• Title/Summary/Keyword: methanol resistance

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Operating Characteristics of Direct Methanol Fuel Cell Based on Pt-Ru/C Anode Catalyst (Pt-Ru/C 촉매를 이용한 직접메탄을 연료전지 운전 특성)

  • Jung, D.H.;Lee, C.H.;Kim, C.S.;Chun, Y.G.;Shin, D.R.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1252-1254
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    • 1997
  • Direct methanol fuel cell based on a proton-exchange membrane electrolyte was investigated. 60% Pt-Ru/C and 60%Pt/C catalysts were employed for methanol oxidation and oxygen reduction, respectively. Morphologies of the catalysts were investigated by x-ray power diffraction, energy dispersive x-ray spectroscopy, and transmission microscopy. Electrochemical characteristics of the catalysts were tested by using cyclic voltametry technique. I-V characteristics of the fuel cell were tested by changing methanol concentration, temperature, and Nafion type as a proton-exchange membrane electrolyte. AC impedance technique was used to investigate the electrochemical performance of the fuel cell. The performance of single cell was enhance with increasing cell temperature. High operation temperature attributed to the combined effects of the reduction of ohmic resistance and polarization. High cell voltage was obtained from the concentration of 205M methanol. With Nafion 112, a current density of $230mA/cm^2$ at 0.55V was obtained from the concentration of 2.5M methanol.

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In Vitro Screening of Anti-lice Activity of Pongamia pinnata Leaves

  • Samuel, Anbu Jeba Sunilson John;Radhamani, Suraj;Gopinath, Rejitha;Kalusalingam, Anandarajagopal;Vimala, Anita Gnana Kumari Anbumani;Husain, Hj Azman
    • Parasites, Hosts and Diseases
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    • v.47 no.4
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    • pp.377-380
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    • 2009
  • Growing patterns of pediculocidal drug resistance towards head louse laid the foundation for research in exploring novel anti-lice agents from medicinal plants. In the present study, various extracts of Pongamia pinnata leaves were tested against the head louse Pediculus humanus capitis. A filter paper diffusion method was conducted for determining the potential pediculocidal and ovicidal activity of chloroform, petroleum ether, methanol, and water extracts of P. pinnata leaves. The findings revealed that petroleum ether extracts possess excellent anti-lice activity with values ranging between 50.3% and 100% where as chloroform and methanol extracts showed moderate pediculocidal effects. The chloroform and methanol extracts were also successful in inhibiting nymph emergence and the petroleum ether extract was the most effective with a complete inhibition of emergence. Water extract was devoid of both pediculocidal and ovicidal activities. All the results were well comparable with benzoyl benzoate (25% w/v). These results showed the prospect of using P. pinnata leave extracts against P. humanus capitis in difficult situations of emergence of resistance to synthetic anti-lice agents.

Low-Temperature Solution Polymerization of Vinyl Acetate in Methanol Using 4,4시-Azobis(4-cyanovaleric acid) in Methanol (4,4시-아조비스(4-시아노발레릭산)을 이용한 아세트산비닐의 메탄올계 저온 용액중합)

  • Kwak, Jin-Woo;Lyoo, Won-Seok
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.52-54
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    • 2003
  • Poly(vinyl alcohol) (PVA) obtained by the saponification of poly(vinyl ester) is a linear semicrystalline polymer; these polymers have been widely used as fibers for clothes and industries, binders, films, membranes, medicines for drug delivery system, and cancer cell-killing embolic materials. PVA fibers have high tensile and compressive strength, tensile modulus, and abrasion resistance because of the highest crystalline lattice modulus. (omitted)

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Sensing characteristics of Polypyrrole-based methanol sensors preparedbyin-situ vapor state polymerization

  • Linshu Jiang;Jun, Hee-Kwon;Hoh, Yong-Su;Lee, Duk-Dong;Huh, Jeung-Soo
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.137-137
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    • 2003
  • Conducting PPy/PVA composite and pure PPy gas sensors were prepared by in-situ vaporstate polymerization method in a vaporization chamber under N2 condition, by exposing the pre-coated electrode with PVA/FeC13 to distilled pyrrole monomer. The various electrical sensing behaviors of both types of sensors were systematically investigated by a flow measuring system including mass flow controller (MFC) and bubbling bottle. The FT-Raman spectroscopy of vapor state polymerized PPy was identical to that of chemically polymerized PPy, confirming the same chemical structure. Both types of sensors had positive sensitivity when exposed to methanol gas. The sensitivity varied linearly with gas concentration in the range of 50ppm to 1059ppm. The detection limit of PPy/PVA sensor was believed to be as low as 10ppm. The sensitivity of PPy/PVA composite sensor was higher than that of pure PPy sensor. Both the response time and recovery time of PPy/PVA composite sensors were longer than those of pure PPy sensors. The thickness of the sensing film affected the sensitivity this way that the sensor having thinner film had higher sensitivity, indicating that the resistance of polymer film involved in the sensing behavior was bulk resistance rather than surface resistance. The reproducibility of PPy/PVA composite sensor was excellent during eight on-off cycles by switching between N2 and 3000ppm methanol gas. The sensitivity of PPy/PVA composite sensor was only maintained for two weeks, while the sensitivity of pure PPy sensor was maintained over two months.

