• 제목/요약/키워드: micro-powder

검색결과 473건 처리시간 0.024초

ZnO와 TiO2 함유 복합나노섬유의 제조와 유해물질분해 성능 평가 (Fabrication of ZnO and TiO2 Nanocomposite Fibers and Their Photocatalytic Decomposition of Harmful Gases)

  • 허윤선;이승신
    • 한국의류학회지
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    • 제35권11호
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    • pp.1297-1308
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    • 2011
  • This research investigates the application of ZnO (zinc oxide) nanoparticles and $TiO_2$ (titanium dioxide) nanoparticles to polypropylene nonwoven fabrics via an electrospinning technique for the development of textile materials that can decompose harmful gases. To fabricate uniform ZnO nanocomposite fibers, two types of ZnO nanoparticles were applied. Colloidal $TiO_2$ nanoparticles were chosen to fabricate $TiO_2$ nano- composite fibers. ZnO/poly(vinyl alcohol) (PVA) and $TiO_2$/PVA nanocomposite fibers were electrospun under a variety of conditions that include various feed rates, electric voltages, and capillary diameters. The morphology of electrospun nanocomposite fibers was examined with a field-emission scanning electron micro- scope and a transmission electron microscope. Decomposition efficiency of gaseous materials (formaldehyde, ammonia, toluene, benzene, nitrogen dioxide, sulfur dioxide) by nanocomposite fiber webs with 3wt% nano-particles (ZnO or $TiO_2$) and 7$g/m^2$ web area density was assessed. This study shows that ZnO nanoparticles in colloid were more suitable for fabricating nanocomposite fibers in which nanoparticles are evenly dispersed than in powder. A heat treatment was applied to water-soluble PVA nanofiber webs in order to stabilize the electrospun nanocomposite fibrous structure against dissolution in water. ZnO/PVA and $TiO_2$/PVA nanofiber webs exhibited a range of degradation efficiency for different types of gases. For nitrogen dioxide, the degradation efficiency was 92.2% for ZnO nanocomposite fiber web and 87% for $TiO_2$ nanocomposite fiber web after 20 hours of UV light irradiation. The results indicate that ZnO/PVA and $TiO_2$/PVA nano- composite fiber webs have possible uses in functional textiles that can decompose harmful gases.

Fe계 벌크 비정질 합금을 이용한 레이저 용접층의 파손 거동 (Failure Behavior of Laser Cladding Layer used by Fe-based Bulk Metallic Glass)

  • 임병철;김대환;박상흡
    • 한국산학기술학회논문지
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    • 제16권9호
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    • pp.5743-5747
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    • 2015
  • 본 연구에서는 가스아토마이저로 제조된 Fe계 벌크비정질 합금 분말을 이용하여 제작된 시험편에 레이저 육성용접을 하였고, 인장시험과 경도시험의 실시 및 미세조직을 관찰하여 육성용접 층의 파괴거동을 분석하였다. 인장시험 결과 육성용접층은 탄성변형 후 바로 파괴가 일어났고, 모재는 소성변형 후 파괴가 일어났다. 육성용접층과 모재의 실제 최대인장강도는 각 각 955.9Mpa과 220.4Mpa이다. 육성용접층과 모재의 미소경도는 각 각 $485.5{\pm}21$$197.4{\pm}14$ 이었고, 육성용접층은 매우 높은 경도를 갖는다. 모재는 조대한 결정립을 갖는 미세 구조를 나타내었다. 인장시험 후 파단면을 고분해능주사전자현미경으로 관찰한 결과 육성용접층과 모재의 파괴형태는 각각 취성파괴와 연성파괴를 나타내었다.

