• Polymer(Korea)
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• v.24 no.5
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• pp.621-628
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• 2000

Microporous polypropylene (PP) membranes have the high chemical and corrosion resistance, the good mechanical properties and the thermal stability under high temperatures, but its application is restricted within narrow limits due to hydrophobicity of membranes. In order to impart permanent hydrophilicity to the PP microfiltration membrane, the radiation-induced graft of 2-hydroxyethyl methacrylate (HEMA) and acrylic acid (AAc) containing hydrophilic functional group onto the membrane has been studied. The effect of graft conditions such as reaction time, total radiation dose, reaction temperatures, acid compositions on graft yield was investigated. Modified PP membranes were shown to cause an increase in the gas flux. Oil emulsion permeation flux of both original PP membrane and modified PP membrane was examined.

• Membrane Journal
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• v.33 no.2
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• pp.53-60
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• 2023

Mechanical energy can be harvested by triboelectric nanogenerators (TENG) from biological and environmental systems. In wearable electronics, TENG has a lot of significance as biomechanical energy can be harvested from the motion of humans, which is applied in vibrational sensors. Wearable TENG is prone to moisture and polytetrafluoroethylene (PTFE) is an excellent hydrophobic material used in these applications. The presence of highly electronegative fluorine atoms leads to very low surface energy. At the same time, the performance of the device increases due to the efficient capture of the electrons on the microporous membrane surface. This similar behavior occurs with polyvinylidene fluoride (PVDF) due to the presence of fluoride atoms, which is relatively less as compared to PTFE.

• Proceedings of the Membrane Society of Korea Conference
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• 1999.07a
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• pp.43-47
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• 1999

Pd-ceramic composite membranes and catalytic membrane reactors(CMR) have been studied for hydrogen purification and recovery in th fusion reactor fuel cycle. The development of techniques for coating microporous ceramic tubes with Pd and Pd/Ag layers is described: composite membranes have been produced by electroless deposition (Pd/Ag film of 10-20${\mu}{\textrm}{m}$) and rolling of thin metal sheet (Pd and Pd/ Ag membranes of 50-70 ${\mu}{\textrm}{m}$). Experimental results on electroless membranes showed that the metallic film presented some defects and the membranes had not complete hydrogen selectivity . Then the catalytic membrane reactors with electroless membranes can be applied for some industrial processes that do not require a complete separation of the hydrogen (i.e. in the dehydrogenation of hydrocarbons). The rolled thin Pd/Ag membranes separated the hydrogen from the other gas with a complete selectivity and exhibited a slightly larger (about a factor 1.7) mass transfer resistance with respect to the electroless membranes. Experimental tests confirmed the good performances in terms of durability.

• 한국전기화학회:학술대회논문집
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• 2005.04a
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• pp.51-51
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• 2005

• Environmental Engineering Research
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• v.25 no.2
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• pp.222-229
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• 2020

Membrane assisted condenser is an innovative membrane operation that exploits the hydrophobic nature of microporous membranes to promote water vapor condensation and recovery. It can be used for water and chemicals recovery from waste gaseous streams. In this work, the testing of membrane condenser for water and ammonia recovery from synthetic streams (i.e., a saturated air stream with ammonia) simulating the plume of cooling tower is illustrated. The modeling of the process was carried out for predicting the membrane-based process performance and for identifying the minimum operating conditions for effectively recovering liquid water. The experimental data were compared with the results achieved through the simulations showing good agreement and confirming the validity of the model. It was found that the recovery of water can be increased growing the temperature difference between the plume and the membrane module (DT), the relative humidity of the plume (RH^plume) and the feed flow rate on membrane area ratio. Moreover, the concentration of NH₃ in the recovered liquid water increased with the growing DT, at increasing NH₃ concentration in the fed gaseous stream and at growing relative humidity of the feed.

