• Title/Summary/Keyword: method of caustic

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Computation of stress Intensity Factors of Hollow Cylinder with Three Dimension Inclination Cracks (3차원 경사크랙을 가진 중공축의 응력확대계수산정)

  • 이종선
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.8 no.1
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    • pp.21-27
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    • 1999
  • In this study, stress intensity factors KI, KII, KIII are existing at the same time to a hollow cylindrical bar of three dimension inclination crack. In order to investigate by experimentally the effect of the inclination angle $\psi$ of crack, artificial inclination cracks in the circumferential direction are put in the surface of a hollow cylindrical bar made by the epoxy-resin. Experimentally, stress analysis methods of stress intensity factors were proposed. But, suitable method are the caustic method and the photoelastic stress freezing method. The mixed mode of KI, and KII, were determined by the photoelastic method of the classical approach method and the FORTRAN language program of the used smallest square method.

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Removal of Arsenic From Closed Mine Tailings by Alkali-Leaching Method (알칼리 용출법에 의한 폐광산 광미중의 비소제거에 관한 연구)

  • 이재령;오종기;이화영;김성규;박재구
    • Journal of Korea Soil Environment Society
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    • v.2 no.2
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    • pp.73-79
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    • 1997
  • Removal of the Arsenic components from the closed mine tailings has been attempted by the alkali-leaching method. Two tailings collected from the Daduck and Yuchon mine which were already closed many years ago were leached with caustic soda solutions. The Arsenic components in the leach liquor resulted from the alkali treatment of tailings could be removed fairly well in the form of insoluble calcium-Arsenic compound by the precipitation with calcium chloride. As a result, the extraction of about 60~90% Arsenic from the tailings could be obtained depending on the leaching conditions and the influence of temperature and the slurry density on the extraction of Arsenic was also found to be very small at the NaOH concentration more than 0.5N. In addition, it seemed that a caustic soda solution over 0.5N NaOH could be used repeatedly for the leaching of tailings since the consumption of NaOH was not so great in a leaching of them. As far as the precipitation of Arsenic components was concerned, more than 99% of Arsenic could be precipitated within 10 minutes by the addition of 2wt% CaC12 in to the leach liquor.

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STUDY ON GY NEW MINERAL PROCESSING TECHNOLOGY FOR SHIZHUYUAN POLYMETALLIC ORE

  • Zhang, Zhonghan;Li, Xiaodong;Ye, Zhiping;Guo, Jianguan
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.325-330
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    • 2001
  • Shizhuyuan W-Mo-Bi-Ca $F_2$polymetallic ore is classified to the refractory one due to its complex property, fine dissemination and close association of minerals. Through several years of researches, in line with GY new mineral processing technology developed by Guangzhou Research Institute of Nonferrous Metals, in sulfide flotation circuit, an iso-flotability flowsheet is used to replace original overall bulk flotation flowsheet, and in tungsten flotation circuit, a new chelating type-GY reagent and a special pulp-conditioning system and a new technology of wolframite slime flotation are used to replace the traditional "Caustic Soda Method"$_{[1]}$, the metallurgical performance is greatly improved. Besides, GY New Method has created a favorable condition for comprehensive recovery of fluoride from tungsten flotation tailings. Notable economic benefit has been achieved.d.

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Manufacturing Method and Characteristics of the Dongrok(copper chloride) pigments (동록(염화동) 안료의 제조방법 및 특성에 관한 연구)