장미 양액재배 배지의 구성요소로서 폐고무의 재활용에 관한 연구 (Study on Recycling of Waste Rubbers as Medium Components for Hydroponic Culture of Rose)

  • 김진국;이형규;정병용;황승재
    • 자원리싸이클링
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    • 제9권3호
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    • pp.46-53
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    • 2000
  • 최근 페고무의 증가에 따른 효율적 처리에 대한 관심이 증가하고 있다, 본 실험에서는 페고무를 장미 양약재배 배지의 구성요소로서 폐고의 재활용 방법을 연구하였으며, 배지내의 장미 생육상태, 미량원소, 다량원소, pH 그리고 EC롤 조사하였다. 생육 초기에 장미는 초기위조(morprent wilting)와 같은 증상이 관찰되었으나, 여러 주 후에 회복하였다. 개화 후 배지내의 $Zn^{2+}$의 농도는 페타이어의 함량이 높을수록 증가하였으며, 장미 식재 전 배지내의 pH는 7.17-7.99로 나타났지만, 개화후 배지내의 pH는 5.7-6.35로 식물의 성장에 적합한 상태로 안정화되는 것을 알 수 있었다. 대조구인 암면과 비교하여 폐암만과 EPDM 분말 9:3의 비율로 혼합한 배지를 제외한 모든 배지에서 장미의 초장, 가지수 그리고 생체증 큰 차이를 보이지 않았으며, 유사한 값을 나타내는 것을 알 수 있었다.

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Design, calibration and application of wireless sensors for structural global and local monitoring of civil infrastructures

  • Yu, Yan;Ou, Jinping;Li, Hui
    • Smart Structures and Systems
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    • 제6권5_6호
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    • pp.641-659
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    • 2010
  • Structural Health Monitoring (SHM) gradually becomes a technique for ensuring the health and safety of civil infrastructures and is also an important approach for the research of the damage accumulation and disaster evolving characteristics of civil infrastructures. It is attracting prodigious research interests and the active development interests of scientists and engineers because a great number of civil infrastructures are planned and built every year in mainland China. In a SHM system the sheer number of accompanying wires, fiber optic cables, and other physical transmission medium is usually prohibitive, particularly for such structures as offshore platforms and long-span structures. Fortunately, with recent advances in technologies in sensing, wireless communication, and micro electro mechanical systems (MEMS), wireless sensor technique has been developing rapidly and is being used gradually in the SHM of civil engineering structures. In this paper, some recent advances in the research, development, and implementation of wireless sensors for the SHM of civil infrastructures in mainland China, especially in Dalian University of Technology (DUT) and Harbin Institute of Technology (HIT), are introduced. Firstly, a kind of wireless digital acceleration sensors for structural global monitoring is designed and validated in an offshore structure model. Secondly, wireless inclination sensor systems based on Frequency-hopping techniques are developed and applied successfully to swing monitoring of large-scale hook structures. Thirdly, wireless acquisition systems integrating with different sensing materials, such as Polyvinylidene Fluoride(PVDF), strain gauge, piezoresistive stress/strain sensors fabricated by using the nickel powder-filled cement-based composite, are proposed for structural local monitoring, and validating the characteristics of the above materials. Finally, solutions to the key problem of finite energy for wireless sensors networks are discussed, with future works also being introduced, for example, the wireless sensor networks powered by corrosion signal for corrosion monitoring and rapid diagnosis for large structures.

HIGH BURNUP FUEL TECHNOLOGY IN KOREA

  • Song, Kun-Woo;Jeong, Yong-Hwan;Kim, Keon-Sik;Bang, Je-Geon;Chun, Tae-Hyun;Kim, Hyung-Kyu;Song, Kee-Nam
    • Nuclear Engineering and Technology
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    • 제40권1호
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    • pp.21-36
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    • 2008
  • High bum-up fuel technology has been developed through a national R&D program, which covers key technology areas such as claddings, $UO_2$ pellets, spacer grids, performance code, and fuel assembly tests. New cladding alloys were developed through alloy designs, tube fabrication, out-of-pile test and in-reactor test. The new Zr-Nb tubes are found to be much better in their corrosion resistance and creep strength than the Zircaloy-4 tube, owing to an optimized composition and heat treatment of the new Zr-Nb alloys. A new fabrication technology for large grain $UO_2$ pellets was developed using various uranium oxide seeds and a micro-doping of Al. The uranium oxide seeds, which were added to $UO_2$ powder, were prepared by oxidizing and heat-treating scrap $UO_2$ pellets. A $UO_2$ pellet containing tungsten channels was fabricated for a thermal conductivity enhancement. For the fuel performance analysis, new high burnup models were developed and implemented in a code. This code was verified by an international database and our own database. The developed spacer grid has two features of contoured contact spring and hybrid mixing vanes. Mechanical and hydraulic tests showed that the spacer grid is superior in its rodsupporting, wear resistance and CHF performance. Finally, fuel assembly test technology was also developed. Facilities for mechanical and thermal hydraulic tests were constructed and are now in operation. Several achievements are to be utilized soon by the Korea Nuclear Fuel and thereby contribute to the economy and safety of PWR fuel in Korea

