geography, while analyzing Tuvaluan migration patterns, discourses and perspectives in relation to environmental change.

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