• 월간산업보건
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• s.143
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• pp.51-52
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• 2000

• 월간산업보건
• /
• s.146
• /
• pp.30-31
• /
• 2000

• 월간산업보건
• /
• s.113
• /
• pp.38-40
• /
• 1997

• 월간산업보건
• /
• s.153
• /
• pp.34-36
• /
• 2001

• Bulletin of the Korean Chemical Society
• /
• v.23 no.6
• /
• pp.911-914
• /
• 2002

• Bulletin of the Korean Chemical Society
• /
• v.23 no.12
• /
• pp.1695-1696
• /
• 2002

• Journal of the Korean Society of Safety
• /
• v.20 no.3 s.71
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• pp.78-83
• /
• 2005

In this study, the evaluate characteristics of fire and explosion of MEK-PO are subjected to spontaneous ignition, flash point and explosion hazard. The minimum ignition temperature and instantaneous ignition temperature for MEK-PO were $188.5^{\circ}C\;and\;230^{\circ}C\;at\;225{\mu}L$. In addition The flash point for MEK-PO was obtained at $49^{\circ}C$. Furthermore, the maximum explosion pressure and the maximum explosion pressure rising velocity: using MCPVT (mini cup pressure vessel tester) were $10.82kgf/cm^2\;and\;33.72kgf/cm^2{\cdot}s$.

• Applied Chemistry for Engineering
• /
• v.32 no.4
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• pp.483-486
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• 2021

Catalytic ozonation of methyl ethyl ketone (MEK) has been examined over mesoporous MnO_x/Al₂O₃ (MA) catalysts developed by a solvent deficient method using two different manganese precursors including manganese chloride (C) and manganese sulfate (S) at room temperature. The maximum catalytic activities of MA with C (MEK removal efficiency and ozone decomposition of 98.4 and 93.7%, respectively) were higher than those of MA with S (MEK removal efficiency and ozone decomposition of 96 and 68%, respectively). Also the catalytic stability of MA with C was much higher than that of MA with S. The physico-chemical properties of catalysts are well correlated with the activity results, which confirmed that fine dispersion of MnO_x species with high ratios of Mn³⁺/Mn⁴⁺ and more acid sites are attributed to the higher catalyst stability for the MA-C catalyst.

• Journal of the Korean Chemical Society
• /
• v.51 no.4
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• pp.356-360
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• 2007

5,7-Diaryl-3,4,6-trihydronaphthalen-2-ones have been synthesized from 3,5-diaryl-cyclohex-2-en-1- ones and methyl vinyl ketone in the presence of sodium ethoxide. The products were characterized by IR, UV-Visible, 1H-NMR, 13C-NMR and mass spectral techniques. To confirm 1H and 13C signals, HSQC spectrum was recorded and analyzed.

• Journal of the Korean Society of Safety
• /
• v.10 no.2
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• pp.92-96
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• 1995

The flash point is generally used as a hazardous index of fire or explosion of a flammable liquid. In this study, the lower flash points and the upper flash points according to the composition of Toluene-o-Xylene and Toluene-Methyl Ethyl Ketone mixtures are determined by air-blowing method. As results, relations between the flash points and the compositions of mixtures ; (1) for Toluene-o-Xylene mixtures $T_{fL}$=25.23 $\alpha$ ＋5.34 $T_{fu}$=27.36 $\alpha$ ＋40.50 (2) for Toluene-Methyl Ethyl Keton mixtures $T_{fL}$=10.00 $\beta$-5.00 $T_{fu}$=16.91 $\beta$＋20.45.