Tribological Performance of Ni-Cr Composite Coating Sprayed onto AISI 4340 (SNCM439) Steel by High Velocity Oxygen Fuel

  • Umarov, Rakhmatjon;Pyun, Young-Sik;Amanov, Auezhan
    • Tribology and Lubricants
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    • 제34권6호
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    • pp.217-225
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    • 2018
  • In this study, we spray a Ni-Cr composite powder onto AISI 4340 steel using the high velocity oxygen fuel method. We subsequently subject the Ni-Cr coating (as-sprayed) to ultrasonic nanocrystal surface modification (UNSM) process to improve the tribological performance. This study aims at increasing the wear resistance and durability of the Ni-Cr coating by altering the surface integrity and microstructure via the UNSM process. The UNSM process reduces the surface roughness of the as-sprayed coating by about 64%, which is explained by observing the elimination of high peaks and valleys and filling up micro-pores. Furthermore, a change in the microstructure of the coating due to continuous high-frequency strikes to the surface by a tip can lead to an increase in hardness from about 48 to 60 HRC. Furthermore, we investigate the characterization of the friction and wear behavior of Ni-Cr coating by a ball-on-disc tribometer in the dry conditions. We determine that after the UNSM process, there is a significant reduction in the friction coefficient of the as-sprayed coating from approximately 1.1 to 0.75. This is owing to the increased hardness and smoothed surface roughness. In addition, we investigate the surface morphology and wear track of the coatings before and after the UNSM process using a scanning electron microscope, energy dispersive spectrometer, and three-dimensional laser scanning microscope. We observe that the wear track of the Ni-Cr coating after the UNSM process is lower than that of the as-sprayed one. Thus, we confirm that the UNSM process has a significant influence on the improvement of the tribological performance of the Ni-Cr composite coating.

대기압 마이크로웨이브 플라즈마를 이용한 다양한 크기의 ZnO tetrapod 합성 및 광촉매 특성 평가 (Synthesis of size-controlled ZnO tetrapods sizes using atmospheric microwave plasma system and evaluation of its photocatalytic property)

  • 허성규;정구환
    • 한국표면공학회지
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    • 제54권6호
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    • pp.340-347
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    • 2021
  • Among various metal oxide semiconductors, ZnO has an excellent electrical, optical properties with a wide bandgap of 3.3 eV. It can be applied as a photocatalytic material due to its high absorption rate along with physical and chemical stability to UV light. In addition, it is important to control the morphology of ZnO because the size and shape of the ZnO make difference in physical properties. In this paper, we demonstrate synthesis of size-controlled ZnO tetrapods using an atmospheric pressure plasma system. A micro-sized Zn spherical powder was continuously introduced in the plume of the atmospheric plasma jet ignited with mixture of oxygen and nitrogen. The effect of plasma power and collection sites on ZnO nanostructure was investigated. After the plasma discharge for 10 min, the produced materials deposited inside the 60-cm-long quartz tube were obtained with respect to the distance from the plume. According to the SEM analysis, all the synthesized nanoparticles were found to be ZnO tetrapods ranging from 100 to 600-nm-diameter depending on both applied power and collection site. The photocatalytic efficiency was evaluated by color change of methylene blue solution using UV-Vis spectroscopy. The photocatalytic activity increased with the increase of (101) and (100) plane in ZnO tetrapods, which is caused by enhanced chemical effects of plasma process.

