• 자원환경지질
• /
• 제17권4호
• /
• pp.315-320
• /
• 1984

The newly discovered minerals found during 30 years have been discovered with election microprobe analysis, and several other new minerals have been described largely on the basis of probe analysis. Widely used types of instrument are the wavelength dispersive spectrometer (WDS) and the energy dispersive Spectrometer (EDS), with emitted X-ray dispersed by a curved crystal that is arranged to satisfy the Bragg equation ($n{\lambda}=2dsin{\theta}$). Atomic Nos of Z 4 to 92 can be analyzed quantitatively if they present in amount exceeding 50~100ppm. The application of the microprobe in mineralogical and geological research is quantitative chemical analysis of grains as small as a few microns in diameter, individual grains in a rock or can be analyzed in thin section and polished section, analysis can be made comparatively short time, methods in non-destructure, to photographical and crystallographical information. This paper was written in order to document data evaluation procedure for quantitative energy dispersive election probe analysis.

• 한국광물학회지
• /
• 제11권1호
• /
• pp.13-19
• /
• 1998

Textures of claystones of the Cheonunsan Formation in the Hwasoon area have been studied using optical microscope and electron microprobe. Microscopic images were observed under the optical microscope using the transmitted polarizing light from thin sections and under the electron microprobe using the back-scattered electron beam from the polished sections. Identification of minerals were made using X-ray diffraction analysis and chemical analysis by electon microprobe. Textural analyses show that the original sedimentary claystones rich in aluminium were subjected to metamorphism by which they changed to the metamorphosed claystone consisting mainly of chloritoid, quartz, andalusite and illite. Later intensive hydrothermal kaolinization of this metamorhosed claystones resulted in the formation of high-aluminous claystones rich in kaolinite exhibiting various complicated replacement textures.

• 동굴
• /
• 제9권
• /
• pp.3-7
• /
• 1999

Corralloid speleothems from Round Mountain lave cave are are studied by scanning microscope and electron microprobe analyses. Scanning microscopy observation indicates that the diatom Melosira seems to contribute significantly to siliceous coralloid speleothems Electron microprobe confirms the presence of diatom and fragmental minerals(plagioclase and orthopyroxene) in coralloid speleothems. Chemical analysis of 3 diatom cells gives SiO2(74.8%), Al2O3(0.12%), FeO(0.11%), CaO(0.47%) and MgO(0.81%).

• Asian Journal of Atmospheric Environment
• /
• 제5권1호
• /
• pp.56-63
• /
• 2011

Quantifying the solute composition of a cloud droplet (or a whole droplet) is an important task for understanding formation processes and heating/cooling rates. In this study, a combination of droplet fixation and SR-XRF microprobe analysis was used to visualize and quantify elements in a micro-scale droplet. In this study, we report the preliminary outcome of this experiment. A spherical micro-scale droplet was successfully solidified through exposure to ${\alpha}$-cyano-acrylate vapor without affecting its size or shape. An X-ray microprobe system equipped at the beam line 37XU of Super Photon ring 8 GeV (SPring-8) was applied to visualize and quantify the elemental composition in an individual micro-scale droplet. It was possible to reconstruct 2D elemental maps for the K and Cl contained in a microdroplet that was dispensed from the 10-ppm KCl standard solution. Multi-elemental peaks corresponding to X-ray energy were also successfully resolved. Further experiments to determine quantitative measures of elemental mass in individual droplets and high-resolution X-ray microtomography (i.e., 3D elemental distribution) are planned for the future.

• 대한전자공학회논문지
• /
• 제25권11호
• /
• pp.1335-1341
• /
• 1988

A pH-ISEFET microprobe for in vivo measurements has been fabricated by combining ISFET (SL-IIS) chip and capillary thin film reference electrode. A two-step TCE oxidation for the gate oxide layer and multilayer encapsulation using silicone rubber and epoxy were specially used for the improvement of the stability and temperature dependence of the ISFET's. The measured sensitivit, response time and temperature dependence of the pH-ISFET microprobes are 50 mV/pH, less than one second, and - 0.01 pH/$^{\circ}$ , respectively. By operating continuously more than 40 days, a long term stability of 0.016 pH/day is obtained. The result of pH monitoring of femoral arterial blood in a rabbit is fairly good agreement with the value of blood gas analysis.