  • KANG Yeongseok;PARK Juhyun;MUN Seongwoo;HWANG Gahyun;KIM Myoungnam;LEE Sunmyung
    • Korean Journal of Heritage: History & Science
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    • v.56 no.2
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    • pp.148-169
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    • 2023
  • Hayeob pigment is known as one of the traditional dark green pigments, but the color, raw material, and manufacturing method have not been clearly identified. However, comparing the analysis results of the particle shape and constituent minerals of Hayeob pigments revealed through pigment analysis studies of colored cultural properties such as Dancheong, Gwaebul, and paintings, Hayeob pigments appear to be the same as Dongrok pigments produced by salt corrosion. Therefore, in order to restore Hayeob pigment, the manufacturing method of Dongrok pigment was studied based on the records of old literature. The Dongrok pigment manufacturing method confirmed in the old literature records is a natural corrosion method in which copper powder and a caustic are mixed and then left in a humid condition to corrode. Based on this, artificial corrosion using a corrosion tester was adopted to corrode the copper powder more efficiently, and an appropriate mixing ratio was selected by analyzing the state of corrosion products according to the mixing ratio of the caustic agent. In addition, the manufacturing method of Dongrok pigment was established by adding a salt removal process to remove residual caustic agents and a purification process to increase chroma during pigment coloring. The prepared Dongrok pigments have a bluish green or green color, show an elliptical particle shape and a form in which small particles are aggregated, and a porous surface is observed. The main constituent elements are copper(Cu) and chlorine(Cl), and the main constituent mineral is identified as atacamite [Cu2Cl(OH)3]. As a result of an accelerated weathering test to evaluate the stability of the prepared Dongrok pigments, it was found that the greenness partially decreased and the yellowness significantly increased as deterioration progressed. Before deterioration, the Dongrok pigments had lower yellowness compared to the Hayeob pigments of the old Dancheong, but after deterioration, yellowness increased significantly, and it was found to have a similar chromaticity range as Dancheong's Hayeob pigments. As a result, the prepared Dongrok pigments were confirmed to be similar to Dancheong's Hayeob pigments in terms of color as well as particle shape and constituent minerals.

Dynamic Fracture Analysis of Structural Element due to Stress Wave Propagation (응력파에 의한 구조부재의 동적파괴 해석)

  • 김경수;박준범;정배훈
    • Computational Structural Engineering
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    • v.10 no.4
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    • pp.195-203
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    • 1997
  • The interaction between cracks and stress wave due to impact and explosive loads is numerically calculated in the study. The interaction and the effects of stress wave are numerically examined with the application of Bicharacteristic Method. This method has been used with confidence for its reliability in reproducing the realistic and physical wave pattern in the complete solution domain. The dynamic stress intensity factor, K/sub I/(t) for cracks under impact loads are numerically simulated and its results are compared favorably with Kalthoff's experimental output. Also the influence of stress wave to the dynamic stress intensity factor for the case of two symmetric holes around cracks are investigated. The results of study are also compared favorably with the experiment and proven to be applied to the structures exposed to impact and explosive loads.

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Evolution of the Hanji-making Technology, from Ancient Times to the Present

  • Oh-Kyu LEE;Seokju KIM;Hyung Won LEE
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.6
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    • pp.509-525
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    • 2023
  • This study has delved into the evolution of Hanji-manufacturing molds and techniques from ancient times to the present, aiming to uncover the current state of traditional Hanji-making techniques. In the absence of records on Hanji-making, various ancient documents, rare books, and documents during the Japanese occupation period, among other artifacts and relics, were analyzed in this study. It was discovered that a sudden significant transformation occurred in the Hanji field during the Japanese occupation period. Soda ash and caustic soda were commonly used for the pretreatment of White bark. Furthermore, a chemical bleaching powder was introduced for the pretreated White bark. Additionally, manual beating of the bark was replaced by mechanical beating methods. While these changes brought convenience to papermakers, they also resulted in a deterioration of Hanji quality. Furthermore, it was revealed that the term "Hanji" has been in use since at least 1908. Furthermore, this study clarified that Heulimtteugi is not the only traditional Hanji-making method in Korea. Instead, there existed Korea's own traditional Gadoomtteugi method, at least up to the 1930s, before the Japanese-style Gadoomtteugi became common in Korea. Additionally, for the first time, this study raises the possibility of the adoption of mold-hanging techniques into Korea's Heulimtteugi method from foreign sources.

Determination of NaOH, $Na_2CO_3$ and $Na_2S$ Concentration in a Naphtha Cracking Process by FT-NIR Spectroscopy (FT-NIR를 이용한 Naphtha Cracking 공정중 NaOH, $Na_2CO_3$$Na_2S$ 정량분석)

  • Jang, Mijin;Kim, Hyunwook;Cho, Ilyoung
    • Analytical Science and Technology
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    • v.11 no.6
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    • pp.448-451
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    • 1998
  • The feasibility of using FT-NIR (Fourier Transform Near Infrared) spectrometer to measure NaOH, $Na_2CO_3$ and $Na_2S$ concentration in a naphtha cracking process, and an outline of the method development to identify spectral feature of the hydroxide whose band is overlapped by a strong water absorption were demonstrated. For measuring NaOH, $Na_2CO_3$ and $Na_2S$, FT-NIR spectrometer is a rapid and possible alternative to the current titration method with a standard deviation of 0.1.