저온 분사를 이용한 Cu계 비정질 코팅층의 제조 및 특성 연구 (Fabrication and Characterization of Cu-based Amorphous Coatings by Cold Spray Process)

  • 정동진;박동용;이진규;김형준;이기안
    • 대한금속재료학회지
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    • 제46권5호
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    • pp.321-327
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    • 2008
  • Cu based amorphous ($Cu_{54}Zr_{22}Ti_{18}Ni_6$) coating was produced by cold spraying as a new fabrication process. The microstructure and macroscopic properties of amorphous coating layer was investigated and compared with those of cold sprayed pure Cu coating. Amorphous powders were prepared by gas atomization and Al 6061 was used as the substrate plate. X-ray diffraction results showed that Cu based amorphous powder could be successfully deposited by cold spraying without any crystallization. The Cu based amorphous coating layer ($300{\sim}400{\mu}m$ thickness) contained 4.87% porosity. The hardness of Cu based amorphous coating represented $412.8H_v$, which was correspond to 68% of the hardness of injection casted bulk amorphous material. The wear resistance of Cu based amorphous coating was found to be three times higher than that of pure Cu coating. The 3-point bending test results showed that the adhesion strength of Cu based amorphous coating layer was higher than that pure Cu coating. It was also observed that hard Cu base amorphous particle could easily deform soft substrate by particle collisions and thus generated strong adhesion between coating and substrate. However, the amorphous coating layer unexpectedly represented lower corrosion resistance than pure Cu coating, which might be resulted from the higher content of porosity in the cold sprayed amorphous coating.

열간가압성형기술을 이용한 Ai-SiC 금속기 복합재료 개발 (Development of Al-SiC Metal Matrix Composites by using Hot Press Forming Technologies)

  • 전호진;김태원
    • Composites Research
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    • 제20권4호
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    • pp.9-17
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    • 2007
  • 분말야금법 및 고온진공가압기술, 열간등가압성형기술을 이용하여 알루미늄 금속기 복합재료를 제작하였으며 이들과 관련한 미시역학 기반 강화공정 모델을 개발하였다. 고온, 가압 성형공정은 기지재료의 비탄성거동과 성형체 내부의 기공 제거를 통한 충진을 수반하게 되며 이러한 공정은 압력, 온도 및 강화재의 체적분률 등과 같은 공정변수의 영향을 받게 된다. 따라서 개발된 강화공정 모델을 유한요소해석 프로그램에 적용함으로써 고온진공가압과 열간등가압 동안 기공의 상대밀도 변화에 따른 충진거동을 예측하였고 다양한 공정조건 하에서 실험결과와 잘 일치함을 확인하였다. 완성된 알루미늄 금속기 복합재료의 건전성 평가와 관련하여 인장시험을 수행하였으며 초기 잔존하는 기공의 영향에 따른 제반 기계적 특성을 고찰할 수 있었다.

국내 엘리트 보디빌더의 영양지식과 Bulking Phase의 영양보충제 복용실태와 영양소 섭취상태 (Study on Nutritional Knowledge, Use of Nutritional Supplements and Nutrient Intakes in Korean Elite Bodybuilders)

  • 이산인군;이한슬;조여원
    • 운동영양학회지
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    • 제13권2호
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    • pp.101-107
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    • 2009
  • The objectives of this study were to investigate 1) the nutritional knowledge, 2) the use of nutritional supplements, and 3) nutrient intakes of male elite bodybuilders (n=20). Participants carried out a comprehensive survey, anthropometric assessment, and 1 day food record. Daily nutrient intakes of the subjects were analyzed using Computer Aided Nutritional Analysis Program (Can-pro 3.0). The mean age of the subjects was 23.4 years. The mean duration of exercise was 5.3 years. The average scores of nutritional knowledge were 71.0%. The subjects were gathered nutrition information from nutrition book (65%), mass communication (50%), friends (50%) and coach (30%) in order. Ninety percentage of the subjects reported that they were taking nutritional supplements. Major reasons for taking nutritional supplements were to improve performance and to build-up muscle. The most frequently taken nutritional supplements were protein powder (85%), multivitamin/mineral (75%), BCAA (60%) and glutamine (55%) in order. The average daily energy intakes of the subjects were 4,248.7 kcal. The mean intake of protein was 370.3 g/day (3.93 g/kg BW). The ratio of total energy intake from carbohydrate, protein and lipid was 51 : 34 : 15. The intakes of most vitamin and minerals through food and nutrition supplements were much higher than those of each nutrient of the RDAs. Especially, vitamin B complex and vitamin C intakes were ranged from 500 to 3,000% of KNHNES. More research needs to be conducted to determine the optimal amounts of carbohydrates, protein, lipid and micro-nutrients for the bodybuilders.