• 대한화학회지
• /
• 제22권3호
• /
• pp.184-193
• /
• 1978

Styrene-divinylbenzene 공중합체를 이황화탄소 용매 속에서 무수염화알루미늄과 반응시켜 염화알루미늄${\cdot}$고분자촉매를 합성하여 이들의 형태를 광학현미경, 주사전자현미경으로 조사하고 원자흡광 및 electron microprobe X-선으로 분석하였다. 각종 유기산과 지방족 및 방향족 알코올과의 에스테르화반응에서 염화알루미늄${\cdot}$고분자촉매의 효과에 관하여 연구하였다.

• 한국측량학회:학술대회논문집
• /
• 한국측량학회 2003년도 춘계학술발표회 논문집
• /
• pp.151-159
• /
• 2003

This study presents method for self-calibration of the SEM(Scanning Electron Microscope) stereo image using the standard microprobe with same grid pattern and using parallel and central perspective projection equation. Result showed that parallel projection method is more suitable for standard microprobe. The maximum error of 3D coordinates acquired by this method did not exceed 5 $\mu\textrm{m}$, and DSM(Digital Surface Model) for three dimensional measurement of the rock sample was generated by the digital photogrammetry. This result can be used for quantification of micro scale change of shape and analysis of the micro morphology of rock due to weathering.

• 한국세라믹학회지
• /
• 제31권1호
• /
• pp.104-114
• /
• 1994

ZrO2 fibers were fabricated by means of the Sol-Gel process using Zr(O-nC3H7)4-H2O-C2H5OH-HNO3 solution as a starting material. The optimum experimental parameters such as molar ratio of starting materials, concentration, temperature, viscosity, the amounts of stabilizer and the pH of solution were determined. The experimentally determined optimum variables which produce good ZrO2 fibers were used to manufacture the Y2O3-and CaO-ZrO2 fibers. The amounts of Y2O3 and CaO were varied within the range from 1.5~5 mol% and 3~15 mol% respectively. The phase transformation and microstructural evolution of the fabricated ZrO2 gel fibers were investigated after heat treatments up to 120$0^{\circ}C$ by X-ray diffraction, Raman microprobe spectroscopy, SEM, and specific surface area and pore volume measurements. From the analysis of X-ray diffraction and Raman spectra, the phase of heat treated Y2O3-and CaO partially stabilized ZrO2 gel fibers(Y2O3:2.5~3 mol%, CaO:6~9 mol%) were identified as a tetragonal phase up to 100$0^{\circ}C$. The maximum tensile strength of 2.5Y2O3-97.5ZrO2 and 6CaO-94ZrO2 (in mol%) fibers heat treated at 100$0^{\circ}C$ for 1 hr was found be 1.3~2 GPa with diameters of 10~20 ${\mu}{\textrm}{m}$.

• 콘크리트학회논문집
• /
• 제19권5호
• /
• pp.577-584
• /
• 2007

Steel microfiber (SMF)가 알칼리-실리카 반응 (ASR)에 미치는 영향을 두 가지 종류 (부순 오팔과 직경이 일정한 pyrex 막대)의 반응 골재를 사용하여 알아보았다. ASR에 의한 균열은 기준 모르타르에서 쉽게 발견되었으나 SMF 모르타르의 균열은 아주 제한적이었다. SMF의 균열 진전 제어 메커니즘을 통하여 ASR에 의한 모르타르의 강도 저하와 팽창을 효과적으로 막을 수 있었고, ASR 생성물들의 유동성이 저하됨을 알 수 있었다. ASR 생성물의 성분을 microprobe 분석과 ICP 분광계를 이용하여 알아보았다. SMF의 구속 효과는 액체상태인 ASR 생성물의 높은 나트륨이 온과 규소이온의 농도를 초래하였으며, 높은 이온의 농도는 ASR 알칼리-실리카 반응성을 저하하는 원인으로 생각되어 진다.

• 한국지구물리탐사학회:학술대회논문집
• /
• 한국지구물리탐사학회 2007년도 특별 심포지엄 논문집
• /
• pp.27-30
• /
• 2007

Martian meteorites are the only available Martian Materials on Earth. A suite of demagnetization experiments, temperature dependence of saturation magnetization, scanning electron microscopy, and electron microprobe analysis were carried out to characterize the remanent magnetization carriers of Martian meteorite SaU 008. A stable paleomagnetic record of SaU 008 originates from a newly found spinel ((Fe, Cr, Ti)-spinel) whose composition has never been documented (or identified as magnetic).