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Multidrug resistance reversal in mouse lymphoma cells by indian tea leaves, indian coffee seeds and chicory

  • Rao, Bhattiproulu Kesava;Motohashi, Noboru;Kawase, Masami;Spengler, Gabriella;Molnar, Joseph
    • Advances in Traditional Medicine
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    • v.3 no.2
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    • pp.100-105
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    • 2003
  • Systematic analysis of caffeine from the commercial samples of Indian tea leaves was performed by a routine method and the content of caffeine was found to be 19.0-37.4 mg/100 g leaves. The caffeine contents from coffee seeds and chicory from Indian origin were analyzed and found to be 0.6540-1.4920 g/100 g seeds. Caffeine contents of roasted Indian chicory roots were lower than either those of Indian tea leaves or Indian coffee seeds. The multidrug resistance (MDR) reversing effects were tested on a mouse leukemia cell line of L-5178 cells by methanol extracts [M1-M15] of Indian tea leaves and coffee seeds, comparing to a control of $({\pm})-verapamil$. The effects were measured by fluorescence ratio between treated and untreated group cells. Among fifteen methanol extracts, a Gemini tea [M6] (fluorescence activity ratio 5.26) had the most potent effect for L-5178 cells. The extract M6 was 0.63-fold of $({\pm})-verapamil$. We suggest that one of mechanisms of reversal by M6 might have strong affinity to dopamine $D_1$ and D_2$ receptors. Further studies with many more tumor and normal cell lines are necessary to confirm the MDR reversal specificity of coffee methanol extracts.

The Operation of Polymer Electrolyte Membrane Fuel Cell using Hydrogen Produced from the Combined Methanol Reforming Process

  • Park, Sang Sun;Jeon, Yukwon;Park, Jong-Man;Kim, Hyeseon;Choi, Sung Won;Kim, Hasuck;Shul, Yong-Gun
    • Journal of Electrochemical Science and Technology
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    • v.7 no.2
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    • pp.146-152
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    • 2016
  • A combined system with PEMFC and reformer is introduced and optimized for the real use of this kind of system in the future. The hydrogen source to operate the PEMFC system is methanol, which needs two parts of methanol reforming reaction and preferential oxidation (PROX) for the hydrogen fuel process in the combined operation PEMFC system. With the optimized methanol steam reforming condition, we tested PROX reactions in various operation temperature from 170 to 270 ℃ to investigate CO concentration data in the reformed gases. Using these different CO concentration, PEMFC performances are achieved at the combined system. Pt/C and Ru promoted Pt/C were catalysts were used for the anode to compare the stability in CO contained gases. The alloy catalyst of PtRu/C shows higher performance and better resistance to CO than the Pt/C at even high CO amount of 200 ppm, indicating a promotion not only to the activity but also to the CO tolerance. Furthermore, in a system point of view, there is a fluctuation in the PEMFC operation due to the unstable fuel supply. Therefore, we also modified the methanol reforming by a scaled up reactor and pressurization to produce steady operation of PEMFC. The optimized system with the methanol reformer and PEMFC shows a stable performance for a long time, which is providing a valuable data for the PEMFC commercialization.

Electric Properties of Carbon Using Electrochemical Process (전기화학 프로세스에 의한 Carbon 특성)

  • Lee, Sang-Heon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.388-389
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    • 2006
  • Electro-deposition of carbon film on silicon substrate in methanol solution was carried out with various current density, solution temperature and electrode spacing between anode and cathode. The carbon films with smooth surface morphology and high electrical resistance were formed when the distance between electrode was relatively wider. The electrical resistance of the carbon films were independent of both current density and solution temperature.

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Fabrication of Carbon Thin Film by Electrochemical Method (전기화학 Carbon Film 합성)

  • Lee, Sang-Heon
    • Proceedings of the KIEE Conference
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    • 2007.11a
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    • pp.128-129
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    • 2007
  • Electrochemical method of carbon film on silicon substrate in methanol solution was carried out with various current density, solution temperature and electrode spacing between anode and cathode. The carbon films with smooth surface morphology and high electrical resistance were formed when the distance between electrode was relatively wider. The electrical resistance of the carbon films were independent of both current density and solution temperature.

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Fabrication of DLC Using Electrodeposition (전기분해 DLC 합성)

  • Lee, Sang-Heon;Choi, Yong
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1265-1266
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    • 2007
  • Electro-deposition of carbon film on silicon substrate in methanol solution was carried out with various current density, solution temperature and electrode spacing between anode and cathode. The carbon films with smooth surface morphology and high electrical resistance were formed when the distance between electrode was relatively wider. The electrical resistance of the carbon films were independent of both current density and solution temperature.

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Screening of the Inhibitory Activity of Medicinal Plants against Protein Tyrosine Phosphatase 1B (생약의 Protein Tyrosine Phosphatase 1B (PTP1B) 저해활성 검색)

  • Hong, Jung-Hyun;Lee, Myung-Sun;Bae, Eun-Young;Kim, Young-Ho;Oh, Hyun-Cheol;Oh, Won-Keun;Kim, Bo-Yeon;Ahn, Jong-Seog
    • Korean Journal of Pharmacognosy
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    • v.35 no.1 s.136
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    • pp.16-21
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    • 2004
  • Protein tyrosine phosphatase 1B(PTP1B) is thought to be a negative regulator in insulin signal-transduction pathway. Insulin-resistance by the activation of PTP1B is a hallmark of both type 2 diabetes and obesity. Thus, the compounds inhibiting PTP1B can improve insulin resistance and can be effective in treating type 2 diabetes and obesity. The methanol extracts of 160 herbal medicines were screened for the inhibitory activity against PTP1B. Among the tested extracts, methanol extracts of Amsonia elliptica, Areca catechu, Benincasa hispida, Morus alba, Salvia miltiorrhiza, Siegesbeckia orientalis, and Trichosanthes kirilowii showed relatively strong inhibitory activity against PTP1B.