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Application of the Method of Caustics into Anisotropic Materials (이방성재료에 대한 코스틱스법의 적용)

  • 백명철;최선호;황재석;김원현
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.12
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    • pp.2226-2240
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    • 1992
  • This paper studies the applicability of the method of caustics into anisotropic materials under mode I and mixed static loading conditions and introduces the procedure to obtain stress intensity factors(S.I.F.) in anisotropic materials by the method of caustics. The mapping equations for initial and caustic curves in anisotropic materials were introduced and their computer graphical images were compared to the experimental ones to check the validity of the mapping equations proposed in this paper. The agreement between them was found to satisfactory. Two kinds of method to determine S.I.F. in anisotropic materials by the method of caustics were proposed in this paper and applied into the orthotropic materials under various loading conditions. In the case of mode I loading condition, the S.I.F.'s obtained by this paper's methods were found to be quite similar to the results by other method, boundary element method(B.E.M) and in the case of mixed loading condtion, the S.I.F's by this paper and B.E.M. showed a little differences(2.2-24.4%) with respect to the slanted angle of crack.

The Kinetics of Delignification in Oxygen·Alkali pulping (효소(酵素)·알칼리 증해(蒸解)의 탈(脱)리그닌에 관(関)한 동역학적(動力學的) 분석(分析))

  • Jo, Byoung Muk;Shin, Dong So
    • Journal of Korean Society of Forest Science
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    • v.56 no.1
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    • pp.26-50
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    • 1982
  • In order to obtain more detailed information concerning the degradation of lignin in the oxygen alkali pulping single stage isothermal delignification of pine wood meal (Pinus koraiensis S. et Z.) was studied in the oxygen alkali system at five temperature level ($110^{\circ}C$, $120^{\circ}C$, $130^{\circ}C$, $140^{\circ}C$, $150^{\circ}C$) for 60 min.. The rate constant, activation energy, oxygen and alkali consumption during the oxygen alkali delignification were determined by the kinetic method. The 2/5 of total lignin was eliminated at the start of the reaction. The delignification rate constant was about 3 times that of caustic soda pulping. The activation energy was about 1/3 lower than in caustic soda pulping. Like oxygen consumption, alkali consumption was also rapid early at the reaction and almost ceased after about 10 min.. The degradation reaction of lignin was strongly dependent upon the pH decrease of the cooking liquor by organic acid generated in pulping. The lignin in the oxygen alkali pulping degraded into lover molecular weight and had more hydrophillic properties. The methoxyl group decreased considerably at the first of oxygen alkali delignification, while the carbonyl, carboxyl and phenolic hydroxyl group increased rapidly.

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Potential of Coal Gasification Slag as an Alkali-activated Cement (석탄가스화 복합발전 슬래그의 알칼리 활성 시멘트로서의 가능성)

  • Kim, Byoungkwan;Lee, Sujeong;Chon, Chul-Min;Choi, Hong-Shik
    • Resources Recycling
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    • v.27 no.2
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    • pp.38-47
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    • 2018
  • Integrated gasification combined cycle (IGCC) is a next generation energy production technology that converts coal into syngas with enhanced power generation efficiency and environmental performance. IGCC produces almost coal gasification slag as the solid by-product. IGCC slag is generated about 140,000 tons for a year although recycling of it is still in the early stages. We evaluated the potential of IGCC slag which is generated from a pilot plant in South Korea as an alkali-activated cement. Samples which were activated with the combined activator of sodium silicate solution and caustic soda had an average compressive strength of 4.5 MPa, showing expansion. Expansion of the alkali-activated slag was presumed to be caused by free CaO in the slag, although it was not detected by the ethylene glycol method. Samples that were activated with the combined activator of sodium aluminate and caustic soda had an average compressive strength of 10 MPa. Hydroxy sodalite and $C_3AH_6$ were found to be the new crystalline phases. IGCC slag can be used as an alkali-activated material, but the strength performance should be improved with proper mix design approach to calculate optimum proportions which can alleviate the expansion issue at the same time.