• Membrane Journal
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• v.29 no.4
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• pp.191-201
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• 2019

Before the commercialization of polymeric membranes applicable for industrial application, the homework remains for the high-performance polymers to overcome the practical challenge: long-term stability for prolonged service time. Polymers of intrinsic microporosity (PIMs), exhibiting exceptionally high fractional free volume and high permeability, are susceptible to physical aging where the extra volume created by the inefficient ladder-type packing will lead them from the volumetric equilibrium and reduce the free volume/permeability over time. Here, we will re-examine the physical aging of polymers of intrinsic microporosity, and discuss some of the most prominent attempts to mitigate physical aging in PIMs.

• Archives of Pharmacal Research
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• v.21 no.5
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• pp.503-507
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• 1998

Percutaneous absorption and model membrane variations of melationin (MT) in aqueous-based propylene glycol and $2-hydroxypropyl-{\beta}-cyclodextrin $vehicles were investigatted. the excised hairless mouse skin (HMS) and two synthetic ethylene vinyl acetate (EVA) and microporous polyethylene (MPE) were selected as a model membrane. the solubility of MT was determined by phase equilibrium study. the vertical $Franz{\circledR}$ type cell was used for diffusion study. The concentration of MT was determined using reverse phse HPLC system. The MT solubility was the highest in a mixture of PG and $2-HP{\beta}CD$. The percutaneous absorption of MT through excised HMS increased as the solubility increased. However, the permeability coefficient decreased and then slightly increased in mixture of PG and $2-HP{\beta}CD$. On the other hand, both flux and permeability coefficient through EVA membrane decreased as the solubility increased. No MT was detected over 12 h after starting diffusion through MPE membrane. The flux of MT was dependent on the type of membrane selected. Flux of MT was greatest in excised HMS followed by EBA and MPE membrane. Flux of MT through EVA membrane was 5-20 times lower when compared to excised HMS. Interestingly, volumes of donor phase when MPE membrane was used, significantly increased during the study period. the HMS might be applicable to expect plasma concentration of MT in human subjects based on flux and pharmacokinetic parameters as studied previously. the current studies may be applied to deliver MT transdermally using aqueous-based vehicles and to fabricate MT dosage forms.

• Polymer(Korea)
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• v.30 no.2
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• pp.175-181
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• 2006

Hybrid process of thermally-induced phase separation and stretching was developed for the preparation of microporous polypropylene hollow fiber membranes. Precursor for stretching was prepared by using soybean oil as a diluent and benzoic acid as a nucleating agent far the sphenlite control and it was stretched far the micrporous hollow fiber membrane. The effects of stretching ratio and deformation rate for stretching process were investigated. Increase of stretching ratio resulted in the greater pore size with nonuniform size distribution. Higher deformation rate also increaser the pore size with uniform size distribution. Stretching ratio was closely related with the orientation of polymer chain and increased the mechanical strength of the fiber. Increase of deformation rate had little effects on the orientation of crystalline phase, and decreased the orientation of amorphous phase which caused the decrease of tensile strength of the fiber and broke the micro-fibrils connecting spherulites to form a circular pore shape.

• Proceedings of the Membrane Society of Korea Conference
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• 2008.05a
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• pp.231-233
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• 2008

• Membrane Journal
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• v.29 no.2
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• pp.67-79
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• 2019

High purity propylene (propene) is an octane-enhancing chemical and also feedstock to industrially important chemicals. Purification of propylene from propane mixture is technologically and financially challenging because of their close boiling points. ZIF-8 membrane has been increasingly researched due to its great potential to separate propylene from propane effectively by molecular sieving. The increasing interest in ZIF-8 membranes lies in the so called "gate opening" effect. The gate opening effect enlarges the membrane pores and preferentially allows propylene to permeate through the membrane pores, while retaining the larger and heavier propane molecules in the feed stream in order to effect high propylene separation from propylene/propane mixture. In this paper, the widely accepted methods of ZIF-8 membrane preparation and parameters affecting propylene permeation and selectivity in ZIF-8 membrane are identified and reviewed.